dichloro-β-aminodiethylsulfide palladium | 58450-63-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: dichloro-β-aminodiethylsulfide palladium
• 英文别名: [PdCl2(2-(ethylsulfanyl)ethylamine)]
• CAS: 58450-63-8
• 化学式: C₄H₁₁Cl₂NPdS
• 分子量: 282.53
• InChiKey: SSPAQYSYQNISRC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  dichloro-β-aminodiethylsulfide palladium 、 sodium perchlorate 在 AgNO₃ 作用下， 以 水 为溶剂， 以35%的产率得到Pd(CH₃CH₂SCH₂CH₂NH₂)2⁽²⁺⁾*2ClO₄^(1-)=[Pd(CH₃CH₂SCH₂CH₂NH₂)2](ClO₄)2
  参考文献：
  名称：

  Riera, X.; Moreno, V.; Font-Bardia, M., Polyhedron, 1999, vol. 18, p. 65 - 74

  摘要：

  DOI：
• 作为产物：
  描述：

  potassium tetrachloropalladate(II) 、 2-(乙硫基)乙胺 以 盐酸 为溶剂， 生成 dichloro-β-aminodiethylsulfide palladium
  参考文献：
  名称：

  Jensen, K. A., Zeitschrift fur anorganische Chemie, 1936, vol. 229, p. 279 - 279

  摘要：

  DOI：

文献信息

• Platinum(II) and palladium(II) complexes with 2-amino-4-methylsulfanylbutanol and 2-(ethylsulfanyl)ethylamine
  作者：Zijian Guo、Umberto Casellato、Giuseppina Faraglia、Rodolfo Graziani、Sergio Sitran

  DOI：10.1039/dt9940003231

  日期：——

  The reaction of K2[PtX4] (X = Cl or Br) with 2-(ethylsulfanyl)ethylamine (esea) (molar ratio 1:1) in aqueous solution yielded ionic [Pt(esea)2][PtX4] complexes which undergo thermal rearrangement to [PtX2(esea)]. By treating [PtCl2(esea)] or [PtX2(ambo)] (ambo = L-2-amino-4-methylsulfanylbutanol; X = Cl or Br) with an excess of the corresponding [PtX4]2- in water the binuclear complexes K[Pt2Cl5(esea)] and K[Pt2X5(ambo)] have been obtained. The crystal structure of K[Pt2Cl5(ambo)] was determined by X-ray crystallography and refined to R = 0.034, based on 1685 observed reflections. This binuclear complex, in which the ambo ligand is chelated to Pt(1) through the N and S donor atoms and also co-ordinated to Pt(2) through the S atom, is the first example of a chelated methionine derivative with S acting as bridging donor. The Pt atoms are four-co-ordinate in a slightly distorted square-planar geometry. Selected bond distances are Pt-Cl 2.30 (mean of five values), Pt-S 2.26 (mean), and Pt-N 2.05(1) angstrom; the Pt(1)-S-Pt(2) angle is 116.8(2)-degrees. Proton NMR spectra support rupture of the sulfur bridge of the binuclear complexes in dimethyl sulfoxide to form the corresponding [PtX2L] species. The presence of equilibria between ionic and neutral species in the same solvent is also discussed.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pd: MVol.2, 127, page 411 - 412
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  DOI：——

  日期：——