三聚氰胺与过氧化氢的化合物 | 3085-95-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 三聚氰胺与过氧化氢的化合物
• 英文名称: melamine hydrogen peroxide
• 英文别名: melamine peroxosolvate；melamine peroxide；Melamine hydroperoxide；hydrogen peroxide;1,3,5-triazine-2,4,6-triamine
• CAS: 3085-95-8
• 化学式: C₃H₆N₆*H₂O₂
• 分子量: 160.136
• InChiKey: KDNFLUWYIMPBSA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.36
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  157
• 氢给体数：
  5
• 氢受体数：
  8

安全信息

• 海关编码：
  2933699090

反应信息

• 作为产物：
  描述：

  三聚氰胺 在 双氧水 作用下， 以 水 为溶剂， 反应 0.5h， 生成 三聚氰胺与过氧化氢的化合物
  参考文献：
  名称：

  Melamine Hydrogen Peroxide (MHP): Novel and Efficient Reagent for the Chemo- and Homoselective and Transition Metal–Free Oxidation of Thiols and Sulfides

  摘要：

  Melamine hydrogen peroxide (MHP) as a novel hydrogen peroxide adduct was easily prepared. Both chemo- and homoselective oxidation of thiols and sulfides to their corresponding disulfides and sulfoxides occurred by using MHP in moderate to excellent yields. AlCl3 acts as a suitable activator in the oxidation of sulfides with MHP.

  DOI：

  10.1080/10426500902758386
• 作为试剂：
  描述：

  2,6-二氯苯硫酚 在 三聚氰胺与过氧化氢的化合物 作用下， 以 乙腈 为溶剂， 反应 0.17h， 以71%的产率得到bis(2,6-dichlorophenyl)disulfide
  参考文献：
  名称：

  Melamine Hydrogen Peroxide (MHP): Novel and Efficient Reagent for the Chemo- and Homoselective and Transition Metal–Free Oxidation of Thiols and Sulfides

  摘要：

  Melamine hydrogen peroxide (MHP) as a novel hydrogen peroxide adduct was easily prepared. Both chemo- and homoselective oxidation of thiols and sulfides to their corresponding disulfides and sulfoxides occurred by using MHP in moderate to excellent yields. AlCl3 acts as a suitable activator in the oxidation of sulfides with MHP.

  DOI：

  10.1080/10426500902758386

文献信息

• Melamine Hydrogen Peroxide (MHP): Novel and Efficient Reagent for the Chemo- and Homoselective and Transition Metal–Free Oxidation of Thiols and Sulfides
  作者：Gholamabbas Chehardoli、Mohammad Ali Zolfigol

  DOI：10.1080/10426500902758386

  日期：2009.12.29

  Melamine hydrogen peroxide (MHP) as a novel hydrogen peroxide adduct was easily prepared. Both chemo- and homoselective oxidation of thiols and sulfides to their corresponding disulfides and sulfoxides occurred by using MHP in moderate to excellent yields. AlCl3 acts as a suitable activator in the oxidation of sulfides with MHP.