2,2,5,5-tetramethyl-3-imidazoline-1-oxyl

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑啉类
• 英文名称: 2,2,5,5-tetramethyl-3-imidazoline-1-oxyl
• 化学式: C₇H₁₃N₂O
• 分子量: 141.193
• InChiKey: ABQRHJBTGCWLAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  16.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,2,5,5-四甲基-2,5-二氢吡嗪-1,4-二氧化碳 、 丙酮 生成 2,2,5,5-tetramethyl-3-imidazoline-1-oxyl
  参考文献：
  名称：

  Synthesis of 2,2,5,5-tetramethyl-3-imidazoline-1-oxyl

  摘要：

  Condensation of alpha-(hydroxylamino)-2-methylpropanal with acetone an ammonia afforded 2,2,5,5-tetramethyl-3-imidazoline-1-oxyl, the first member of a series of stable nitroxyl radicals which are derivatives of 3-imidazoline. It was shown that 2,2,5,5-tetramethyl-2,5-dihydropyrazine-1,4-dioxide can reversibly add two molecules of water or ammonia to the nitrone groups.

  DOI：

  10.1007/bf00698954

文献信息

• Synthesis of 2,2,5,5-tetramethyl-3-imidazoline-1-oxyl
  作者：V. A. Reznikov、L. A. Vishnivetskaya、L. B. Volodarskii

  DOI：10.1007/bf00698954

  日期：1993.5

  Condensation of alpha-(hydroxylamino)-2-methylpropanal with acetone an ammonia afforded 2,2,5,5-tetramethyl-3-imidazoline-1-oxyl, the first member of a series of stable nitroxyl radicals which are derivatives of 3-imidazoline. It was shown that 2,2,5,5-tetramethyl-2,5-dihydropyrazine-1,4-dioxide can reversibly add two molecules of water or ammonia to the nitrone groups.