Xenon Monoiodide | 55130-05-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: Xenon Monoiodide
• 英文别名: Xenon iodide
• CAS: 55130-05-7
• 化学式: IXe
• 分子量: 258.195
• InChiKey: GKUXZDSXCFGSFF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.89
• 重原子数：
  2.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氙气 在 碘 作用下， 生成 Xenon Monoiodide
  参考文献：
  名称：

  Product branching ratios in the reaction of Xe*(³P_2,0) with IBr. Role of excited potential surface

  摘要：

  The reaction of Xe*(3P2,0) with IBr to form the XeI* and XeBr* excimers was studied using two crossed molecular beam techniques. Emission spectra were obtained between 200 and 400 nm, and relative cross sections and branching ratios were measured as a function of collision energy over the range 15–420 meV. The observed effects are discussed in terms of a curve crossing model, involving the neutral potential surface and both ground and excited Xe++IBr− potential surfaces. In this model, XeBr* is formed from the ground state ionic potential and XeI* is formed from the excited potential.

  DOI：

  10.1063/1.447934

文献信息

• Competitive channels in the interaction of Xe(3 P J) with Cl2, Br2 and I2. Atom transfer, excitation transfer, energy disposal and product rotational alignment
  作者：Keith Johnson、Roland Pease、John P. Simons、Peter A. Smith、Agust Kvaran

  DOI：10.1039/f29868201281

  日期：——

  excited rare-gas atoms, e.g. Xe[np5(n+ 1)s] with the molecular halogens leads both to atom transfer (generating vibrationally and electronically excited rare gas halides) and to excitation transfer (generating electronically excited molecular halogens in a range of ion-pair excimer states). Translational energy utilisation and rotational alignment in the products of the atom transfer channel have been probed

  电子激发的稀有气体原子的碰撞，例如Xe [ np 5（n + 1）s]与分子卤素一起导致原子转移（产生振动和电子激发的稀有气体卤化物）和激发转移（产生在离子对准分子态范围内的电子激发的分子卤素）。使用超热脉冲分子束技术研究了原子转移通道产物中的平移能量利用和旋转排列，同时通过直接反演解析的化学发光发射光谱重新评估了在热碰撞条件下确定的振动能和支化比。 。通过激发转移已经确定了通过激发转移而形成的卤素准分子态的范围。
• Translational energy dependence of reaction dynamics in kinematically constrained systems. Xe(3P2)+ HCl, HBr, Hl and CH3l
  作者：William S. Hartree、John P. Simons

  DOI：10.1039/ft9908600011

  日期：——

  chemiluminescence spectra excited by reactions of Xe(3P2) with Hl, HBr, HCl and CH3l have been recorded under superthermal beam–Maxwellian gas conditions. Direct spectral inversion has enabled determination of the rare-gas halide product vibrational energy distributions at selected collision energies in the range 〈ET〉≈(4–90)kJ mol–1. The mean vibrational energy disposals 〈E′v〉 are found to increase linearly with

  Xe（3 P 2）与Hl，HBr，HCl和CH 3 l反应激发的完全分散的化学发光光谱已在超热束-麦克斯韦气体条件下记录。直接频谱倒置在<范围，使上述稀有气体卤化物产物的振动能量分布的测定在选择的碰撞能量Ë Ť >≈（4-90）千焦摩尔-1。平均振动能量处置< é ' v >被发现与平均碰撞能量<线性增加È Ť〉。该结果，随着反应性激发函数较早测量（KM约翰逊，JP西门子，PA史密斯，C.华盛顿和A. Kvaran，一起摩尔的PHY。，1986，57，255），并与动态运动约束，允许将平均能量处置的单独估计值转换为旋转和平移以及平均无功横截面。
• Two-color, two-photon, direct laser-assisted reactions of Xe with Br2, I2, CCl4, CCl3Br and CCl2Br2
  作者：J. Qin、D.W. Setser

  DOI：10.1016/0009-2614(91)87175-b

  日期：1991.9

  pulsed dye laser have been used to induce two-photon, laser-assisted reactions in low pressure gas mixtures of Xe with Br2, CCl4, CCl3Br, CCl2Br2 and I2. The products are XeCl(B, C), XeBr(B, C) or XeI(B, C) following two-photon promotion to the reactive ion-pair potentials. The utilization of a two-color scheme enhances the two-photon, laser-assisted reactions because of better match with an intermediate

  脉冲染料激光器的基本输出加倍的输出已用于在Xe与Br 2，CCl 4，CCl 3 Br，CCl 2 Br 2和I 2的低压气体混合物中引发双光子激光辅助反应。在两个光子提升到反应性离子对电位之后，产物为XeCl（B，C），XeBr（B，C）或XeI（B，C）。由于与试剂分子的中间状态更好地匹配，因此采用双色方案可增强双光子激光辅助反应。由CCl 3 Br和CCl 2 Br 2形成XeCl（B，C）的产物选择性 通过激光辅助反应，证明了与Xe（6s）或Xe（6p）原子的完全碰撞。
• Rate constants and branching fractions for xenon halide formation from Xe(³<i>P</i>₂) and Xe(³<i>P</i>₁) reactions
  作者：Daimay Lin、Y. C. Yu、D. W. Setser

  DOI：10.1063/1.447636

  日期：1984.12.20

  The rate constants for XeF(B,C), XeCl(B,C), and XeI(B,C) formation from reactions of Xe(3P1) and Xe(3P2) with NF3, N2F4, NF2, CCl4, and CF3I have been measured relative to XeCl(B,C) formation from the reactions with Cl2. The XeCl(B,C) formation rate constants from Cl2 are assumed to equal the total Xe(3P2) and Xe(3P1) quenching rate constants. The dependence of the XeX* formation rate constants upon reagent for Xe(3P1) and Xe(3P2) are similar with the polyatomic reagents having considerably smaller XeX* product formation rate constants than does Cl2. The previous claim from this laboratory that the XeF(B,C) formation rate constant from NF3 was approximately equal to the total quenching rate constant is revised downward in this work.
• Emission spectra of KrXeCl*, KrXeBr*, KrXeI*, ArKrF*, and ArKrCl*
  作者：H. C. Brashears、D. W. Setser、Y.‐C. Yu

  DOI：10.1063/1.440863

  日期：1981.1

  Sensitized reactions of Xe and Kr with halogen donors in the presence of high buffer gas pressures of Kr and Ar, respectively, have led to the observation of five emission bands in the ultraviolet region of the spectrum. These broad structureless bands are assigned to the mixed rare gas–halide trimers KrXeCl, KrXeBr, KrXeI, ArKrF, and ArKrCl. Despite an extensive search, no emission corresponding to KrXeF could be found and this mixed trimer may be unstable because of interaction with a lower repulsive state. The positions and half-widths of the five emission bands are characterized, and the formation mechanism of the mixed trimers in these experiments is discussed.