yttrium(III) chloride hexahydrate | 10025-94-2

• 物质功能分类: 无机化工 - 无机盐 - 金属卤化物及卤酸盐
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: yttrium(III) chloride hexahydrate
• 英文别名: YCl3.6H2O；yttrium(III) chloride hexahyrate；yttrium trichloride hexahydrate；yttrium chloride；yttrium chloride hexahydrate；Yttrium(Iii) Chloride Hydrate；yttrium(3+);trichloride;hydrate
• CAS: 10025-94-2
• 化学式: Cl₃Y*6H₂O
• 分子量: 303.357
• InChiKey: BWOAAAYNOWWMHL-UHFFFAOYSA-K

物化性质

• 熔点：
  100 °C (dec.)(lit.)
• 密度：
  2.18 g/mL at 25 °C(lit.)
• 溶解度：
  极易溶于H2O；溶于乙醇
• 稳定性/保质期：
  溶解度为：217 g/100g H₂O（20℃），235 g/100g H₂O（50℃）。在HCl气流中加热可脱去六个水分子。

计算性质

• 辛醇/水分配系数(LogP)：
  1.24
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 海关编码：
  28469026
• RTECS号：
  ZG3160000
• 储存条件：
  2-8°C

SDS

Name:	Yttrium Chloride Hydrate Material Safety Data Sheet
Synonym:	None
CAS:	10025-94-2

Section 1 - Chemical Product MSDS Name:Yttrium Chloride Hydrate Material Safety Data Sheet
Synonym:None

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
10025-94-2	Yttrium Chloride Hydrate	>99.0	unlisted

Hazard Symbols: None Listed.
Risk Phrases: None Listed.

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Causes severe eye irritation. Causes redness and pain.
Skin:
Causes mild skin irritation. Skin absorption not likely.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion:
Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically and supportively.
Antidote: None reported.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Cool containers with flooding quantities of water until well after fire is out.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

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Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Do not get on skin or in eyes. Avoid ingestion and inhalation.
Storage:
Keep container closed when not in use. Store in a cool, dry, well-ventilated area away from incompatible substances.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Crystalline Solid
Appearance: white to pale yellow
Odor: odorless
pH: 4.5 - 5.8
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 100 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble
Specific Gravity/Density: 2.18 @ 32 F
Molecular Formula: Cl3Y.nH2O
Molecular Weight: 195.2649

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Moisture, strong bases, strong acids, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, irritating and toxic fumes and gases, chlorine.
Hazardous Polymerization: Will not occur.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 10025-94-2: ZG3160000 LD50/LC50:
Not available.
Carcinogenicity:
Yttrium Chloride Hydrate - Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.

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Section 12 - ECOLOGICAL INFORMATION
Other No information available.

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
No information available.
IMO
No information available.
RID/ADR
No information available.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 10025-94-2: No information available.
United Kingdom Occupational Exposure Limits
CAS# 10025-94-2: OES-United Kingdom, TWA (listed as ** undefined
**): 1 mg/m3 TWA
CAS# 10025-94-2: OES-United Kingdom, STEL (listed as ** undefined
**): 3 mg/m3 STEL
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 10025-94-2 is not listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 10025-94-2 (listed as ** undefined **): OEL-AUSTRALIA:TWA 1 mg/m3
US FEDERAL
TSCA
CAS# 10025-94-2 is not listed on the TSCA inventory.
It is for research and development use only.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

制备方法与用途

生产方法： 适量的氧化物溶解于过量的2 mol/L 盐酸中，煮沸以促进进一步浓缩。随后将溶液置于无水硫酸钙干燥器中放置数周，最终析出晶体。

反应信息

• 作为反应物：
  描述：

  yttrium(III) chloride hexahydrate 以 水 为溶剂， 生成 yttrium(III) hydroxide
  参考文献：
  名称：

  通过在氯化物介质中阴极生长的 Y(OH)[sub 3] 热处理合成 Y[sub 2]O[sub 3] 纳米球

  摘要：

  Y 2 O 3 纳米球通过两步法制备，包括在氯化物浴中阴极沉积氢氧化钇薄膜，然后在空气中将氢氧化物热转化为结晶 Y 2 O 3 。通过施加 2 mA cm -2 的阴极电流密度，通过恒电流合成获得 Y(OH) 3 纳米球在钢基材上的粘附和致密薄膜的最佳条件。通过扫描电子显微镜和透射电子显微镜 (TEM) 方法以及 X 射线衍射检查沉积和热处理材料的形貌和结构。拉曼和傅立叶变换红外光谱用于进一步表征氧化物样品。为了研究脱水和分解行为，样品的热分析是通过差示扫描量热法和热重分析法进行的。获得的氧化物包含直径接近 500 nm 的较大的单分散球体。TEM 显示这些由平均粒径为 50 nm 的较小纳米颗粒组成。

  DOI：

  10.1149/1.3469574
• 作为产物：
  描述：

  yttrium(III) oxide 在 盐酸 作用下， 以 盐酸 为溶剂， 生成 yttrium(III) chloride hexahydrate
  参考文献：
  名称：

  The yttrium ion as a template in the synthesis of the macrocyclic and acyclic complexes formed in the reactions with 2,6-diacetylpyridine and hydrazine

  摘要：

  DOI：

  10.1016/s0277-5387(00)81143-2

文献信息

• Preparation and characterisation of dithiophosphinato-complexes of yttrium and the lanthanoids
  作者：A. Alan Pinkerton、Yisay Meseri、Charly Rieder

  DOI：10.1039/dt9780000085

  日期：——

  Hydrated lanthanoid(III) chlorides react with salts of dithiophosphinic acids in hot ethanolic solution to form the corresponding neutral tris or anionic tetrakis complexes, [Ln(S2PR2)3](R = C6H11) and [Ln(S2PR2)4]–(R = Me, OEt, or C6H11) respectively. The product of the reaction is sterically controlled. Displacement reactions with PPh3O to give mixed complexes are described. The characterisation, structures

  水合镧系元素（III）的氯化物与二硫代次膦酸盐在热乙醇溶液中反应，形成相应的中性三或阴离子四环配合物[Ln（S 2 PR 2）3 ]（R = C 6 H 11）和[Ln（S 2 PR 2）4 ] –（R = Me，OEt或C 6 H 11）。反应产物在空间上受到控制。PPh 3的置换反应描述了给出混合配合物的O。讨论了所有分离的配合物的表征，结构和光谱性质。将镧系元素-硫键与过渡金属-硫键进行比较
• Complexes of lanthanides with trioctylphosphine oxide and tributylphosphine oxide
  作者：V.K. Manchanda、Keshav Chander、N.P. Singh、G.M. Nair

  DOI：10.1016/0022-1902(77)80260-1

  日期：1977.1

  Several complexes of lanthanide nitrates, chlorides and thiocyanates with trioctylphosphine oxide and tributylphosphine oxide were prepared by solvent extraction method. An attempt was made to characterize them by IR and thermoanalytical studies. Nitrate groups in these complexes were found to be covalently bonded. These complexes were found to be converted to their corresponding metaphosphates on

  通过溶剂萃取法制备了硝酸镧，氯化物和硫氰酸镧与三辛基氧化膦和三丁基氧化膦的几种配合物。尝试通过IR和热分析研究来表征它们。发现这些复合物中的硝酸根基团是共价键合的。发现这些配合物在加热至1000℃时转化为它们相应的偏磷酸盐。
• Fullerides: heterometallic superconductors with composition M2M′C60 (M = K, Rb; M′ = Yb, Lu, Sc)
  作者：B. M. Bulychev、R. A. Lunin、V. A. Kul’bachinskii、R. V. Shpanchenko、V. I. Privalov

  DOI：10.1007/s11172-005-0018-9

  日期：2004.8

  K, Rb; k = 3—6) and K6C60 + m K mixtures (m = 1, 3) with anhydrous salts M′Cl3 (M′ = La, Pr, Nd, Sm, Gd, Tb, Yb, Lu, Y, Sc) and YbI2 in a toluene—THF medium afforded heterometallic fullerides M3–nM′nC60 (n = 1—3). Among these compounds, substituted fullerides with composition M2M′C60 (M′ = Yb, Lu, Sc) display superconducting properties with critical temperatures of 14—20 K.

  具有 MkC60 (M = K, Rb; k = 3-6) 和 K6C60 + m K 混合物 (m = 1, 3) 的钾和富勒酸铷的一步或两步反应与无水盐 M'Cl3 (M' = La、Pr、Nd、Sm、Gd、Tb、Yb、Lu、Y、Sc）和 YbI2 在甲苯-THF 介质中提供异金属富勒化物 M3-nM'nC60（n = 1-3）。在这些化合物中，组成为 M2M'C60 (M' = Yb, Lu, Sc) 的取代富勒烯显示出临界温度为 14-20 K 的超导特性。
• The thermal decomposition of the 5,7-dihalo-8-quinolinol rare earth metal chelates
  作者：Wesley W. Wendlandt

  DOI：10.1016/s0003-2670(00)87061-0

  日期：——

  5,7-dibromo- and 5,7-duodo-8-quinohnol chelates of lanthanum, cerium, praseodymium, neodymium, samarium and yttrium was investigated on the thermobalance. The chelates decomposed in the temperature range from 65 to 125°C while the oxide levels were obtained from 395 to 805°C Although the chelate thermal stability temperatures varied little with the chelating agent, the minimum oxide level temperatures

  摘要 在热天平上研究了镧、铈、镨、钕、钐和钇的5,7-二氯-、5,7-二溴-和5,7-二氢-8-醌醇螯合物的热分解。螯合物在 65 到 125°C 的温度范围内分解，而氧化物水平在 395 到 805°C 之间获得 虽然螯合物的热稳定性温度随螯合剂变化很小，但最低氧化物水平温度在很大程度上取决于卤素取代在 8-羟基喹啉分子上。这项研究的结果与之前对稀土金属氯化物与 8-羟基喹啉和 2-甲基-8-羟基喹啉的研究相关。
• Fine-tuning of lanthanide-monocarboxylate coordination networks through ligand decoration
  作者：Zeeshan Majeed、George E. Kostakis、Yanhua Lan、Annie K. Powell

  DOI：10.1039/c1dt10917k

  日期：——

  We report herein five new coordination polymers of general formula [LnNa(C6H5CO2)4] where Ln = Y (6), Tb (7), Er (8), [DyNa(CH3CO2)4(MeOH)] (9) and [DyNa(C3H7CO2)4] (10). Single crystal structure analyses revealed that all compounds have a repeating unit containing one Ln3+, one Na+ and four monocarboxylate ligands (RCO2−) (R = –CH3, –C3H7, –C6H5). Compounds 6–8 and 10 possess helical polymeric structures which are extended in three dimensions forming chiral srs networks whilst compound 9 constitutes a two dimensional honeycomb network, illustrating that variation in the alkyl group of the monocarboxylate can result in versatile and variable polymeric networks. The magnetic properties of the reported compounds have also been studied.

  本文报道了五种新的配合物聚合物，通式为[LnNa(C6H5CO2)4]，其中Ln = Y (6), Tb (7), Er (8), [DyNa(CH3CO2)4(MeOH)] (9) 和 [DyNa(C3H7CO2)4] (10)。单晶结构分析显示，所有化合物均含有一个Ln3+、一个Na+和四个单羧酸盐配体（RCO2−）（R = –CH3, –C3H7, –C6H5）的重复单元。化合物6-8和10具有螺旋聚合物结构，这些结构在三维空间中延伸，形成手性的srs网络，而化合物9构成一个二维蜂窝状网络，说明单羧酸盐的烷基团变化可导致多种多样的聚合物网络。此外，还研究了所报道化合物的磁性质。