A new synthesis and i.r. characterisation of chromium hexafluoride
作者:Eric G. Hope、Peter J. Jones、William Levason、J. Steven Ogden、Mahmoud Tajik
DOI:10.1039/c39840001355
日期:——
A convenient synthesis of CrF6 from CrO3 and F2(170 °C/25 atm/72 h) is described; it is characterized by matrix-isolation i.r. spectroscopy, and using this technique there is wvidence that molecular CrF6 undergoes thermal decomposition to CrF4 at low pressures.
描述了从CrO 3和F 2(170°C / 25 atm / 72 h)方便地合成CrF 6的方法。它的特征在于基体隔离红外光谱,并且使用这种技术可以证明分子CrF 6在低压下会热分解为CrF 4。