2,2-dichlorohexamethylcyclotetrasiloxane | 100652-24-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 2,2-dichlorohexamethylcyclotetrasiloxane
• 英文别名: 2,2-Dichloro-4,4,6,6,8,8-hexamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane
• CAS: 100652-24-2
• 化学式: C₆H₁₈Cl₂O₄Si₄
• 分子量: 337.455
• InChiKey: IQHOKDGXXUWHJZ-UHFFFAOYSA-N

物化性质

• 沸点：
  80-90 °C(Press: 10 Torr)
• 密度：
  1.1117 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.09
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,2-dichlorohexamethylcyclotetrasiloxane 在 氨基甲酸铵 、 sodium chloride 作用下， 以 乙醚 为溶剂， 以88%的产率得到4,4,6,6,8,8-Hexamethyl-[1,3,5,7,2,4,6,8]tetroxatetrasilocane-2,2-diol
  参考文献：
  名称：

  2,2-Dihydroxy-methylcyclosiloxanes and other 2,2-difunctional methylcyclosiloxanes

  摘要：

  Starting from 2,2-dichloro-methylcyclosiloxanes [-OSiCl2-(OSiMe2)(n)-] (1a-c) [n: 1, 2, 3] the corresponding 2,2-dihydroxymethylcyclosiloxanes [-OSi(OH)(2)-(OSiMe2)(n)-] (2a-c), the 2,2-dimethoxy-methylcyclosiloxanes [-OSi(OMe)(2)-(OSiMe2)(n)-] (3a-c), the 2,2-difluoro-methylcyclosiloxanes [-OSiF2-(OSiMe2)(n)-] (4a,b) [n: 2, 3], the 2,2-dihydrido-methylcyclosiloxanes [-oSiH(2)-(OSiMe2)(n)-] (5a,b) [n: 2, 3] and two spirosiloxanes [-(OSiMe)(m),-OSi-][-OSi-(OSiMe2)(n)-] (6a,b) [m,n: a: 3, 1; b: 2, 3] have been synthesized and characterized by NMR-, MS and partly by IR spectroscopy. 2a is stable in diluted solution only. 2b forms a crystalline 1:1 adduct with H2O characterized by X-ray analysis as a highly organized tube like structure. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00653-2
• 作为产物：
  描述：

  二[(羟基-二甲基硅烷基)氧基]-二甲基硅烷 在 吡啶 、 四氯化硅 作用下， 以 乙醚 为溶剂， 反应 1.0h， 以66%的产率得到2,2-dichlorohexamethylcyclotetrasiloxane
  参考文献：
  名称：

  2,2-Dihydroxy-methylcyclosiloxanes and other 2,2-difunctional methylcyclosiloxanes

  摘要：

  Starting from 2,2-dichloro-methylcyclosiloxanes [-OSiCl2-(OSiMe2)(n)-] (1a-c) [n: 1, 2, 3] the corresponding 2,2-dihydroxymethylcyclosiloxanes [-OSi(OH)(2)-(OSiMe2)(n)-] (2a-c), the 2,2-dimethoxy-methylcyclosiloxanes [-OSi(OMe)(2)-(OSiMe2)(n)-] (3a-c), the 2,2-difluoro-methylcyclosiloxanes [-OSiF2-(OSiMe2)(n)-] (4a,b) [n: 2, 3], the 2,2-dihydrido-methylcyclosiloxanes [-oSiH(2)-(OSiMe2)(n)-] (5a,b) [n: 2, 3] and two spirosiloxanes [-(OSiMe)(m),-OSi-][-OSi-(OSiMe2)(n)-] (6a,b) [m,n: a: 3, 1; b: 2, 3] have been synthesized and characterized by NMR-, MS and partly by IR spectroscopy. 2a is stable in diluted solution only. 2b forms a crystalline 1:1 adduct with H2O characterized by X-ray analysis as a highly organized tube like structure. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)00653-2

文献信息

• Zachernyuk, A. B.; Burlova, E. A.; Zhdanov, A. A., Journal of general chemistry of the USSR, 1985, vol. 55, # 6, p. 1221 - 1227
  作者：Zachernyuk, A. B.、Burlova, E. A.、Zhdanov, A. A.

  DOI：——

  日期：——
• Zachernyuk, A. B.; Zhdanov, A. A.; Isaev, V. B., Doklady Chemistry, 1987, vol. 295, # 8, p. 338 - 341
  作者：Zachernyuk, A. B.、Zhdanov, A. A.、Isaev, V. B.、Ovchinnikov, Yu. E.、Shklover, V. E.、Struchkov, Yu. T.

  DOI：——

  日期：——
• Chernyshev, E. A.; Mudrova, N. A.; Krasnova, T. L., Journal of general chemistry of the USSR, 1992, vol. 62, # 6.1, p. 1076 - 1081
  作者：Chernyshev, E. A.、Mudrova, N. A.、Krasnova, T. L.、Ushakov, Yu. M.、Petrunin, A. B.、Kuznetsova, M. G.

  DOI：——

  日期：——
• Chernyshev, E. A.; Mudrova, N. A.; Krasnova, T. L., Journal of general chemistry of the USSR, 1990, vol. 60, # 7.2, p. 1494
  作者：Chernyshev, E. A.、Mudrova, N. A.、Krasnova, T. L.、Kuznetsova, M. G.、Turkel'taub, G. N.

  DOI：——

  日期：——
• CHERNYSHEV, E. A.;MUDROVA, N. A.;KRASNOVA, T. L.;KUZNETSOVA, M. G.;TURKEL+, ZH. OBSHCH. XIMII, 60,(1990) N, S. 1674-1675
  作者：CHERNYSHEV, E. A.、MUDROVA, N. A.、KRASNOVA, T. L.、KUZNETSOVA, M. G.、TURKEL+

  DOI：——

  日期：——