2,5-di-sec-butyl-thiophene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 2,5-di-sec-butyl-thiophene
• 英文别名: 2,5-Di-sec-butyl-thiophen；2,5-Di(butan-2-yl)thiophene；2,5-di(butan-2-yl)thiophene
• 化学式: C₁₂H₂₀S
• 分子量: 196.357
• InChiKey: ARGBFUQGBYZGAZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  噻吩 、 2-丁烯 在 boron fluoride ether 作用下， 生成 2,5-di-sec-butyl-thiophene
  参考文献：
  名称：

  Hydrogen Transfer. IV.¹ Reaction of p-Isobutyltoluene and of p-s-Butyltoluene with Methylcyclohexene

  摘要：

  DOI：

  10.1021/ja01160a038

文献信息

• Organic compound having functional groups different in elimination reactivity at both terminals, organic thin film, organic device and method of producing the same
  申请人：Imada Hiroshi

  公开号：US20070195576A1

  公开（公告）日：2007-08-23

  Provided are a single monomolecular film uniform in film thickness and highly ordered in molecule alignment and its multilayer film, an organic compound allowing production of such films at high reproducibility, an organic device superior in electroconductive properties and a method of producing the same. An organic compound represented by Formula: Si(A 1 )(A 2 )(A 3 )-B—Si(A 4 )(A 5 )(A 6 ) (A 1 to A 6 each represent a hydrogen atom, a halogen atom, an alkoxy group or an alkyl group and satisfy the relationship in elimination reactivity of: A 1 to A 3 >A 4 to A 6 ; and B represents a bivalent organic group), an organic thin film using the compound, and an organic device having the thin film; A method of producing an organic thin film and organic device, comprising a step of forming a single monomolecular film by allowing the silyl group having A 1 to A 3 in the organic compound to react with the substrate surface; a step of removing unreacted organic compounds by using a non-aqueous solvent; and a step of forming an additional monomolecular film of the organic compound by using the unreacted silyl groups present on the film surface side of the monomolecular film obtained as the sites for adsorption reaction.

  提供了一种在薄膜厚度上均匀且分子排列高度有序的单分子膜以及其多层膜，一种有机化合物可在高可重复性下制备这种膜，一种优越于导电性能的有机器件以及其生产方法。一种由化学式表示的有机化合物：Si(A1)(A2)(A3)-B—Si(A4)(A5)(A6)（其中A1到A6分别表示氢原子、卤素原子、烷氧基或烷基，并满足消除反应性的关系：A1到A3>A4到A6；B表示二价有机基），使用该化合物的有机薄膜，以及具有该薄膜的有机器件；一种制备有机薄膜和有机器件的方法，包括以下步骤：通过使具有A1到A3的硅基团与基底表面反应形成单分子膜；使用非水溶剂去除未反应的有机化合物；通过利用单分子膜表面上存在的未反应硅基团作为吸附反应位点形成有机化合物的额外单分子膜。
• SUBSTITUTED THIOPHENE OLIGOMERS AND POLYMERS
  申请人：Whitten David G.

  公开号：US20200245619A1

  公开（公告）日：2020-08-06

  The present disclosure provides an antimicrobial substrate including a substrate and a polythiophene polymer. The polythiophene polymer has a number of repeated monomer units from n is 5-14 or 30 to 120, a number average molecular weight (Mn) from 1,000 to 4,000 or 10,000 to 40,000; and a polydispersity index (PDI) from 1 to 1.3. The present disclosure also provides the polythiophene polymer and uses thereof.

  本公开提供了一种抗菌基底，包括一个基底和一个聚噻吩聚合物。该聚噻吩聚合物具有从n为5-14或30至120的重复单体单位数，数均分子量（Mn）从1,000至4,000或10,000至40,000，聚分散指数（PDI）从1至1.3。本公开还提供了该聚噻吩聚合物及其用途。
• Silicon Compound Containi-Electron Conjugated-System Molecule and Process for Producing the Same
  申请人：Nakagawa Masatoshi

  公开号：US20070287848A1

  公开（公告）日：2007-12-13

  A π-electron conjugate molecule-containing silicon compound represented by the formula (I): wherein R1 represents an organic group obtained by combining two or more units constituting plural π-electron conjugate systems, R2 represents a hydrophobic group and X1 to X3, which may be the same or different, respectively represent a group providing a hydroxyl group when it is hydrolyzed or a hydrogen atom.

  一种含有π-电子共轭分子的硅化合物，其化学式表示为(I)：其中，R1代表由构成多个π-电子共轭系统的两个或更多单元组合而成的有机基团，R2代表疏水基团，X1至X3分别可以相同或不同，代表在水解时提供羟基的基团或氢原子。
• Substituted thiophene oligomers and polymers
  申请人：Whitten David G.

  公开号：US11154059B2

  公开（公告）日：2021-10-26

  The present disclosure provides an antimicrobial substrate including a substrate and a polythiophene polymer. The polythiophene polymer has a number of repeated monomer units from n is 5-14 or 30 to 120, a number average molecular weight (Mn) from 1,000 to 4,000 or 10,000 to 40,000; and a polydispersity index (PDI) from 1 to 1.3. The present disclosure also provides the polythiophene polymer and uses thereof.

  本公开提供了一种抗菌基材，包括基材和聚噻吩聚合物。聚噻吩聚合物的重复单体单元数 n 为 5-14 或 30 至 120，平均分子量 (Mn) 为 1,000 至 4,000 或 10,000 至 40,000，多分散指数 (PDI) 为 1 至 1.3。本公开还提供了聚噻吩聚合物及其用途。
• Side Chain-Containing Type Organic Silane Compound, Thin Film Transistor and Method of Producing Thereof
  申请人：Nakagawa Masatoshi

  公开号：US20080303019A1

  公开（公告）日：2008-12-11

  A side chain-containing type organic silane compound represented by the formula (I) R—SiX 1 X 2 X 3 wherein R represents a π-electron conjugate type organic residue composed of 3 to 10 units whose units are a group derived from a monocyclic aromatic hydrocarbon, a group derived from a monocyclic heterocyclic compound or the combination thereof, or an organic residue composed of 2 to 10 five-membered or six-membered rings, both of the residues having at least one side chain and X 1 , X 2 and X 3 , the same or different represent a group affording a hydroxyl group upon hydrolysis.