(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)2SnBr2 | 96325-97-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)2SnBr2
• CAS: 96325-97-2
• 化学式: C₁₆H₈Br₂F₂₆Sn
• 分子量: 972.716
• InChiKey: UYVNLNCASUHUMK-UHFFFAOYSA-L

物化性质

• 熔点：
  54-57 °C(Solv: hexane (110-54-3))
• 沸点：
  360.5±52.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  11.48
• 重原子数：
  45
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  26

反应信息

• 作为反应物：
  描述：

  (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)2SnBr2 在 2,2'-联吡啶 作用下， 以 乙醚 为溶剂， 以>99的产率得到(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)2SnBr2(bipyridyl)
  参考文献：
  名称：

  Synthesis, Characterisation and Anti-Tumour Activity of Bis(Polyfluoroalkyl)Tin Dihalides

  摘要：

  AbstractThe synthesis and characterisation of fifteen new organotin compounds containing at least two CF3(CF2)5CH2‐CH2 groups bound to tin are described. The activity of six of these compounds towards the murine P388 lymphocytic leukaemia tumour is given.

  DOI：

  10.1002/bscb.19840931209
• 作为产物：
  描述：

  1-碘-1H,1H,2H,2H-全氟辛烷 在 Mg 作用下， 以 四氢呋喃 、 四氯化碳 、 乙醚 为溶剂， 生成 (3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctyl)2SnBr2
  参考文献：
  名称：

  Synthesis and characterization of fluoroalkyldistannoxanes

  摘要：

  1.3-Disubstituted tetrakis(fluoroalkyl)distannoxanes (XRf(2)SnOSnRf(2)Y)(2) (Rf = C6F13C2H4, C4F9C2H4; X, Y = Cl, Br, NCS) were synthesized from readily available dibenzyltin dibromide. The dimeric formulation of these compounds that was confirmed by Sn-119-NMR spectra gave rise to a structure in which the metalloxane core is covered by the surface fluorophilic alkyl groups. Thus. these compounds exhibited high solubility in fluorocarbon solvents and large partition coefficients for FC-72 against common organic solvent. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(01)01398-5

文献信息

• A Practical and Green Chemical Process: Fluoroalkyldistannoxane-Catalyzed Biphasic Transesterification
  作者：Jiannan Xiang、Shinji Toyoshima、Akihiro Orita、Junzo Otera

  DOI：10.1002/1521-3773(20011001)40:19<3670::aid-anie3670>3.0.co;2-9

  日期：2001.10.1
• DE, CLERCQ, L.;WILLEM, R.;GIELEN, M.;ATASSI, G., BULL. SOC. CHIM. BELG., 1984, 93, N 12, 1089-1097
  作者：DE, CLERCQ, L.、WILLEM, R.、GIELEN, M.、ATASSI, G.

  DOI：——

  日期：——
• Synthesis and characterization of fluoroalkyldistannoxanes
  作者：Jiannan Xiang、Akihiro Orita、Junzo Otera

  DOI：10.1016/s0022-328x(01)01398-5

  日期：2002.4

  1.3-Disubstituted tetrakis(fluoroalkyl)distannoxanes (XRf(2)SnOSnRf(2)Y)(2) (Rf = C6F13C2H4, C4F9C2H4; X, Y = Cl, Br, NCS) were synthesized from readily available dibenzyltin dibromide. The dimeric formulation of these compounds that was confirmed by Sn-119-NMR spectra gave rise to a structure in which the metalloxane core is covered by the surface fluorophilic alkyl groups. Thus. these compounds exhibited high solubility in fluorocarbon solvents and large partition coefficients for FC-72 against common organic solvent. (C) 2002 Elsevier Science B.V. All rights reserved.
• Synthesis, Characterisation and Anti-Tumour Activity of Bis(Polyfluoroalkyl)Tin Dihalides
  作者：Ludo De Clercq、Rudolph Willem、Marcel Gielen、Ghanem Atassi

  DOI：10.1002/bscb.19840931209

  日期：——

  AbstractThe synthesis and characterisation of fifteen new organotin compounds containing at least two CF3(CF2)5CH2‐CH2 groups bound to tin are described. The activity of six of these compounds towards the murine P388 lymphocytic leukaemia tumour is given.