diisopropylphosphorylthiourea | 118835-59-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: diisopropylphosphorylthiourea
• 英文别名: diisopropoxyphosphoryl-thiourea；N-Thiocarbamoyl-amidophosphorsaeure-diisopropylester；Phosphorsaeure-diisopropylester-thioureid；Diisopropoxyphosphoryl-thioharnstoff；Di(propan-2-yloxy)phosphorylthiourea
• CAS: 118835-59-9
• 化学式: C₇H₁₇N₂O₃PS
• 分子量: 240.263
• InChiKey: WFDKZZZOQQCJSI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  106
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diisopropylphosphorylthiourea 、 氯乙酸甲酯 在 三乙胺 作用下， 以 苯 为溶剂， 以54%的产率得到2-[di(propan-2-yloxy)phosphorylamino]-1,3-thiazol-4-one
  参考文献：
  名称：

  Kamalov, R. M.; Khailova, N. A.; Pudovik, M. A., Journal of general chemistry of the USSR, 1989, vol. 59, # 12.1, p. 2383 - 2387

  摘要：

  DOI：
• 作为产物：
  描述：

  氯磷酸二异丙酯 在 氨 、 水 、 丙酮 作用下， 生成 diisopropylphosphorylthiourea
  参考文献：
  名称：

  Lewtschenko; Shmurowa, Ukrainskij Khimicheskij Zhurnal, 1956, vol. 22, p. 623,626

  摘要：

  DOI：

文献信息

• Xi, Shi-Kang; Zhao, Yu-Fen, Synthetic Communications, 1990, vol. 20, # 21, p. 3295 - 3301
  作者：Xi, Shi-Kang、Zhao, Yu-Fen

  DOI：——

  日期：——
• SYNTHESIS AND CHARACTERIZATION OF CADMIUM COMPLEXES WITH PHOSPHORYLATED LIGANDS
  作者：Judith Felcman、Damiana C. N. Lopes、Renata A. Cattapan、Claudio A. Téllez Soto

  DOI：10.1081/sim-100002236

  日期：2001.3.31

  Complexes of cadmium(II) with phosphorylated ligands were studied in the solid state. One of these ligands is phosphocreatine (HPCR), an important natural compound and the others are diisopropylphosphorylguanidine (DPG) and diisopropylphosphorylthiourea (DPT). The complexes were synthesized and characterized by elemental and thermogravimetric analyses and IR and Raman spectroscopy. The formed complexes are: [Cd(PCr)Cl](2), Cd(DPG)Cl-2 and [Cd(DPT)(3)Cl]Cl. In the HPCR and DPG complexes, Cd(II) is bound through the oxygen of the phosphoryl group and the nitrogen of the guanidine group and in the DPT complexes through the sulfur atom.
• Lin, Whei Oh; Guimaraes, Carlos N.; Souza, Marcos C. De, Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 92, # 1-4, p. 1 - 10
  作者：Lin, Whei Oh、Guimaraes, Carlos N.、Souza, Marcos C. De、Costa, Joao B. N. Da、Alt, Helmut G.

  DOI：——

  日期：——
• Studies on zinc(II) complexes with N-thioacylamidophosphates: X-ray crystal structure of the [Zn(RC(S)NP(O)(OiPr)2)2] (R = NH2, tBuNH, c-C6H11NH)
  作者：Damir A. Safin、Felix D. Sokolov、Heinrich Nöth、Maria G. Babashkina、Timur R. Gimadiev、Joanna Galezowska、Henryk Kozlowski

  DOI：10.1016/j.poly.2008.03.005

  日期：2008.6

  The photoluminescent properties of 17 zinc(II) chelates [Zn(RC(S)NP(C)(OiPr)(2)-0,S)(2)] (R = Ph (1a), PhNH (1b), p-BrPh (1c), p-MeCC6H4NH (1d), p-BrC6H4NH (le), NH2 (1f), iPrNH (1g), tBuNH (1h), Et2N (1i), c-C5H10N (1j), c-OC4HgN (1k), c-C6H11NH (1I), aminobenzo-15-crown-5 (1m)) and [Zn(B) (RC(S)NP(O)(OiPr)(2)-O,S)(2)](R=Ph, B=2,2'-bipyridine (2a); R=Ph, B=1,10-phenanthroline (2b); R = PhNH, B = 2,2'-bipyridine (2c); R = PhNH, B = 1,10-phenanthroline (2d)), are reported. Colorless and air/moisture stable chelate complexes of divalent zinc show blue emission in the solid state when excited with UV light. Complexes If, 1h, 1I were investigated by single crystal X-ray diffraction. The zinc(II) atom in complexes If, 1h, 1I is in a distorted tetrahedral O2S2 environment formed by the C=S sulphur atoms and the P=O oxygen atoms of two deprotonated ligands. (C) 2008 Elsevier Ltd. All rights reserved.
• KAMALOV, R. M.;XAJLOVA, N. A.;PUDOVIK, M. A.;PUDOVIK, A. N., ZH. OBSHCH. XIMII, 59,(1989) N2, S. 2666-2671
  作者：KAMALOV, R. M.、XAJLOVA, N. A.、PUDOVIK, M. A.、PUDOVIK, A. N.

  DOI：——

  日期：——