申请人:The Lubrizol Corporation
公开号:EP0921136A1
公开(公告)日:1999-06-09
A composition comprising a hydrocarbon polymer having M¯n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently a member of the group of formula -Q-Kk wherein each Q is independently an aliphatic or aromatic hydrocarbon group, each K is independently a member selected from the group consisting of amide groups, nitrile groups, ester groups and carboxylic acid groups, and each k is independently a number ranging from 1 to about 3, and when k ≥ 2, groups -K on adjacent carbon atoms, taken together, may constitute a succinimide group, and a is 0 or a number ranging from 1 to about 50; and each B is independently a member of the group of formula:
wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxyhydrocarbyl, or aminohydrocarbyl, each s is independently 1 or 2, and each Z is independently a hydrocarbyl group, optionally substituted with one or more carboxylic acid groups or amide groups, each Ra is independently an ethylene group, a propylene group, which groups optionally have hydrocarbyl or hydroxyhydrocarbyl substituents, or
wherein J is H, SH, NH2, or OH, and tautomers thereof;
and b is a number ranging from 1 to about 50 with the proviso that when X is O, then b ranges from 2 to about 50.
一种包含烃聚合物的组合物,当该聚合物不是星型聚合物时,其 M¯n 范围为 20,000 至约 500,000 ;当该聚合物是星型聚合物时,其 GPC 峰值分子量可达约 4,000,000 ,该聚合物上附有垂饰基团 Aa 和 Bb,其中每个 A 独立地是式 -Q-Kk 组的成员,其中每个 Q 独立地是脂肪族或芳香族烃基团,每个 K 独立地是选自酰胺基团、腈基团、酯基团和羧酸基团组成的组的成员、每个 K 独立地选自由酰胺基团、腈基团、酯基团和羧酸基团组成的组,且每个 k 独立地为 1 至约 3 的数字,当 k ≥ 2 时,相邻碳原子上的基团 -K 合在一起可构成琥珀酰亚胺基团,且 a 为 0 或 1 至约 50 的数字;每个 B 独立地是式组的成员:
其中每个 X 独立地为 O、S 或 NRb,每个 Rb 独立地为 H、NH2、烃基、羟基烃基或氨基烃基,每个 s 独立地为 1 或 2,每个 Z 独立地为烃基,可选地被一个或多个羧酸基团或酰胺基团取代,每个 Ra 独立地为乙烯基团、丙烯基团,这些基团可选地具有烃基或羟基烃基取代基,或
其中 J 是 H、SH、NH2 或 OH 及其同系物;
b 是范围从 1 到约 50 的数字,但当 X 为 O 时,b 的范围为 2 到约 50。