溴化钨(IV) | 14055-81-3

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 中文名称: 溴化钨(IV)
• 英文名称: tungsten(IV) bromide
• 英文别名: Tungsten, tetrabromo-；tetrabromotungsten
• CAS: 14055-81-3
• 化学式: Br₄W
• 分子量: 503.466
• InChiKey: YXPHMGGSLJFAPL-UHFFFAOYSA-J

物化性质

• 溶解度：
  与H2O反应

计算性质

• 辛醇/水分配系数(LogP)：
  3.38
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  溴化钨(IV) 、 双(三甲基硫化硅) 以 四氢呋喃 为溶剂， 生成 tungsten(IV) sulfide
  参考文献：
  名称：

  Martin, Michael J.; Qiang, Guo-Hua; Schleich, Donald M., Inorganic Chemistry, 1988, vol. 27, # 16, p. 2804 - 2808

  摘要：

  DOI：
• 作为产物：
  描述：

  tungsten(VI) bromide 在 磷化氢 作用下， 反应 0.5h， 生成 溴化钨(IV)
  参考文献：
  名称：

  Cluster Harvesting in the WBr₆–P System

  摘要：

  A combined thermal scanning-X-ray diffraction (XRD) approach was performed for the WBr6-P system to detect and analyze phases in this system, including metal-rich phases generated with increasing amounts of elemental (red) phosphorus under partial PBr3 release. Phases were characterized by powder XRD. A black crystalline powder of W-4(PBr)Br-10 was obtained after reduction of WBr6 with elemental phosphorus at 450 degrees C. The crystal structure of the new compound was found to be isotypic with the structure of W-4(PCl)Cl-10 on the basis of powder XRD data. The structure of W-4(PBr)Br-10 is represented by a cyclobutadiene-like tetranuclear tungsten cluster interconnected into a layered (W-4(mu(4)-PBr)Br6i)Br-8/2(a-a) arrangement via outer bromide ligands. The mu(4)-capping bromophosphinidene ligand was verified by solid-state magic-angle spinning P-31 NMR spectroscopy.

  DOI：

  10.1021/ic502333u

文献信息

• Improved synthetic routes to tungsten(IV) bromide complexes
  作者：Mohammad A. I. Bhuiyan、Willie R. Hargrove、Clyde R. Metz、Peter S. White、Shawn C. Sendlinger

  DOI：10.1007/s11243-015-9954-x

  日期：2015.9

  routes to the compounds WBr4 (1), WBr4(MeCN)2 (2), WBr4(THF)2 (3), WBr4(PPh3)2 (4), WBr4(bpy) (6), and WBr4(dppe) (7) are described via the solution-phase oxidation of W(CO)6 using two equivalents of bromine. These one-pot syntheses use inexpensive and readily available starting materials and produce analytically pure compounds with high yields under mild conditions. Attempts to grow crystals of 1 by heating

  合成化合物 WBr4 (1)、WBr4(MeCN)2 (2)、WBr4(THF)2 (3)、WBr4(PPh3)2 (4)、WBr4(bpy) (6) 和 WBr4(dppe) 的便捷合成路线) (7) 是通过使用两当量的溴对 W(CO)6 进行液相氧化来描述的。这些一锅法合成使用廉价且容易获得的起始材料，并在温和的条件下以高产率生产分析纯的化合物。尝试通过在 ~200 °C 的密封管中加热来生长 1 的晶体导致形成了先前报道的化合物 WOBr4。尝试从二氯甲烷溶液中重结晶 4 产生 [HPPh3]2[WBr6] (5)。X 射线晶体学研究表明，5 由一系列 [WBr6]2- 阴离子和 [HPPh3]+ 阳离子组成，7·CH2Cl2 具有预期的六配位钨中心。通过 W(CO)6 氧化合成溴化钨 (IV) 化合物很简单，并且比以前报道的方法产率更高。与涉及还原 WCl6 的类似氯化钨 (IV)
• Improved synthetic routes to tungsten-nitrido compounds
  作者：Willie R. Hargrove、Shawn C. Sendlinger

  DOI：10.1080/15533174.2015.1137315

  日期：2017.1.2

  Convenient synthetic routes to the compounds WNBr3 and WNBr2(bpy) are described using WBr4 as the starting material. One-pot syntheses using W(CO)6, Br2, (CH3)3SiN3, and 2,2′-bipyridine as inexpensive and readily available starting materials are also described. These one-pot syntheses produce analytically pure compounds in gram quantities with high yields under mild conditions. Use of (CH3)3SiN3 as

  描述了以WBr 4为起始原料合成化合物WNBr 3和WNBr 2（bpy）的简便方法。还描述了使用W（CO）6，Br 2，（CH 3）3 SiN 3和2,2'-联吡啶作为廉价且容易获得的起始原料的一锅合成。这些一锅合成可以在温和的条件下以克的形式高产量地产生分析纯的化合物。使用（CH 3）3 SiN 3作为氮化物源要优于不稳定易爆的IN 3 在以前的钨-氮化化合物的制备中已经使用过。
• Katti, Kattesh V.; Roesky, Herbert W.; Rietzel, Mathias, Inorganic Chemistry, 1987, vol. 26, # 24, p. 4032 - 4035
  作者：Katti, Kattesh V.、Roesky, Herbert W.、Rietzel, Mathias

  DOI：——

  日期：——
• Martin, Michael J.; Qiang, Guo-Hua; Schleich, Donald M., Inorganic Chemistry, 1988, vol. 27, # 16, p. 2804 - 2808
  作者：Martin, Michael J.、Qiang, Guo-Hua、Schleich, Donald M.

  DOI：——

  日期：——
• Cluster Harvesting in the WBr₆–P System
  作者：Markus Ströbele、Klaus Eichele、Hans-Jürgen Meyer

  DOI：10.1021/ic502333u

  日期：2015.2.2

  A combined thermal scanning-X-ray diffraction (XRD) approach was performed for the WBr6-P system to detect and analyze phases in this system, including metal-rich phases generated with increasing amounts of elemental (red) phosphorus under partial PBr3 release. Phases were characterized by powder XRD. A black crystalline powder of W-4(PBr)Br-10 was obtained after reduction of WBr6 with elemental phosphorus at 450 degrees C. The crystal structure of the new compound was found to be isotypic with the structure of W-4(PCl)Cl-10 on the basis of powder XRD data. The structure of W-4(PBr)Br-10 is represented by a cyclobutadiene-like tetranuclear tungsten cluster interconnected into a layered (W-4(mu(4)-PBr)Br6i)Br-8/2(a-a) arrangement via outer bromide ligands. The mu(4)-capping bromophosphinidene ligand was verified by solid-state magic-angle spinning P-31 NMR spectroscopy.