Thorium trichloride | 15123-26-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 锕系盐类
• 英文名称: Thorium trichloride
• 英文别名: trichlorothorium
• CAS: 15123-26-9
• 化学式: Cl₃Th
• 分子量: 338.397
• InChiKey: LQPUBIDKGBFLMP-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  2.07
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  钍二氯化物 、 氯化钍 生成 Thorium trichloride
  参考文献：
  名称：

  High‐temperature equilibrium studies of the gaseous thorium chlorides

  摘要：

  High-temperature gaseous equilibria among the species Th, ThCl, ThCl2, and ThCl3 were studied by mass spectrometry over broad temperature ranges; both enthalpy and entropy data were derived by the second law procedure. In addition, the sublimation of ThCl4 was studied by the torsion-effusion method and the thermodynamics of the gaseous tetrachloride were evaluated. Individual bond dissociation energies in ThCl4 fall within the range 489–545 kJ mol−1, and vary with ligand number in a way similar to ThF4. Only ThCl appears to have a significant electronic entropy in the experimental temperature range. For ThCl4 the experimental entropy indicates the likelihood of a regular tetrahedral structure as with ThF4, but unlike the uranium tetrahalides which appear to be distorted tetrahedra. In the mass spectrum of ThCl4, the fragment ions ThCl+3, ThCl+2, and ThCl+ show a larger and more nearly correct temperature dependence than the parent ion ThCl+4. Results are compared with those of other thorium and uranium halides.

  DOI：

  10.1063/1.458335

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Th: MVol., 79, page 254 - 256
  作者：

  DOI：——

  日期：——
• Hayek, E.; Rehnker, T., 1949, vol. 50, p. 161 - 161
  作者：Hayek, E.、Rehnker, T.

  DOI：——

  日期：——