[(hex-5-yn-1-yloxy)methanetriyl]tribenzene | 52517-93-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: [(hex-5-yn-1-yloxy)methanetriyl]tribenzene
• 英文别名: 1-trityloxyhex-5-yne；1-Triphenylmethoxy-5-hexin；1-Triphenylmethoxy-5-hexyne；[hex-5-ynoxy(diphenyl)methyl]benzene
• CAS: 52517-93-8
• 化学式: C₂₅H₂₄O
• 分子量: 340.465
• InChiKey: YCPDADMFCLZNEP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  [(hex-5-yn-1-yloxy)methanetriyl]tribenzene 在 吗啉 、 Au-TiO₂ 、 水 作用下， 以 1,4-二氧六环 为溶剂， 反应 2.0h， 以89%的产率得到6-(trityloxy)hexan-2-one
  参考文献：
  名称：

  Supported Gold Nanoparticle-Catalyzed Hydration of Alkynes under Basic Conditions

  摘要：

  TiO2-supported nanosize gold particles catalyze the hydration of alkynes using morpholine as a basic cocatalyst. Unlike most homogeneous cationic gold catalysts, the TiO2-Au/morpholine system is weakly basic and is compatible with acid-sensitive functional groups (e.g., silyl ethers, ketals) or with a strongly coordinating group such as pyridine. Whats more, this gold catalyst can be recycled by simple filtration and works well in flow reactors.

  DOI：

  10.1021/ol5033859
• 作为产物：
  描述：

  5-己炔-1-醇 、 三苯基氯甲烷 在 4-二甲氨基吡啶 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以80%的产率得到[(hex-5-yn-1-yloxy)methanetriyl]tribenzene
  参考文献：
  名称：

  Supported Gold Nanoparticle-Catalyzed Hydration of Alkynes under Basic Conditions

  摘要：

  TiO2-supported nanosize gold particles catalyze the hydration of alkynes using morpholine as a basic cocatalyst. Unlike most homogeneous cationic gold catalysts, the TiO2-Au/morpholine system is weakly basic and is compatible with acid-sensitive functional groups (e.g., silyl ethers, ketals) or with a strongly coordinating group such as pyridine. Whats more, this gold catalyst can be recycled by simple filtration and works well in flow reactors.

  DOI：

  10.1021/ol5033859

文献信息

• Redox-ligand sustains controlled generation of CF₃ radicals by well-defined copper complex
  作者：Jérémy Jacquet、Sébastien Blanchard、Etienne Derat、Marine Desage-El Murr、Louis Fensterbank

  DOI：10.1039/c5sc03636d

  日期：——

  Cooperative catalysis involving copper(ii) complex bearing redox ligands allows generation of CF˙3 radicals through ligand-based SET while metallic oxidation state is preserved.

  铜（II）配合物参与的合作催化可以通过氧化还原配体产生CF˙3自由基，同时保持金属的氧化态。
• Hydroxylated 15-deoxy derivatives of 9-hydroxy-13-trans-prostenoic acid
  申请人：American Cyanamid Company

  公开号：US03950406A1

  公开（公告）日：1976-04-13

  This disclosure describes certain 15-deoxy prostanoic acid derivatives having a hydroxy group further along in the beta-chain, useful as bronchodilators, hypotensive agents, anti-ulcer agents, or as intermediates.

  本披露描述了某些具有β-链中进一步的羟基的15-去氧前列腺酸衍生物，可用作支气管扩张剂、降压剂、抗溃疡剂或中间体。
• Novel hydroxy substituted 15-deoxy-5-cis-prostenoic acids and esters
  申请人：American Cyanamid Company

  公开号：US04179451A1

  公开（公告）日：1979-12-18

  This disclosure describes certain hydroxy substituted 15-deoxy-5-cis-prostenoic acids and esters useful as hypotensive agents, anti-ulcer agents, bronchodilators, anti-microbial agents, anticonvulsants, or as intermediates.

  本文披露了某些羟基取代的15-去氧-5-顺式前列腺酸及其酯类，可用作降压剂、抗溃疡剂、支气管扩张剂、抗微生物剂、抗癫痫剂或中间体。
• Blueberry plant named ‘Ridley 4609’
  申请人：Mountain Blue Orchards Pty Ltd.

  公开号：USPP029469P3

  公开（公告）日：2018-07-10

  The new blueberry plant variety ‘RIDLEY 4609’ is provided. The variety is produced from a cross of ‘C95-152’ (unpatented) and pollen parent ‘C00-09’ (U.S. Plant Pat. No. 22,778), which can be distinguished by its outstanding features.

  提供了新的蓝莓植物品种“ RIDLEY 4609”。该品种是由“ C95-152”（未受专利保护）和花粉亲本“ C00-09”（美国植物专利号22,778）的交叉产生的，可以通过其突出的特征来区分。
• Derivatives of 9-hydroxy-13-trans-prostenoic acid
  申请人：American Cyanamid Company

  公开号：US04061672A1

  公开（公告）日：1977-12-06

  This disclosure describes certain 15-deoxy prostanoic acid derivatives having a hydroxy group further along in the beta-chain, useful as bronchodilators, hypotensive agents, anti-ulcer agents, or as intermediates.

  本公开说明了某些15-去氧前列腺酸衍生物，其在β-链中进一步具有羟基，可用作支气管扩张剂、降压剂、抗溃疡剂或中间体。