1,2-bis(dichloromethylsilyl)ethylene

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2-bis(dichloromethylsilyl)ethylene
• 英文别名: Bis(methyldichlorosilyl)ethylene；dichloro-[2-[dichloro(methyl)silyl]ethenyl]-methylsilane
• 化学式: C₄H₈Cl₄Si₂
• 分子量: 254.091
• InChiKey: ASOWGRLKUSLAAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.72
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2-bis(dichloromethylsilyl)ethylene 在 氯 作用下， 反应 4.5h， 以43%的产率得到1,2-Dichloro-1,2-bis-(dichloro-methyl-silanyl)-ethane
  参考文献：
  名称：

  摘要：

  The liquid-phase chlorination of bis(chloromethylsilyl)ethylenes and -acetylenes Me(n)Cl(3-n)SiZ-SiMenCl3-n (n = 0-3; Z = CH=CH, C=C) was studied. Novel carbochlorosilanes were obtained and characterized. The effect of substituents on the activity of the multiple bond of chlorosilylolefins in the reaction studied was determined.

  DOI：

  10.1023/a:1026174517484

文献信息

• ——
  作者：V. G. Lakhtin、V. M. Nosova、A. V. Kisin、P. V. Ivanov、E. A. Chernyshev

  DOI：10.1023/a:1013225112569

  日期：——

  Reactions of a series of 1,2-bis(methylchlorosilyl)ethylenes and -acetylenes Me(n)Cl(3-n)SiZ-SiCl3-nMen (Z = CH=CH, Cequivalent toC; n=0-2) with ethanol and acetoxime were studied. Novel alkoxy- and isopropylideneaminooxysilanes were obtained and characterized. A relation was found between the activity of Si-Cl bonds in the reactions studied and the structure of the carbon-carbon bridge.
• ——
  作者：V. G. Lakhtin、V. D. Sheludyakov、V. M. Nosova、A. V. Kisin、E. A. Chernyshev

  DOI：10.1023/a:1013990617636

  日期：——

  Hydrochlorination of 1,2-bis(silyl)ethylenes of the general formula MenCl3-nSiCH=CHSiMen.Cl3-n where n =0-3, in the presence of FeCl3 was carried out. By NMR spectroscopy it was shown that in the case of the MeCl2Si derivative the major product is 1,1-bis(silyl)chloroethane and the minor product is its isomeric 1,2-bis(silyl)chloroethane (4:1). A reaction scheme is proposed, that includes isomerization of the intermediate bis(silyl)ethyl cation.
• ——
  作者：V. G. Lakhtin、V. D. Sheludyakov、E. A. Chernyshev

  DOI：10.1023/a:1026174517484

  日期：——

  The liquid-phase chlorination of bis(chloromethylsilyl)ethylenes and -acetylenes Me(n)Cl(3-n)SiZ-SiMenCl3-n (n = 0-3; Z = CH=CH, C=C) was studied. Novel carbochlorosilanes were obtained and characterized. The effect of substituents on the activity of the multiple bond of chlorosilylolefins in the reaction studied was determined.