4-[Bis(4-aminophenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]aniline | 873664-04-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 4-[Bis(4-aminophenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]aniline
• CAS: 873664-04-1
• 化学式: C₃₁H₂₆N₃O₂P
• 分子量: 503.54
• InChiKey: AHOYKMCKWGJDAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  37
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  104
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  马来酸酐 、 4-[Bis(4-aminophenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]aniline 在 sodium acetate 、 乙酸酐 作用下， 反应 19.5h， 以92.5%的产率得到1,1',1''-(((6-oxidodibenzo[c,e][1,2]oxaphosphinin-6-yl)methanetriyl)tris(benzene-4,1-diyl))tris(1H-pyrrole-2,5-dione)
  参考文献：
  名称：

  Nonlinear optical hyperbranched polyaspartimide/montmorillonite nanocomposites based on reactive fluorine- or phosphorous-containing organoclays

  摘要：

  A series of novel hyperbranched polyaspartimide/organoclay nanocomposites were developed for second-order nonlinear optics. The hyperbranched polyaspartimides were synthesized from an azobenzene chromophore bis(4-aminopheny1(4-(4-nitrophenyl)-diazenyl)phenyl)amine (DAC; A(2) type monomer) and a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-containing trimaleimide (Dopo-trimaleimide; B3 type monomer) via Michael addition reaction. Moreover, reactive fluorine- and phosphorous-containing organoclays (F-montmorillonite, i.e. F-MMT and P-montmorillonite, i.e. P-MMT) which had been prepared by modifying the high aspect ratio silicate layers of MMTs with two different swelling agents 1,1,1-tris[4-(4-amino-2-trifluoromethylphenoxy)-phenyl]ethane (F-triamine) and (9,10dihydro-9-oxa-10-phosphaphenanthrene-10-yl)tris(4-aminophenyl)methane (P-triamine) were respectively incorporated into the nonlinear optical hyperbranched polyaspartimides. The organoclays were exfoliated and dispersed in the hyperbranched polyaspartimide films. The incorporation of exfoliated organoclay F-MMT could effectively enhance the electro-optical (60) coefficients and temporal stability of the hyperbranched polyaspartimides. The hyperbranched polyaspartimide/F-MMT nanocomposite exhibited temporal stability (r(33)(t)/r(33)(0) = 73%) at 100 degrees C, 60 coefficient r(33) of 20.9 pm/V, and optical loss of 3.0 dB/cm at 1310 nm. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2013.05.040
• 作为产物：
  描述：

  碱性红 9 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 三乙胺 作用下， 以 乙醇 为溶剂， 反应 14.0h， 以78.5%的产率得到4-[Bis(4-aminophenyl)-(6-oxobenzo[c][2,1]benzoxaphosphinin-6-yl)methyl]aniline
  参考文献：
  名称：

  Nonlinear optical hyperbranched polyaspartimide/montmorillonite nanocomposites based on reactive fluorine- or phosphorous-containing organoclays

  摘要：

  A series of novel hyperbranched polyaspartimide/organoclay nanocomposites were developed for second-order nonlinear optics. The hyperbranched polyaspartimides were synthesized from an azobenzene chromophore bis(4-aminopheny1(4-(4-nitrophenyl)-diazenyl)phenyl)amine (DAC; A(2) type monomer) and a 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide-containing trimaleimide (Dopo-trimaleimide; B3 type monomer) via Michael addition reaction. Moreover, reactive fluorine- and phosphorous-containing organoclays (F-montmorillonite, i.e. F-MMT and P-montmorillonite, i.e. P-MMT) which had been prepared by modifying the high aspect ratio silicate layers of MMTs with two different swelling agents 1,1,1-tris[4-(4-amino-2-trifluoromethylphenoxy)-phenyl]ethane (F-triamine) and (9,10dihydro-9-oxa-10-phosphaphenanthrene-10-yl)tris(4-aminophenyl)methane (P-triamine) were respectively incorporated into the nonlinear optical hyperbranched polyaspartimides. The organoclays were exfoliated and dispersed in the hyperbranched polyaspartimide films. The incorporation of exfoliated organoclay F-MMT could effectively enhance the electro-optical (60) coefficients and temporal stability of the hyperbranched polyaspartimides. The hyperbranched polyaspartimide/F-MMT nanocomposite exhibited temporal stability (r(33)(t)/r(33)(0) = 73%) at 100 degrees C, 60 coefficient r(33) of 20.9 pm/V, and optical loss of 3.0 dB/cm at 1310 nm. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2013.05.040

文献信息

• Phosphorus-containing compounds and their preparing process and use
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：US08222441B2

  公开（公告）日：2012-07-17

  A series of novel phosphorus-containing compounds having the following formula are disclosed: wherein R1-R12, A, B, D, X, and Y are as defined in the specification. A process for the preparation of the compound of formula (1), a curing agent, and a flame resistant epoxy resin and a preparation process thereof are also provided.

  披露了一系列具有以下公式的含磷新化合物： 其中 R1-R12、A、B、D、X和Y的定义如说明书所述。 还提供了公式（1）化合物的制备方法、固化剂以及耐火焰环氧树脂及其制备过程。
• PROCESS FOR MAKING BENZOXAZINES
  申请人：Cytec Industries Inc.

  公开号：US20160115139A1

  公开（公告）日：2016-04-28

  A synthesis process for making a benzoxazine compound containing at least one benzoxazine unit from aromatic amine containing at least one primary amino group, at least one phenolic compound with at least one ortho-hydrogen, and alkyl formcel. In one embodiment, the aromatic amine is reacted with alkyl formcel to generate an alkoxymethyl intermediate compound. Subsequently, the intermediate compound is reacted with a phenol to generate the benzoxazine compound. In another embodiment, the benzoxazine compound is formed by reacting aromatic amine with alkyl formcel and phenol in one reaction step. Also disclosed is a method for isolating the alkoxymethyl compound formed by reacting aromatic amine with alkyl formcel. The isolated alkoxymethyl compound is useful as a reactant in a subsequent reaction.

  一种合成过程，用于从含有至少一个苯并噁嗪单元的芳香胺，至少含有一个一级氨基的芳香胺，至少含有一个邻位氢的酚类化合物和烷基甲醛制备含有至少一个苯并噁嗪单元的苯并噁嗪化合物。在一种实施方式中，将芳香胺与烷基甲醛反应以生成烷氧甲基中间体化合物。随后，将中间体化合物与酚反应以生成苯并噁嗪化合物。在另一种实施方式中，通过在一个反应步骤中将芳香胺与烷基甲醛和酚反应来形成苯并噁嗪化合物。还公开了一种方法，用于分离由芳香胺与烷基甲醛反应形成的烷氧甲基化合物。分离的烷氧甲基化合物可用作随后反应中的反应物。
• BENZOXAZINE-BASED MONOMER FOR THERMOSETTING RESINS
  申请人：Cytec Industries Inc.

  公开号：EP3456709A1

  公开（公告）日：2019-03-20

  A benzoxazine monomer of formula (A) useful to prepare thermosetting resins.

  式 (A) 的苯并恶嗪单体 可用于制备热固性树脂。
• Process for making benzoxazines
  申请人：CYTEC INDUSTRIES INC.

  公开号：US10227313B2

  公开（公告）日：2019-03-12

  A synthesis process for making a benzoxazine compound containing at least one benzoxazine unit from aromatic amine containing at least one primary amino group, at least one phenolic compound with at least one ortho-hydrogen, and alkyl formcel. In one embodiment, the aromatic amine is reacted with alkyl formcel to generate an alkoxymethyl intermediate compound. Subsequently, the intermediate compound is reacted with a phenol to generate the benzoxazine compound. In another embodiment, the benzoxazine compound is formed by reacting aromatic amine with alkyl formcel and phenol in one reaction step. Also disclosed is a method for isolating the alkoxymethyl compound formed by reacting aromatic amine with alkyl formcel. The isolated alkoxymethyl compound is useful as a reactant in a subsequent reaction.

  一种用含有至少一个伯氨基的芳香胺、至少一种含有至少一个正交氢的酚类化合物和甲酰烷基醚制取含有至少一个苯并恶嗪单元的苯并恶嗪化合物的合成工艺。在一个实施方案中，芳香胺与甲缩醛烷基酯反应生成烷氧基甲基中间化合物。随后，中间化合物与苯酚反应生成苯并恶嗪化合物。在另一个实施方案中，苯并恶嗪化合物是通过芳香胺与烷基甲缩醛和苯酚在一个反应步骤中反应生成的。还公开了一种分离芳香胺与烷基甲缩醛反应生成的烷氧基甲基化合物的方法。分离出的烷氧基甲基化合物可用作后续反应的反应物。
• Novel phosphorus-containing compounds and their preparing process and use
  申请人：Chang Chun Plastics Co., Ltd.

  公开号：EP2116549B1

  公开（公告）日：2015-08-05