cesium bis(fluorosulfonyl)amides | 15060-34-1

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 碱金属盐
• 英文名称: cesium bis(fluorosulfonyl)amides
• 英文别名: cesium bis(fluorosulfuryl)imide；cesium-di(fluorosulfonyl)amide；cesium bis(fluorosulfonyl)amide；CsFSA；Cs[N(SO2F)2]；cesium;bis(fluorosulfonyl)azanide
• CAS: 15060-34-1
• 化学式: Cs*F₂NO₄S₂
• 分子量: 313.039
• InChiKey: DDTHIWHPMUUXTA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.21
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  cesium chloride 、 亚氨基二硫酰氟 以 硝基甲烷 为溶剂， 生成 cesium bis(fluorosulfonyl)amides
  参考文献：
  名称：

  New inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Ternary mixtures of alkali bis(fluorosulfonyl)amides

  摘要：

  Four kinds of ternary phase diagrams of alkali bis(fluorosulfonyl)amides, LiFSA-NaFSA-KFSA, LiFSA-NaFSA-CsFSA, LiFSA-KFSA-CsFSA and NaFSA-KFSA-CsFSA, have been constructed. All the ternary systems possess the only one eutectic point around equimolar composition with the temperature of 309-318 K. The electrochemical window of the eutectic LiFSA-KFSA-CsFSA ((x(Li), X-K, x(Cs))= (0.30, 0.35, 0.35)) is as wide as 5.4V at 323 K with the cathode limit being lithium metal deposition. The electrochemical window of the eutectic NaFSA-KFSA-CsFSA ((x(Na), X-K, x(Cs))= (0.40, 0.25, 0.35)) is 4.9V at 323 K with sodium metal deposition as the cathode limit reaction. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.electacta.2012.01.097

文献信息

• Method for fluorinating a compound comprising a halosulphonyl or dihalophosphonyl group
  申请人：——

  公开号：US20040097757A1

  公开（公告）日：2004-05-20

  The invention relates to a fluorination process for producing fluorinated compounds. The process consists in reacting a compound (I) corresponding to the formula 1 with an ionic fluoride of a monovalent cation. M represents H, an alkali metal, a quaternary phosphonium group or a quaternary ammonium group. Y represents SO 2 and m is 1, or else Y is PO and m is 2. Z represents CR 2 , N or P. R 1 represents an electron-withdrawing group which has a Hammet &sgr; P parameter of greater than 0.4. R 2 represents a carbonaceous and/or electron-withdrawing group. X represents a halogen other than a fluorine. The fluorinated compounds obtained are of use in particular as electrolytes in lithium batteries.

  该发明涉及一种用于生产氟化合物的氟化过程。该过程包括将符合式1的化合物(I)与一价阳离子的离子氟化物发生反应。其中，M代表H、碱金属、季铵磷基团或季铵基团。Y代表SO2，m为1，或者Y为PO，m为2。Z代表CR2、N或P。R1代表一个具有比0.4更大的Hammet &sgr;P参数的吸电子基团。R2代表一个含碳和/或吸电子基团。X代表除氟之外的卤素。所得到的氟化合物特别适用于锂电池中作为电解质。
• A new route to the syntheses of alkali metal bis(fluorosulfuryl)imides: Crystal structure of LiN(SO2F)2
  作者：Martin Beran、Jiří Příhoda、Zdirad Žák、Miloš Černík

  DOI：10.1016/j.poly.2005.09.017

  日期：2006.4

  Abstract A new route for the preparation of Li and Na salts of imido-bis(sulfuric acid) difluoride from KN(SO2F)2 as a starting material is described. KN(SO2F)2 was converted to Li and Na salts by metathetical reactions with lithium and sodium perchlorates in acetonitrile, while Rb and Cs salts were obtained from imido-bis(sulfuric acid) difluoride liberated from its K-salt. The crystal structure of

  摘要描述了一种以KN（SO2F）2为起始原料制备亚氨基双（硫酸）二氟化物锂盐和钠盐的新途径。通过与乙腈中的高氯酸锂和高氯酸钠发生易位反应，将KN（SO2F）2转化为Li和Na盐，而Rb和Cs盐则是从其K盐中释放出来的亚氨基-双（硫酸）二氟化物获得的。确定了双（氟硫磺酰基）酰亚胺锂LiN（SO2F）2（LISFI）的晶体结构。
• New inorganic ionic liquids possessing low melting temperatures and wide electrochemical windows: Ternary mixtures of alkali bis(fluorosulfonyl)amides
  作者：Keigo Kubota、Toshiyuki Nohira、Rika Hagiwara

  DOI：10.1016/j.electacta.2012.01.097

  日期：2012.4

  Four kinds of ternary phase diagrams of alkali bis(fluorosulfonyl)amides, LiFSA-NaFSA-KFSA, LiFSA-NaFSA-CsFSA, LiFSA-KFSA-CsFSA and NaFSA-KFSA-CsFSA, have been constructed. All the ternary systems possess the only one eutectic point around equimolar composition with the temperature of 309-318 K. The electrochemical window of the eutectic LiFSA-KFSA-CsFSA ((x(Li), X-K, x(Cs))= (0.30, 0.35, 0.35)) is as wide as 5.4V at 323 K with the cathode limit being lithium metal deposition. The electrochemical window of the eutectic NaFSA-KFSA-CsFSA ((x(Na), X-K, x(Cs))= (0.40, 0.25, 0.35)) is 4.9V at 323 K with sodium metal deposition as the cathode limit reaction. (C) 2012 Elsevier Ltd. All rights reserved.