n-Butyl(triphenylmethyl)sulfane | 24760-10-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: n-Butyl(triphenylmethyl)sulfane
• 英文别名: S-tritylbutanethiol；Butyl-triphenylmethylsulfid；n-Butyl-tritylsulfid；[Butylsulfanyl(diphenyl)methyl]benzene
• CAS: 24760-10-9
• 化学式: C₂₃H₂₄S
• 分子量: 332.51
• InChiKey: PXOUXKZIXVEYKW-UHFFFAOYSA-N

物化性质

• 沸点：
  435.9±14.0 °C(Predicted)
• 密度：
  1.063±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  三苯甲硫醇 在 二氯化二硫 作用下， 以 乙醚 为溶剂， 反应 72.0h， 生成 n-Butyl(triphenylmethyl)sulfane
  参考文献：
  名称：

  Structure and chemistry of chloro(triphenylmethyl)sulfanes

  摘要：

  The structures of chloro(triphenylmethyl)mono-, di-, and -trisulfanes were obtained. The monosulfane displayed a triclinic (P1) space group, a = 10.792(2) Angstrom, b = 15.090(2) Angstrom, c = 10.027(2) Angstrom, alpha = 100.15(1)degrees, beta 103.13(1)degrees, gamma = 88.80(1)degrees, Z = 4. The disulfane gave a triclinic (P1) space group, a = 9.758(1) Angstrom, b = 10.426(2) Angstrom, c = 9.1691(6) Angstrom, alpha = 97.52(1)degrees, beta = 90.116(1)degrees, gamma = 116.750(1)degrees, Z = 2. The trisulfane gave an orthorhombic space group (Pna2(1)), a = 9.224(1) Angstrom, b = 19.196(3) Angstrom, c = 10.308(1) Angstrom, Z = 4. The sulfenyl chlorides decompose above their melting points to mixtures consisting primarily of triphenylchloromethane and sulfur. The sulfur was determined to consist of several allotropes (S-6, S-7, S-8, and S-9). The di- and trisulfanes slowly decompose to the same products at room temperature; the decompositions are enhanced by light. The decomposition of the trisulfane in the presence of dienes gave adducts consistent with the transfer of a two-sulfur species. The disulfane and trisulfane undergo the normal nucleophilic substitution reactions of the monosulfanes.

  DOI：

  10.1021/jo00083a022

文献信息

• An All‐in‐One Molecule for the One‐Step Synthesis of Functional Hybrid Silica Particles with Tunable Sizes
  作者：Julien Graffion、Dounia Dems、Mesut Demirelli、Thibaud Coradin、Nicolas Delsuc、Carole Aimé

  DOI：10.1002/ejic.201701181

  日期：2017.11.24

  particles with well-defined diameters are obtained by self-assembly of trityl-based molecules. Thanks to the robustness of the organic scaffold, a variety of modifications can be covalently introduced into the network. Using supramolecular chemistry, we show that the synthesis of hybrid small molecules allows engineering nanomaterials with tunable size and functionality.

  通过基于三苯甲基的分子的自组装获得具有明确定义的直径的球形粒子。由于有机支架的坚固性，可以将各种修饰共价引入网络。使用超分子化学，我们表明杂化小分子的合成允许工程纳米材料具有可调的大小和功能。
• The thermal reaction of phenylazotriphenylmethane and naphthylazotriphenylmethane derivatives with sulphur dioxide
  作者：H. Takeuchi、T. Nagai、N. Tokura

  DOI：10.1016/s0040-4020(01)82832-5

  日期：1969.1

  The thermal reaction of phenylazotriphenylmethane, (I), with SO2 in benzene or n-heptane gives triphenylmethyl phenyl sulphone (II) in good yield. This reaction is suppressed by a radical scavenger such as n-butylmercaptan to give n-butyl triphenylmethyl sulphide. The kinetic data obtained from the decomposition of I in liquid SO2 does not differ much from the data in toluene. However, when two crossed

  苯基偶氮三苯基甲烷（I）与SO 2在苯或正庚烷中的热反应可得到高产率的三苯基甲基苯基砜（II）。该反应被自由基清除剂如正丁基硫醇抑制，得到正丁基三苯基甲基硫醚。从液态SO 2中的I分解获得的动力学数据与甲苯数据相差无几。然而，当在每种情况下使用两种化学标记的偶氮化合物进行两个交叉反应时，尽管选择的两个偶氮化合物以大致相同的速率分解，但未观察到各自的交叉化合物。此外，没有形成分子间偶联产物二苯基二砜。这些事实表明II的形成不是4中心型构型或分子间自由基机理，而是由于SO 2的特殊笼形而通过分子内自由基反应。
• Direct evidence for an electron transfer mechanism in the reactions of lithium thioalkoxides with organic substrates
  作者：E.C. Ashby、A.B. Goel、W.S. Park

  DOI：10.1016/s0040-4039(01)82106-7

  日期：——
• ASHBY, E. C.;PARK, W. S.;GOEL, A. B.;SU, WEI-YANG, J. ORG. CHEM., 1985, 50, N 25, 5184-5193
  作者：ASHBY, E. C.、PARK, W. S.、GOEL, A. B.、SU, WEI-YANG

  DOI：——

  日期：——
• Structure and chemistry of chloro(triphenylmethyl)sulfanes
  作者：Charles R. Williams、James F. Britten、David N. Harpp

  DOI：10.1021/jo00083a022

  日期：1994.2

  The structures of chloro(triphenylmethyl)mono-, di-, and -trisulfanes were obtained. The monosulfane displayed a triclinic (P1) space group, a = 10.792(2) Angstrom, b = 15.090(2) Angstrom, c = 10.027(2) Angstrom, alpha = 100.15(1)degrees, beta 103.13(1)degrees, gamma = 88.80(1)degrees, Z = 4. The disulfane gave a triclinic (P1) space group, a = 9.758(1) Angstrom, b = 10.426(2) Angstrom, c = 9.1691(6) Angstrom, alpha = 97.52(1)degrees, beta = 90.116(1)degrees, gamma = 116.750(1)degrees, Z = 2. The trisulfane gave an orthorhombic space group (Pna2(1)), a = 9.224(1) Angstrom, b = 19.196(3) Angstrom, c = 10.308(1) Angstrom, Z = 4. The sulfenyl chlorides decompose above their melting points to mixtures consisting primarily of triphenylchloromethane and sulfur. The sulfur was determined to consist of several allotropes (S-6, S-7, S-8, and S-9). The di- and trisulfanes slowly decompose to the same products at room temperature; the decompositions are enhanced by light. The decomposition of the trisulfane in the presence of dienes gave adducts consistent with the transfer of a two-sulfur species. The disulfane and trisulfane undergo the normal nucleophilic substitution reactions of the monosulfanes.