Dichromium tricarbonate | 6449-00-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: Dichromium tricarbonate
• 英文别名: chromium(3+);tricarbonate
• CAS: 6449-00-9
• 化学式: C3Cr2O9
• 分子量: 284.02
• InChiKey: XHFVDZNDZCNTLT-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  -7.35
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  190
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  disodium;carbonate 生成 Dichromium tricarbonate
  参考文献：
  名称：

  LAMBRECHT, WOLFGANG;WILDE, MICHAEL;SPINDLER, HERBERT;MEYE, HORST;SCHWOKOW+

  摘要：

  DOI：

文献信息

• CHROMIUM (III) CARBONATE AND PROCESS FOR PRODUCING THE SAME
  申请人：Kuwano Hiroyuki

  公开号：US20110168051A1

  公开（公告）日：2011-07-14

  The chromium (III) carbonate of the present invention exhibits a light blue color in a solid state. This chromium (III) carbonate has an L* value of 50 to 70, an a* value of −4 to −2, and a b* value of −10 to −7, which are represented by the L*a*b* color system (JIS Z8729). This chromium (III) carbonate is preferably completely dissolved within 30 minutes when the chromium (III) carbonate is added, in an amount corresponding to a Cr content of 1 g, to 1 liter of an aqueous solution of hydrochloric acid having a pH of 0.2 at a temperature of 25° C. This chromium (III) carbonate is preferably obtained by contacting an aqueous solution of carbonate and an aqueous solution containing trivalent chromium at a pH of 6 to 12 under the condition of a reaction liquid temperature of 0° C. or more and less than 50° C. Also, preferably, after production of the chromium (III) carbonate, filtration is performed, and the chromium (III) carbonate is washed with water until the conductivity of the filtrate is 5 mS/cm or less.

  本发明的三价铬碳酸盐在固态下呈现淡蓝色。该三价铬碳酸盐的L*值为50到70，a*值为-4到-2，b*值为-10到-7，这些值由L*a*b*色彩系统（JIS Z8729）表示。当将相当于1克Cr含量的三价铬碳酸盐加入到1升pH为0.2的盐酸水溶液中，在25℃下，最好在30分钟内完全溶解。该三价铬碳酸盐最好是在碳酸盐水溶液和三价铬水溶液在pH为6到12的条件下接触，并在反应液温度为0℃以上但低于50℃的条件下进行制备。此外，最好在制备三价铬碳酸盐后进行过滤，并用水洗涤三价铬碳酸盐，直到过滤液的电导率小于5 mS/cm。
• Chromium (III) carbonate and process for producing the same
  申请人：Kuwano Hiroyuki

  公开号：US08580221B2

  公开（公告）日：2013-11-12

  The chromium (III) carbonate of the present invention exhibits a light blue color in a solid state. This chromium (III) carbonate has an L* value of 50 to 70, an a* value of −4 to −2, and a b* value of −10 to −7, which are represented by the L*a*b* color system (JIS Z8729). This chromium (III) carbonate is preferably completely dissolved within 30 minutes when the chromium (III) carbonate is added, in an amount corresponding to a Cr content of 1 g, to 1 liter of an aqueous solution of hydrochloric acid having a pH of 0.2 at a temperature of 25° C. This chromium (III) carbonate is preferably obtained by contacting an aqueous solution of carbonate and an aqueous solution containing trivalent chromium at a pH of 6 to 12 under the condition of a reaction liquid temperature of 0° C. or more and less than 50° C. Also, preferably, after production of the chromium (III) carbonate, filtration is performed, and the chromium (III) carbonate is washed with water until the conductivity of the filtrate is 5 mS/cm or less.

  本发明的三价铬碳酸盐在固态下呈现淡蓝色。该三价铬碳酸盐在L*a*b*颜色系统（JIS Z8729）下的L*值为50至70，a*值为-4至-2，b*值为-10至-7。当在25℃的pH为0.2的盐酸水溶液中加入相当于1克Cr含量的三价铬碳酸盐，该三价铬碳酸盐最好在30分钟内完全溶解。该三价铬碳酸盐最好是在pH为6至12，反应液温度为0℃或以上但低于50℃的条件下，将碳酸盐水溶液和三价铬水溶液接触而得到的。此外，最好在制备三价铬碳酸盐后进行过滤，并用水冲洗三价铬碳酸盐，直到过滤液的电导率为5mS/cm或以下。
• LAMBRECHT, WOLFGANG;WILDE, MICHAEL;SPINDLER, HERBERT;MEYE, HORST;SCHWOKOW+
  作者：LAMBRECHT, WOLFGANG、WILDE, MICHAEL、SPINDLER, HERBERT、MEYE, HORST、SCHWOKOW+

  DOI：——

  日期：——