1,4-dimethylamino-2,2,5,5-tetramethyl-1,4-diaza-2,5-disilacyclohexane | 230977-82-9

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,4-dimethylamino-2,2,5,5-tetramethyl-1,4-diaza-2,5-disilacyclohexane
• 英文别名: 1-N,1-N,4-N,4-N,2,2,5,5-octamethyl-1,4,2,5-diazadisilinane-1,4-diamine
• CAS: 230977-82-9
• 化学式: C₁₀H₂₈N₄Si₂
• 分子量: 260.53
• InChiKey: RQGUNTBAIFUMNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.05
• 重原子数：
  16.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.96
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  1,4-dimethylamino-2,2,5,5-tetramethyl-1,4-diaza-2,5-disilacyclohexane 在 水 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以92%的产率得到1,3-bis(N',N'-dimethylhydrazinomethyl)-1,1,3,3-tetramethyldisiloxane
  参考文献：
  名称：

  摘要：

  Organosilicon and carbofunctional organosilicon compounds were reacted with chloro(chloromethyl)dimethylsilane, disilaethane, and disilaethene to obtain previously unknown linear and heterocyclic products.

  DOI：

  10.1023/a:1023459111655
• 作为产物：
  描述：

  氯甲基二甲基氯硅烷 、 1,1-bis(trimethylsilyl)-2,2-dimethylhydrazine 以86%的产率得到1,4-dimethylamino-2,2,5,5-tetramethyl-1,4-diaza-2,5-disilacyclohexane
  参考文献：
  名称：

  Synthesis and chemical transformations of silicon-containing derivatives ofN,N-dimethylhydrazine

  摘要：

  Reactions of carbofunctional organosilicon compounds with N,N-dimethyl-N'-trimethylsilylhydrazine and N,N-dimethyl-N',N'-bis(trimethylsilyl)hydrazine were studied. The composition and structure of the reaction products were found to be dependent on the reagent nature and the reaction conditions. 1,4-Dimethylamino-2,2,5,5-tetramethyl-1,4-diaza-2,5-disilacyclohexane, a first representative of a new type of 2, 5-disilapiperazines, was synthesized. A scheme of its formation was proposed.

  DOI：

  10.1007/bf02494422