n-丁氧基三氯硅烷 | 1825-85-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: n-丁氧基三氯硅烷
• 英文名称: n-butoxytrichlorosilane
• 英文别名: trichloro(butoxy)silane；Butoxy-trichlor-silan；Trichlorsilanol-n-butylether；n-Butoxytrichlorsilan；Trichlor-butoxy-silan；mono-n-butoxy-trichlorosilane；Butyloxy-trichlor-silan；Trichlor-butyloxy-silan；butoxy-trichloro-silane；Trichloro(butyloxy)silane；butoxy(trichloro)silane
• CAS: 1825-85-0
• 化学式: C₄H₉Cl₃OSi
• 分子量: 207.559
• InChiKey: SZZPLIQXDJWGIS-UHFFFAOYSA-N

物化性质

• 熔点：
  150-151 °C
• 沸点：
  87-92 °C(Press: 11 Torr)
• 密度：
  1?+-.0.06 g/cm3(Predicted)
• 保留指数：
  894;900;900

计算性质

• 辛醇/水分配系数(LogP)：
  2.96
• 重原子数：
  9
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  n-丁氧基三氯硅烷 、 异丙基氯化镁 以 四氢呋喃 、 甲苯 为溶剂， 反应 5.0h， 以90%的产率得到1-(triisopropylsilyl)oxybutane
  参考文献：
  名称：

  将大量取代基引入烷氧基氯硅烷的通用方法

  摘要：

  由四氯硅烷和醇原位制备的各种烷氧基三氯硅烷与带有大体积取代基的格利雅试剂如异丙基，仲丁基和环己基的反应，可高收率得到三异丙基，三（仲丁基）和三环己基烷氧基硅烷。的反应Ñ -butoxytrichlorosilane与这些格氏试剂制备三异丙基，三（仲丁基，和三环己基（ -丁基）ñ分别在94％，96％，和92分％的收率丁氧基）硅烷，。甲氧基甲基二氯用相同的格氏试剂反应，得到二异丙基，二（仲丁基-丁基）-和二环己基甲氧基甲基硅烷，产率分别为84％，83％和83％。用格氏试剂对甲氧基二甲基氯硅烷的处理容易地以优异的产率得到异丙基，仲丁基和环己基甲氧基二甲基硅烷。用叔丁基氯化镁对甲氧基二甲基氯硅烷进行类似处理，以62％的收率得到叔丁基甲氧基二甲基硅烷。

  DOI：

  10.1016/j.jorganchem.2005.08.030
• 作为产物：
  描述：

  正硅酸丁酯 在 四氯化硅 作用下， 生成 n-丁氧基三氯硅烷
  参考文献：
  名称：

  311.异构丁氧基硅烷对四氯化硅和氯化氢的稳定性

  摘要：

  DOI：

  10.1039/jr9520001690

文献信息

• Scale-up of single phase axial dispersion coefficients in batch and continuous oscillatory baffled tubes
  作者：Xiongwei Ni、Yann Sommer De Gélicourt、Malcolm H. I. Baird、Nadella V. Rama Rao

  DOI：10.1002/cjce.5450790318

  日期：2001.6

  This note presents the development of a scale-up correlation of single-phase axial dispersion coefficients in both batch and continuous oscillatory baffled flow systems. A hydraulic diameter is introduced to relate axial dispersion coefficients for various baffle geometry, including close-fit and loose-fit baffles, Karr plate and multiperforated plate, and various scales. The significance of this note

  本说明介绍了批量和连续振荡挡流系统中单相轴向色散系数的放大相关性的发展。引入了水力直径来关联各种挡板几何形状的轴向扩散系数，包括紧配合和松配合挡板、Karr 板和多孔板以及各种尺度。本说明的意义在于振荡流装置中的混合特性是线性的。关于一个错误的点 dans cet 文章 une 相关性倾倒 l'extrapolation des 系数 de 分散轴单相 dans les systemes d'ecoulement a chicanes oscillatoire discontinu et continu。Un diametre hydraulique est introduit afin de relier les coefficients dedispersion axise pour differentes geometries de chicanes, dont les chicanes
• Production processes for triorganomonoalkoxysilanes and triorganomonochlorosilanes
  申请人：Bannou Tadashi

  公开号：US20050070730A1

  公开（公告）日：2005-03-31

  A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R 3-(x+y) (R 1 ) x (R 2 ) y Si(OR 3 ) can be produced by reacting a silane of the formula (I) (R 1 ) x (R 2 ) y SiCl 3-(x+y) (OR 3 ) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R 1 )(R 2 )(R 3 )SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R 1 )(R 2 )(R 3 )SiZ 1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R 3-(x+y) (R 1 ) x (R 2 ) y Si(OR 3 ) can be produced when a silane of the formula (XXI) (R 1 ) x (R 2 ) y SiCl 4-(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.

  含有庞大烃基或基团R的硅烷，其具有式(III)R3-(x+y)(R1)x(R2)ySi(OR3)，可通过反应式(I)(R1)x(R2)ySiCl3-(x+y)(OR3)的硅烷与式(II)RMgX的格氏试剂制得。此外，式(XIIa)(R1)(R2)(R3)SiCl的三有机氯硅烷可通过反应式(XIa)(R1)(R2)(R3)SiZ1的三有机硅烷与盐酸制得。再者，当式(XXI)(R1)x(R2)ySiCl4-(x+y)的硅烷与式(XXII)RMgX的格氏试剂反应，并在反应过程中加入并反应酒精或环氧化合物时，可制得式(XXIII)R3-(x+y)(R1)x(R2)ySi(OR3)的三有机单烷氧基硅烷。
• PROCESSES FOR THE PRODUCTION OF TRI-ORGANO-MONOALKOXYSILANES AND PROCESS FOR THE PRODUCTION OF TRI-ORGANO-MONOCHLOROSILANES
  申请人：Bannou Tadashi

  公开号：US20090082585A1

  公开（公告）日：2009-03-26

  A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R 3−(x+y) (R 1 ) x (R 2 ) y Si(OR 3 ) can be produced by reacting a silane of the formula (I) (R 1 ) x (R 2 ) y SiCl 3−(x+y) (OR 3 ) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R 1 )(R 2 )(R 3 )SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R 1 )(R 2 )(R 3 )SiZ 1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R 3−(x+y) (R 1 ) x (R 2 ) y Si(OR 3 ) can be produced when a silane of the formula (XXI) (R 1 ) x (R 2 ) y SiCl 4−(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.

  含有笨重烃基团R的硅烷化合物，其化学式为(III)R3−(x+y)(R1)x(R2)ySi(OR3)，可以通过将化学式为(I)(R1)x(R2)ySiCl3−(x+y)(OR3)的硅烷与化学式为(II)RMgX的格氏试剂反应来制备。此外，可以通过将化学式为(XIa)(R1)(R2)(R3)SiZ1的三元有机硅烷与盐酸反应来制备化学式为(XIIa)(R1)(R2)(R3)SiCl的三元有机氯硅烷。此外，在反应过程中加入醇或环氧化合物，可以通过将化学式为(XXI)(R1)x(R2)ySiCl4−(x+y)的硅烷与化学式为(XXII)RMgX的格氏试剂反应来制备化学式为(XXIII)R3−(x+y)(R1)x(R2)ySi(OR3)的三元有机单烷氧基硅烷。
• Processes for the production of tri-organo-monoalkoxysilanes and process for the production of tri-organo-monochlorosilanes
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：US08163950B2

  公开（公告）日：2012-04-24

  A silane containing a bulky hydrocarbon group or groups R therein and having the formula (III) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced by reacting a silane of the formula (I) (R1)x(R2)ySiCl3−(x+y)(OR3) with a Grignard reagent of the formula (II) RMgX Further, a tri-organo-chlorosilane of the formula (XIIa) (R1)(R2)(R3)SiCl can be produced by reacting a tri-organo-silane of the formula (XIa) (R1)(R2)(R3)SiZ1 with hydrochloric acid. Furthermore, a tri-organo-monoalkoxysilane of the formula (XXIII) R3−(x+y)(R1)x(R2)ySi(OR3) can be produced when a silane of the formula (XXI) (R1)x(R2)ySiCl4−(x+y) is reacted with a Grignard reagent of the formula (XXII) RMgX with addition of and reaction with an alcohol or an epoxy compound during the reaction.

  含有笨重烃基团R的硅烷化合物可以通过将式(I)(R1)x(R2)ySiCl3−(x+y)(OR3)的硅烷化合物与式(II)RMgX的格氏试剂反应产生，其中R3−(x+y)(R1)x(R2)ySi(OR3)的化学式为(III)。此外，可以通过将式(XIa)(R1)(R2)(R3)SiZ1的三元有机硅烷与盐酸反应来产生式(XIIa)(R1)(R2)(R3)SiCl的三元有机氯硅烷。此外，可以在反应期间加入并反应醇或环氧化合物，从而使式(XXI)(R1)x(R2)ySiCl4−(x+y)的硅烷化合物与式(XXII)RMgX的格氏试剂反应并生成式(XXIII)R3−(x+y)(R1)x(R2)ySi(OR3)的三元有机单烷氧硅烷。
• Brune,H.A., Chemische Berichte, 1964, vol. 97, p. 2829 - 2847
  作者：Brune,H.A.

  DOI：——

  日期：——