Reactions of N,N′-ethylenebis(salicylideneiminato)metal(II) complexes with electrons, halide ions and halogen radicals in gaseous plasmas
作者:G.W. Dillow、I.K. Gregor
DOI:10.1016/s0020-1693(00)90414-6
日期:1989.1
Abstract Results of the gas phase reactions between a series of N , N′ -ethylenebis(salicylideneiminato)metal(II) complexes (metal = Co, Ni, Cu, Zn) and electrons, radicals and negative ions contained in plasmas of the halogenated reagent gases NF 3 , CF 2 Cl 2 and CF 3 Br are presented. Resonance electron capture and nucleophilic addition of a halideion to the metalcomplexes compete as the two primary