hexachloroosmate(IV) ion | 16871-52-6

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: hexachloroosmate(IV) ion
• 英文别名: tetrachloroosmium;dichloride
• CAS: 16871-52-6
• 化学式: Cl₆Os
• 分子量: 402.918
• InChiKey: UTIXXJBEMJZGFB-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  4.13
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  三氟化溴 、 hexachloroosmate(IV) ion 生成 cis-dichlorotetrafluoroosmate(IV) ion 、 cis-difluorotetrachloroosmate(IV) ion
  参考文献：
  名称：

  Dipyridiniomethane cis- and trans-Difluorotetrachloroosmate(IV), cis- and trans-[(C5H5N)2CH2][OsCl4F2]

  摘要：

  In the structures of N,N' difluorotetrachloroosmate(IV), (I), and N,N'-methylenedipyridinium trans-difluorotetrachloroosmate(IV), (II), cis- and trans-[(C5H5N)(2)CH2][OsCl4F2], the trans influence in the F-Os-Cl axes of (I) lengthens the average Os-F distance to 1.948 Angstrom and shortens the average Os-Cl distance to 2.316 Angstrom, compared with those of the symmetrically coordinated axes F-Os-F in (II) and Cl-Os-Cl in (I) and (II), respectively, with mean values of 1.926 and 2.337 Angstrom observed for Os-F and Os-Cl, respectively.

  DOI：

  10.1107/s0108270195010717

文献信息

• Dipyridiniomethane cis- and trans-Difluorotetrachloroosmate(IV), cis- and trans-[(C5H5N)2CH2][OsCl4F2]
  作者：C. Bruhn、W. Preetz

  DOI：10.1107/s0108270195010717

  日期：1996.2.15

  In the structures of N,N' difluorotetrachloroosmate(IV), (I), and N,N'-methylenedipyridinium trans-difluorotetrachloroosmate(IV), (II), cis- and trans-[(C5H5N)(2)CH2][OsCl4F2], the trans influence in the F-Os-Cl axes of (I) lengthens the average Os-F distance to 1.948 Angstrom and shortens the average Os-Cl distance to 2.316 Angstrom, compared with those of the symmetrically coordinated axes F-Os-F in (II) and Cl-Os-Cl in (I) and (II), respectively, with mean values of 1.926 and 2.337 Angstrom observed for Os-F and Os-Cl, respectively.