4-hydroxybenzoic acid 4'-trifluoromethylphenyl ester | 132586-45-9

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 4-hydroxybenzoic acid 4'-trifluoromethylphenyl ester
• 英文别名: 4-hydroxy-benzoic acid-(4-trifluoromethyl-phenyl ester)；4-Hydroxy-benzoesaeure-(4-trifluormethyl-phenylester)；[4-(Trifluoromethyl)phenyl] 4-hydroxybenzoate
• CAS: 132586-45-9
• 化学式: C₁₄H₉F₃O₃
• 分子量: 282.219
• InChiKey: JJRAQSRIZBVWBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4-hydroxybenzoic acid 4'-trifluoromethylphenyl ester 在 4-二甲氨基吡啶 、 palladium 10% on activated carbon 、 氢气 作用下， 以 乙醇 、 二氯甲烷 、 氯仿 为溶剂， 反应 24.34h， 生成 [4-[4-(Trifluoromethyl)phenoxy]carbonylphenyl] 3-[4-[4-[11-[[dimethyl(trimethylsilylmethyl)silyl]methyl-dimethylsilyl]undecoxy]benzoyl]oxybenzoyl]oxybenzoate
  参考文献：
  名称：

  Topological Ferroelectric Bistability in a Polarization-Modulated Orthogonal Smectic Liquid Crystal

  摘要：

  We report a bent-core liquid crystal (LC) compound exhibiting two fluid smectic phases in which two-dimensional, polar, orthorhombic layers order into three-dimensional ferroelectric states. The lower-temperature phase has a uniform polarization field which responds in an analog fashion to applied electric field. The higher-temperature phase is a new smectic state with periodic undulation of the polarization, structurally modulated layers, and a bistable response to applied electric field which originates in the periodically splay-modulated bulk of the LC rather than by surface stabilization at the cell boundaries.

  DOI：

  10.1021/ja3009314
• 作为产物：
  描述：

  4-硝基三氟甲苯 在 盐酸 、 氢氟酸 、 tin(ll) chloride 作用下， 生成 4-hydroxybenzoic acid 4'-trifluoromethylphenyl ester
  参考文献：
  名称：

  Jones, Journal of the American Chemical Society, 1947, vol. 69, p. 2352

  摘要：

  DOI：

文献信息

• Curable composition and color filter
  申请人：FUJIFILM Corporation

  公开号：US10175573B2

  公开（公告）日：2019-01-08

  Provided is a colored curable composition having a good chemical resistance, and capable of forming a good colored layer pattern, the colored curable composition including an epoxy group-containing compound, and a phthalocyanine dye having a functional group capable of forming a covalent bond by a reaction with the epoxy group under heating.

  本发明提供了一种具有良好耐化学性并能形成良好彩色图层图案的彩色可固化组合物，该彩色可固化组合物包括一种含环氧基团的化合物，以及一种酞菁染料，其官能团能在加热条件下与环氧基团反应形成共价键。
• CURABLE COMPOSITION AND COLOR FILTER
  申请人：FUJIFILM Corporation

  公开号：US20150316844A1

  公开（公告）日：2015-11-05

  Provided is a colored curable composition having a good chemical resistance, and capable of forming a good colored layer pattern, the colored curable composition including an epoxy group-containing compound, and a phthalocyanine dye having a functional group capable of forming a covalent bond by a reaction with the epoxy group under heating.
• US6013748A
  申请人：——

  公开号：US6013748A

  公开（公告）日：2000-01-11