2-(三甲氧基硅烷基)乙硫醇 | 7538-45-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 中文名称: 2-(三甲氧基硅烷基)乙硫醇
• 中文别名: 1,1'-联苯基,3-甲基-4'-硝基-
• 英文名称: trimethoxysilylethanethiol
• 英文别名: trimethoxy(2-sulfanylethyl)silane；2-mercaptoethyl(trimethoxysilane)；2-(Trimethoxysilyl)-ethylmercaptan；β-Trimethoxysilyl-ethylmercaptan；(β-mercaptoethyl)trimethoxysilane；2-trimethoxysilanyl-ethanethiol；2-(trimethoxysilyl)ethanethiol；mercaptoethyl trimethoxysilane；Trimethoxysilyl-ethanthiol；Ethanethiol, 2-(trimethoxysilyl)-；2-trimethoxysilylethanethiol
• CAS: 7538-45-6
• 化学式: C₅H₁₄O₃SSi
• mdl: MFCD01728281
• 分子量: 182.316
• InChiKey: LOSLJXKHQKRRFN-UHFFFAOYSA-N

物化性质

• 沸点：
  195.2±13.0 °C(Predicted)
• 密度：
  1.013±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.82
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  28.7
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-(三甲氧基硅烷基)乙硫醇 生成 3,3,15,15-tetramethoxy-2,16-dioxa-6,9,12-trithia-3,15-disilaheptadecane
  参考文献：
  名称：

  2-(Trialkoxysilylalkylthio)ethyl vinyl sulfides

  摘要：

  DOI：

  10.1007/bf00921523
• 作为产物：
  描述：

  乙烯基三甲氧基硅烷 在 偶氮二异丁腈 、 sodium methylate 作用下， 以 甲醇 为溶剂， 生成 2-(三甲氧基硅烷基)乙硫醇
  参考文献：
  名称：

  Preparation of silylalkanethiols

  摘要：

  DOI：

  10.1021/jo01271a067

文献信息

• Omega -[2-(polyalkyleneoxy)ethylthio]alkylalkoxysilane derivative and preparation method thereof
  申请人：Yoo Ryul Bok

  公开号：US20070043232A1

  公开（公告）日：2007-02-22

  The present invention relates to a ω-[2-(polyalkyleneoxy)ethylthio]alkylalkoxysilane derivative and a preparation method thereof, more particularly to a ω-[2-(polyalkyleneoxy)ethylthio]alkylalkoxysilane derivative prepared by transforming a (ω-mercaptoalkyl)alkylalkoxysilane compound into a ω-(alkoxysilyl)alkylthiolate metal salt by treating it with a metallic base and performing dehalometallation at low reaction temperature using a poly(alkyleneoxy)alkyl ether halide or a poly(alkyleneoxy)bis(haloalkyl) ether to form a carbon-sulfur bond and a preparation method thereof. The novel compound of the present invention has not only a Si—OR bond but also contains a sulfur atom in the molecule, so that it can be used as monomer for synthesizing hydrophilic functional silicon polymers, source material of silicon-based surfactants and surface modifier of organic/inorganic materials. In addition, the preparation method of the compound is an economical one as the reaction can be performed at room temperature, the production yield is high and the reaction byproduct (metal halide) can be easily removed by filtration.

  本发明涉及一种ω-[2-(聚烷氧基)乙硫基]烷基烷氧硅烷衍生物及其制备方法，更特别地，涉及通过将(ω-巯基烷基)烷基烷氧硅烷化合物转化为通过用金属碱处理并在低反应温度下进行脱卤金属化反应，使用聚(烷氧基)烷基醚卤化物或聚(烷氧基)双(卤烷基)醚形成碳硫键的ω-(烷氧硅基)烷基硫酯金属盐的制备方法。本发明的新化合物不仅具有Si—OR键，而且分子中还含有硫原子，因此可用作合成亲水性功能硅聚合物的单体，硅基表面活性剂的原料和有机/无机材料的表面改性剂。此外，该化合物的制备方法是经济的，因为反应可在室温下进行，产量高，反应副产物(金属卤化物)可通过过滤轻松去除。
• (Butylsulfanyl)ethanal and 3-(Organylsulfanyl)butanal 1,1-Dimethylhydrazones
  作者：M. S. Sorokin、V. A. Lopyrev、M. G. Voronkov

  DOI：10.1007/s11176-005-0341-8

  日期：2005.6

  Previously unknown (butylsulfanyl)ethanal and 3-(organylsulfanyl)butanal 1,1-dimethylhydrazones were synthesized. Their reactivity toward methyl iodide was studied.

  合成了以前未知的（丁硫基）乙醛和 3-（斲乙硫基）丁醛 1,1-二甲基肼。研究了它们与碘甲烷的反应性。
• Stabilization of silicates using salts of substituted nitrogen or sulfur
  申请人：Dow Corning Corporation

  公开号：US04344860A1

  公开（公告）日：1982-08-17

  Salts of substituted nitrogen or sulfur containing siliconates are effective stabilizers for aqueous silicates in such applications as treating boiler water, geothermal water and other aqueous silicates. They are also useful in antifreeze and coolant solutions.

  含有取代氮或硫的硅酸盐盐类对水溶性硅酸盐在处理锅炉水、地热水和其他水溶性硅酸盐应用中具有有效的稳定剂作用。它们还可用于防冻剂和冷却剂溶液。
• Vriesea plant named ‘SHADE’
  申请人：Corn Bak B.V.

  公开号：USPP032250P2

  公开（公告）日：2020-09-29

  A new and distinct Vriesea cultivar named ‘SHADE’ is disclosed, characterized by a compound, orange-red bipinnate spike inflorescence and light green foliage. The new variety is a Vriesea , typically produced as an indoor ornamental plant.

  一种新的、独特的Vriesea栽培品种被命名为“SHADE”，其特征为复合的、橙红色的二回羽状穗花序和浅绿色的叶子。这个新品种是一种Vriesea，通常作为室内观赏植物生产。
• Synthesis and some properties of trimethyl(trialkoxy)silylalkyl esters of trivalent arsenic thioacids
  作者：N. A. Chadaeva、K. A. Mamakov、D. A. Iskhakova、G. Kh. Kamai

  DOI：10.1007/bf00922354

  日期：1974.1