piperazinylethyldiethylenetriamine | 114289-18-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: piperazinylethyldiethylenetriamine
• 英文别名: N~1~-(2-Aminoethyl)-N~2~-[1-(piperazin-1-yl)ethyl]ethane-1,2-diamine；N'-[2-(1-piperazin-1-ylethylamino)ethyl]ethane-1,2-diamine
• CAS: 114289-18-8
• 化学式: C₁₀H₂₅N₅
• 分子量: 215.342
• InChiKey: DKQPCHWVNASWNV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.7
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  65.4
• 氢给体数：
  4
• 氢受体数：
  5

文献信息

• Process of preparing linearly-extended polyalkylenepolyamines
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0384766A2

  公开（公告）日：1990-08-29

  Linearly-extended polyalkylenepolyamines, such as linear and branched polyethylenepolyamines, are prepared by contacting a difunctional aliphatic alcohol, such as monoethanolamine, with a reactant amine, such as ethylenediamine, in the presence of a catalyst containing (a) a Group VB metal oxide, (b) a niobium phosphate or tantalum phosphate, wherein the mole ratio of phosphorus to niobium or tantalum is no greater than about 1.3, or (c) mixtures thereof. Included among the linearly-extended polyalkylenepolyamines are alcohol-­extended piperazines, such as N-(2-hydroxyethyl)­piperazine, and amine-extended piperazines, such as N-(2-aminoethyl)piperazine.

  线型延伸的聚亚烷基多胺，如线型和支化的聚亚乙基多胺，是在含有以下物质的催化剂存在下，通过将双官能团脂肪醇，如单乙醇胺，与反应物胺，如乙二胺接触制备的：(a) VB 族金属氧化物；(b) 磷酸铌或磷酸钽，其中磷与铌或钽的摩尔比不大于约 1.3，或 (c) 它们的混合物。线性延伸的聚亚烷基多胺包括醇延伸的哌嗪，如 N-(2-羟乙基)哌嗪和胺延伸的哌嗪，如 N-(2-氨乙基)哌嗪。
• Chemical reaction suppression system
  申请人：UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION

  公开号：EP0506041A2

  公开（公告）日：1992-09-30

  A process for inhibiting chemical reactions of a fluid functionally reactive organic material by mixing it with supercritical fluid ("SCF") or near supercritical fluid, especially carbon dioxide maintained under supercritical fluid conditions. The process includes the ability to restrain a chemical reaction that occurs otherwise between functionally compatible organic molecules by the inclusion of supercritical fluid, particularly CO₂, with the molecules, so that the reaction can be made to occur according to a predetermined but different from normal pattern.

  一种通过与超临界流体（"SCF"）或接近超临界流体，特别是在超临界流体条件下保持的二氧化碳混合，抑制流体功能反应性有机材料化学反应的工艺。该工艺包括通过将超临界流体，特别是 CO₂ 与分子混合，抑制功能相容的有机分子之间发生的化学反应，从而使反应按照预定的但不同于正常的模式进行。
• Expandable films and molded products therefrom
  申请人：THE DEXTER CORPORATION

  公开号：EP0511716A1

  公开（公告）日：1992-11-04

  A thin, tacky, non-pourable film of incompatible in situ-expandable thermoplastic particles and thermosettable matrix resin that contains an essentially uniform density and thickness across the breadth of the film. The in situ-expandable mass is not pourable yet can be easily dispensed in a uniform manner within a mold and thereafter expanded to the dimensions of the mold. Composites and reinforced compositions, as well as methods of molding, are disclosed.

  一种由不相容的原位可膨胀热塑性颗粒和热固性基体树脂组成的薄而粘稠的非有利薄膜，在薄膜的整个宽度上具有基本均匀的密度和厚度。这种可就地膨胀的材料不能浇注，但可以很容易地以均匀的方式分配到模具中，然后膨胀到模具的尺寸。复合材料和增强组合物以及成型方法均已公开。
• Method for preparing 1,2-substituted imidazoline compositions
  申请人：Huntsman Corporation

  公开号：EP0568254A2

  公开（公告）日：1993-11-03

  A 1,2-substituted imidazoline composition is prepared by reacting a polyamine mixture comprising triethylenetetramine or tetraethylenepentamine oligomers with an acidic compound selected from aliphatic monocarboxylic and dicarboxylic acids, and esters and mixtures thereof, at imidazoline reaction temperature and pressure. The polyamine mixture comprises 75 wt% or more of linear triethylenetetramine oligomer or 65 wt% or more of linear tetraethylenepentamine oligomer, and leads to improved yields of the 1,2-substituted imidazoline.

  一种 1,2-取代咪唑啉组合物的制备方法是，在咪唑啉反应温度和压力下，将由三乙烯四胺或四乙烯五胺低聚物组成的多胺混合物与选自脂肪族单羧酸和二羧酸及其酯和混合物的酸性化合物反应。该多胺混合物包括 75 wt% 或更多的线性三乙烯四胺低聚物或 65 wt% 或更多的线性四乙烯五胺低聚物，可提高 1,2-取代咪唑啉的产率。
• Low moisture absorption syntactic foam
  申请人：THE DEXTER CORPORATION

  公开号：EP0588437A1

  公开（公告）日：1994-03-23

  A syntactic foam in the form of a thin uniform sheet that possesses enhanced moisture resistance, which comprises a composite filled with hollow microspheres such as glass in a polymer matrix resin such as an epoxy resin where the resin encapsulates the microspheres and the filled composite at weight equilibrium has less than 15% of the available internal volume of the microspheres occupied by liquid water as determined by the LMA test. The process of making the sheet and composites incorporating the sheet is described.

  一种具有更强防潮性能的均匀薄片状合成泡沫塑料，它包括一种在环氧树脂等聚合物基体树脂中填充了玻璃等中空微球的复合材料，其中树脂包裹着微球，并且根据 LMA 试验的测定，在重量平衡状态下填充的复合材料的微球可用内部体积被液态水占据的比例小于 15%。描述了片材和含有片材的复合材料的制作过程。