1,3,5-tris(2-mercaptoethyl)-1,3,5-triazinane-2,4,6-trione | 37917-44-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 1,3,5-tris(2-mercaptoethyl)-1,3,5-triazinane-2,4,6-trione
• 英文别名: 1,3,5-tris(2-mercaptoethyl)-[1,3,5]-triazine-2,4,6-trione；1,3,5-tris(2-sulfanylethyl)-[1,3,5]-triazine-2,4,6-trione；1,3,5-Triazine-2,4,6(1H,3H,5H)-trione, 1,3,5-tris(2-mercaptoethyl)-；1,3,5-tris(2-sulfanylethyl)-1,3,5-triazinane-2,4,6-trione
• CAS: 37917-44-5
• 化学式: C₉H₁₅N₃O₃S₃
• 分子量: 309.434
• InChiKey: GLUUNQWVPRUADO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  18
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  63.9
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,3,5-tris(2-mercaptoethyl)-1,3,5-triazinane-2,4,6-trione 、 2-nitrocinnamic acid 在 4-二甲氨基吡啶 、 铁粉 、 溶剂黄146 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 作用下， 以 乙醇 、 二氯甲烷 、 水 为溶剂， 反应 5.0h， 生成
  参考文献：
  名称：

  KR2022/52138

  摘要：

  公开号：

文献信息

• Crosslinkable chemical formulation and composite semipermeable membrane made therewith
  申请人：W.L. GORE & ASSOCIATES, INC.

  公开号：EP0160473A2

  公开（公告）日：1985-11-06

  A composite semipermeable membrane comprises: (a) a flexible film of microporous polytetrafluoroethylene or other hydrophobic material having a water vapour transmission rate in excess of 10,000 g/m2 · 24 hours, preferably above 100,000 g/m2 · 24 hours, and an advancing water contact angle exceeding 90 degrees, and (b) a continuous, crosslinked amorphous hydrophilic layer preferably of polyoxyethylene polythioether penetrated to an extent into the face of the hydrophobic layer. The hydrophilic layer provides a composite membrane having a water vapour transmission rate of the complete ensemble comparable to or even exceeding that of the hydrophobic material alone, and simultaneously offering two mechanisms of separation; that imposed by the microporous hydrophobic material and that imposed by the hydrophilic layer, and as such is capable of numerous separation operations. The crosslinkable and crosslinked hydrophilic polyoxyethylene polythioether materials are new chemical formulations.

  复合半透膜包括 (a) 微孔聚四氟乙烯或其他疏水材料的柔性薄膜，其水蒸气透过率超过 10,000 克/平方米-24 小时，最好超过 100,000 克/平方米-24 小时，水接触角超过 90 度，以及 (b) 连续的、交联的无定形亲水层，最好是聚氧乙烯聚硫醚亲水层，并渗透到疏水层的表面。亲水层提供了一种复合膜，其完整组合的水蒸气透过率与单独的疏水材料相当，甚至超过疏水材料，同时提供两种分离机制：微孔疏水材料施加的分离机制和亲水层施加的分离机制，因此能够进行多种分离操作。可交联和交联亲水聚氧乙烯聚硫醚材料是一种新型化学配方。
• Carbodiimide-containing hardening type reactive particles, process for producing the same, and use of the same
  申请人：NISSHINBO INDUSTRIES, INC.

  公开号：EP1344795A2

  公开（公告）日：2003-09-17

  A hardening type reactive particles which contain a carbodiimide compound in such a way to have the reactive performance the carbodiimide group inherently has only in the surface layer section or both surface layer section and inside of the base particle, without deforming shape of the base particle. The hardening type reactive particles each comprising a base particle (A) of thermoplastic resin having a functional group and carbodiimide compound (B) impregnated only in the surface layer section or both surface layer section and inside of the base particle, wherein the base particle (A) and carbodiimide compound (B) are strong bonded to each other by the crosslinking reaction taking place under heating between the functional group in the former and carbodiimide group in the latter, and a process for producing the same.

  一种硬化型活性粒子，它含有碳化二亚胺化合物，使碳化二亚胺基团仅在表层部分或表层部分和基粒内部具有固有的活性性能，而不会使基粒的形状变形。硬化型反应颗粒，包括具有官能团的热塑性树脂基质颗粒（A）和仅浸渍在基质颗粒表层部分或表层部分和内部的碳化二亚胺化合物（B），其中基质颗粒（A）和碳化二亚胺化合物（B）通过前者中的官能团和后者中的碳化二亚胺基团在加热下发生的交联反应彼此牢固地结合在一起，以及生产这种颗粒的工艺。
• COMPOSITE PARTICLE HAVING CARBODIIMIDE RESIN LAYER AND PROCESS FOR PRODUCING THE SAME
  申请人：Nisshinbo Industries, Inc.

  公开号：EP1528077A1

  公开（公告）日：2005-05-04

  A composite particle that can be easily converted to cured particle or half cured particle by the use of carbodiimide resin without changing of the configuration of matrix particle of, for example, a thermoplastic resin, excelling in mechanical and functional characteristics by virtue of the reaction capability inherently possessed by a carbodiimide group. In particular, a composite particle comprising matrix particle (A) having a functional group capable of reacting with a carbodiimide group and carbodiimide resin (B), characterized in that the functional group of the matrix particle (A) couples with the carbodiimide group of the carbodiimide resin (B) and that the composite particle is provided with an outer shell layer of carbodiimide resin (B) having an average thickness diameter (L), defined by the following formula [1], ranging from 0.01 to 20 µm : L = (L2 -L1) /2 [1] wherein L1 represents the average diameter of matrix particle, and L2 represents the average diameter of composite particle.

  一种复合微粒，通过使用碳化二亚胺树脂，可以在不改变热塑性树脂等基质微粒结构的情况下，轻松转化为固化微粒或半固化微粒，凭借碳化二亚胺基团固有的反应能力，具有优异的机械和功能特性。特别是一种复合颗粒，由基质颗粒（A）和碳化二亚胺树脂（B）组成，基质颗粒（A）具有能与碳化二亚胺基团反应的官能团，其特征在于基质颗粒（A）的官能团与碳化二亚胺树脂（B）的碳化二亚胺基团偶联，复合颗粒具有碳化二亚胺树脂（B）的外壳层，外壳层的平均厚度直径（L）由下式[1]定义，范围为 0.01 至 20 µm : L = (L2 -L1) /2 [1] 其中 L1 代表基质颗粒的平均直径，L2 代表复合颗粒的平均直径。
• FLAKY PARTICLES AND PROCESS FOR PRODUCTION THEREOF
  申请人：Nisshinbo Industries, Inc.

  公开号：EP1553124A1

  公开（公告）日：2005-07-13

  Flaky particles which are produced through easy conversion from mother particles by using an organic compound other than monomers having double bonds as the hardening and crosslinking agent and to which at least one mechanical or functional characteristic selected from among reactivity, close adhesion, and tackiness is imparted by the presence of part of the unreacted reactive groups of the organic compound inside and on the particles; and a process for the production of the flaky particles. More specifically, flaky particles composed of mother particles (A) having functional groups and an organic compound (B) which has groups reactive with the functional groups of the particles (A) and is soluble in a solvent, characterized in that at least part of the functional groups of the mother particles (A) and at least part of the reactive groups of the organic compound (B) react with each other to form crosslinks.

  片状颗粒，这种颗粒是通过使用具有双键的单体以外的有机化合物作为硬化剂和交联剂，从母颗粒中通过简易转化生产出来的，并且由于颗粒内部和颗粒上存在有机化合物的部分未反应的反应基团，使颗粒具有从反应性、紧密粘附性和粘性中选出的至少一种机械或功能特性；以及片状颗粒的生产工艺。更具体地说，片状颗粒由具有官能团的母颗粒（A）和具有与颗粒（A）的官能团反应的基团并可溶于溶剂的有机化合物（B）组成，其特征在于母颗粒（A）的至少部分官能团和有机化合物（B）的至少部分反应基团相互反应形成交联。
• FILLER FOR SUBSTRATE AND COMPOSITION FOR USE AS MATERIAL FOR INORGANIC/ORGANIC COMPOSITE SUBSTRATE FORMATION
  申请人：Nisshinbo Industries, Inc.

  公开号：EP1894967A1

  公开（公告）日：2008-03-05

  A filler for substrates which comprises an inorganic substance and a carbodiimide-group-containing organic layer chemically bonded to the surface of the inorganic substance. Examples of the carbodiimide-group-containing organic layer include a layer comprising a carbodiimide-group-containing compound represented by either of the following formulae. Due to the constitution, the filler for substrates can be highly dispersed in a resin for substrates even when added in a high proportion and can give a substrate inhibited from deteriorating in electrical properties, mechanical properties, etc. X1m-Z-A-R1-N=C=Nn-R1-NCO1 X1m-Z-A-R1-N=C=Nn-R1-A-Z-X231 [R1 represents a residue of an isocyanate compound; X1 and X2 each independently represents hydrogen, halogeno, etc.; Z's each independently represents silicon or titanium; A represents an organic group having a valence of 2 or higher containing a bond derived from an isocyanate group; m and 1 each is an integer of 1-3, provided that m+1=4; and n is an integer of 1-100.]

  一种用于基底的填料，包括无机物和与无机物表面化学键合的含碳化二亚胺基团的有机层。含碳化二亚胺基团有机层的例子包括由下列式子中任一式子所代表的含碳化二亚胺基团化合物组成的层。由于这种结构，基材用填料即使以高比例添加，也能高度分散在基材用树脂中，并能获得电性能、机械性能等性能不会劣化的基材。X1m-Z-A-R1-N=C=Nn-R1-NCO1 X1m-Z-A-R1-N=C=Nn-R1-A-Z-X231 [R1 代表异氰酸酯化合物的残余物；X1 和 X2 各自独立地代表氢、卤素等；Z's 各自独立地代表硅或钛；A 代表价数为 2 或更高的有机基团，其中含有从异氰酸酯基团衍生的键；m 和 1 各自为 1-3 的整数，条件是 m+1=4 ；n 为 1-100 的整数。］