Oxidation of magnesium and thallium with bis(η5-cyclopentadienyltricarbonylmolybdenum) in dimethyl sulfoxide and of indium with octacarbonyldicobalt in tetrahydrofuran was studied. The formal-kinetics relationships of the processes were revealed, and the intermediate and final products were identified. The apparent equilibrium constants, enthalpies and entropies of adsorption of reactants on the metal surface, and rate constants and activation energies of the reactions were determined. The reaction scheme was suggested.
研究了在
二甲亚砜中用双(η5-
环戊二烯基三羰基
钼)
氧化镁和
铊以及在
四氢呋喃中用八羰基二
钴氧化
铟。揭示了过程的形式动力学关系,并确定了中间产品和最终产品。测定了反应物在
金属表面上的表观平衡常数、吸附焓和熵,以及反应的速率常数和活化能。提出了反应方案。