Reactors of hydrogen fluoride with metals and metalloids
作者:E.L. Muetterties、J.E. Castle
DOI:10.1016/0022-1902(61)80382-5
日期:1961.3
of liquid hydrogenfluoride with a number of metals, metalloids and refractory materials have been investigated. The reactions with metals proved to be a good route to pure fluorides. The closed-system furnished two unique features: (1) the hydrogen generated in the fluorination maintained a strong reducing atmosphere that permitted isolation of otherwise difficulty obtainable fluorides of lower oxidation