4-methyl-2-[(2,2,3,3,4,4,5,5-octafluoropentyl)oxy]-1,3,2-dioxaphosphinane | 1594135-03-1

• 分子结构分类: 有机化合物 - 有机磷化合物 - 亚磷酸三烷基酯
• 英文名称: 4-methyl-2-[(2,2,3,3,4,4,5,5-octafluoropentyl)oxy]-1,3,2-dioxaphosphinane
• 英文别名: 4-Methyl-2-(2,2,3,3,4,4,5,5-octafluoropentyloxy)-1,3,2-dioxaphosphorinane；4-methyl-2-(2,2,3,3,4,4,5,5-octafluoropentoxy)-1,3,2-dioxaphosphinane
• CAS: 1594135-03-1
• 化学式: C₉H₁₁F₈O₃P
• 分子量: 350.146
• InChiKey: SMLPGAAOQBAQQW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  2,2,3,3,4,4,5,5-八氟-1-戊醇 、 2-Chloro-4-methyl-1,3,2-dioxaphosphorinane 在 三乙胺 作用下， 以 正己烷 为溶剂， 以72%的产率得到4-methyl-2-[(2,2,3,3,4,4,5,5-octafluoropentyl)oxy]-1,3,2-dioxaphosphinane
  参考文献：
  名称：

  Electrolyte additive and electrolyte including same and lithium rechargeble battery including electrolyte

  摘要：

  公开了一种由以下化学式1表示的电解质添加剂，以及包括该电解质添加剂的可充电锂电池的电解质，以及包括该电解质的可充电锂电池。在化学式1中，R1至R4的定义与详细说明中的相同。

  公开号：

  EP2746288A1

文献信息

• Synthesis and Isomer Composition of 2-Polyfluoroalkoxy-1,3,2-dioxaphospholanes and -phosphinanes
  作者：N. K. Gusarova、S. I. Verkhoturova、S. N. Arbuzova、T. I. Kazantseva、A. I. Albanov、A. M. Nalibaeva、G. K. Bishimbaeva、K. A. Apartsin、V. V. Kireeva、B. A. Trofimov

  DOI：10.1134/s107036321804014x

  日期：2018.4

  Polyfluoroalkanols readily reacted with 2-chloro-1,3,2-dioxaphospholanes and 2-chloro-1,3,2-dioxaphosphinanes in hexane in the presence of triethylamine (-10 to 25A degrees C, 5 h) to give 2-polyfluoroalkoxy-1,3,2- dioxaphospholanes and 2-polyfluoroalkoxy-1,3,2-dioxaphosphinanes in 48-72% yield. The products were found to exist as mixtures of cis and trans isomers with the trans isomer predominating for the phospholanes and cis isomer predominating for the phosphinanes according to the H-1, C-13, F-19, and P-31 NMR data.
• ELECTROLYTE ADDITIVE AND ELECTROLYTE INCLUDING SAME AND LITHIUM RECHARGEABLE BATTERY INCLUDING ELECTROLYTE
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20140178748A1

  公开（公告）日：2014-06-26

  Disclosed is an electrolyte additive represented by the following Chemical Formula 1, and an electrolyte for a rechargeable lithium battery including the electrolyte additive, and a rechargeable lithium battery including the electrolyte. In Chemical Formula 1, R 1 to R 4 are the same as defined in the detailed description.
• Electrolyte additive and electrolyte including same and lithium rechargeble battery including electrolyte
  申请人：Samsung SDI Co., Ltd.

  公开号：EP2746288A1

  公开（公告）日：2014-06-25

  Disclosed is an electrolyte additive represented by the following Chemical Formula 1, and an electrolyte for a rechargeable lithium battery including the electrolyte additive, and a rechargeable lithium battery including the electrolyte. In Chemical Formula 1, R1 to R4 are the same as defined in the detailed description.

  公开了一种由以下化学式1表示的电解质添加剂，以及包括该电解质添加剂的可充电锂电池的电解质，以及包括该电解质的可充电锂电池。在化学式1中，R1至R4的定义与详细说明中的相同。