ytterbium antimonide

• 分子结构分类: 无机化合物 - 无机盐 - 无机锑盐
• 英文名称: ytterbium antimonide
• 化学式: Sb₂Yb
• 分子量: 416.54
• InChiKey: AYUKTQBGHTVADE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.37
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  亚锑氢化物 、 iron;stibane 、 ytterbium antimonide 生成
  参考文献：
  名称：

  Synthesis, crystal-structure determination and physical properties of YbFe 4 Sb 12

  摘要：

  A new compound YbFe4Sb12 was synthesized by reaction sintering. It belongs to the family of ternary filled skutterudites. The crystal structure was determined from single crystal X-ray counter data: LaFe4P12-(skutterudite)-type, space group Im (3) over bar-T-h(5) No. 204, Z = 2, a = 0.91571(5) nm; residual values: R-F = 3.0, wR = 6.9, GOF = 1.316. Magnetic susceptibility and magnetization data assisted by Fe-57 Mossbauer and XAS spectra revealed that the compound is a Curie-Weiss paramagnet down to 1.7 K, only due to magnetic moments carried by the Yb atoms exhibiting an intermediate valence state. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0038-1098(98)00556-0
• 作为产物：
  描述：

  亚锑氢化物 、 氢化镱 生成 ytterbium antimonide
  参考文献：
  名称：

  Rustamov, P. G.; Maksudova, T. F.; Aliev, O. M., Russian Journal of Inorganic ChemistryRuss. J. Inorg. Chem. (Transl. of Zh. Neorg. Khim.), 1982, vol. 27, p. 1010 - 1013

  摘要：

  DOI：

文献信息

• Effect of rapid solidification on the synthesis and thermoelectric properties of Yb-filled Co4Sb12 skutterudite
  作者：F. Aversano、S. Branz、E. Bassani、C. Fanciulli、A. Ferrario、S. Boldrini、M. Baricco、A. Castellero

  DOI：10.1016/j.jallcom.2019.04.337

  日期：2019.8

  intermediate step for lowering the total processing time of skutterudites. Sintering of powders obtained from the slowly cooled ingot and rapidly solidified ribbons leads to the formation of massive samples with different densities, depending on the particle size distributions of the starting powders. The effect of Yb content on the thermoelectric properties was critically analysed, considering both data from

  摘要 在这项工作中，评估了不同加工路线对方钴矿笼中 Co4Sb12 相和 Yb 填充物的形成动力学以及热电行为的影响。由于以两个包晶反应为特征的复杂凝固路径，制备的缓慢冷却的锭和快速凝固的带显示出多相的存在。随着凝固速度的增加，晶粒细化得到促进。由于晶界扩散率增加，快速凝固带的退火会导致 Yb 更快地溶解。出于这个原因，快速凝固可以被认为是降低方钴矿总加工时间的有前途的中间步骤。从缓慢冷却的锭和快速凝固的带获得的粉末的烧结导致形成具有不同密度的块状样品，这取决于起始粉末的粒度分布。考虑到来自文献和这项工作的数据，对 Yb 含量对热电性能的影响进行了批判性分析。
• Resistivity and Thermal Expansion (4.2–820 K) of Skutterudites after Severe Plastic Deformation via HPT
  作者：Gerda Rogl、Viktor Soprunyuk、Wilfried Schranz、Michael J. Zehetbauer、Jiri Bursik、Herbert Müller、Ernst Bauer、Peter F. Rogl

  DOI：10.1002/zaac.202000040

  日期：2020.7.31

  temperature‐dependent electrical resistivity and of thermal expansion were compared. It could be shown that for p‐ and n‐type skutterudites, being hot‐pressed and HPT‐processed as well as directly HPT‐processed from compacted powder, these changes occur more or less simultaneously within the same temperature ranges. This evaluation gives a much deeper insight into the thermoelectric behavior of HPT samples under the

  具有高品质因数ZT的热电材料是构建热电发电机的必要基础，该发电机可将热量直接转化为电能。通过高压扭转（HPT）进行的严重塑性变形（SPD）已成功应用于增强球磨和热压方钴矿的ZT以及直接由粉末生产块状纳米结构方钴矿。SPD将许多缺陷引入样品中，与此同时，微晶尺寸也大大减小。在测量引起的加热过程中，这些缺陷会部分退火，晶粒长大。在这项工作中，这是第一次系统地比较了温度依赖性电阻率和热膨胀率的变化。可以证明，对于p型和n型skutterudite，通过热压和HPT加工以及直接从压实粉末进行HPT加工，这些变化或多或少地在相同温度范围内同时发生。该评估可以更深入地了解温度变化影响下的HPT样品的热电行为。
• Enhanced Thermoelectric Performance of Yb-Single-Filled Skutterudite by Ultralow Thermal Conductivity
  作者：Wenjie Li、Jue Wang、Yuantao Xie、Jennifer L. Gray、Jean J. Heremans、Han Byul Kang、Bed Poudel、Scott T. Huxtable、Shashank Priya

  DOI：10.1021/acs.chemmater.8b03994

  日期：2019.2.12

  The filling fraction limitation (FFL) in n-type CoSb3 skutterudites is far below that of p-type (Fe,Co)Sb3-based skutterudites, and it is critical to increase FFL for accomplishing high thermoelectric figure of merit (ZTmax). Here, a series of YbxCo4–yFeySb12 alloys with x = 0.25–0.5 and y = 0.1–0.5 were synthesized, which demonstrate a clear increase of the FFL of Yb from ∼0.3 in CoSb3 to 0.5. Ultralow thermal conductivities of 2.0–2.5 W/m·K at 300 K and 1.75 W/m·K at ∼600 K have been achieved, which are the lowest values reported among skutterudite materials and comparable with p-type skutterudites. These ultralow thermal conductivities result from the combination of secondary phase scattering and phonon scattering from dynamic electron exchange between Fe2+ and Co3+. High ZTmax values of 1.28 at 740 K and 1.34 at 780 K are obtained, which are among the best values reported in the temperature range of 740–800 K. The temperature at which maximum ZTmax appears is shifted below 850 K. These results are highly exciting toward the development of multistage segmented and cascade thermoelectric power generators for in-air operations.

  n 型 CoSb3 硅钙钛矿的填充分数限制（FFL）远低于 p 型（Fe,Co）Sb3 硅钙钛矿的填充分数限制，因此提高填充分数限制对于获得高热电性能（ZTmax）至关重要。本文合成了一系列 x = 0.25-0.5 和 y = 0.1-0.5 的 YbxCo4-yFeySb12 合金，结果表明 Yb 的 FFL 明显从 CoSb3 中的 0.3 增加到 0.5。在 300 K 和 ∼ 600 K 的超低热导率分别为 2.0-2.5 W/m-K 和 1.75 W/m-K，这是目前所报道的矽卡岩材料中的最低值，与 p 型矽卡岩相当。这些超低导热系数是由 Fe2+ 和 Co3+ 之间动态电子交换产生的次相散射和声子散射共同作用的结果。在 740 K 和 780 K 时分别获得了 1.28 和 1.34 的高 ZTmax 值，这是在 740-800 K 温度范围内报告的最佳值之一。
• Effect of quasi-two-dimensional Fermi surfaces on electronic properties in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant="normal">YbSb</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>
  作者：N. Sato、T. Kinokiri、T. Komatsubara、H. Harima

  DOI：10.1103/physrevb.59.4714

  日期：——

  We have measured the electrical resistivity rho(T), magnetization M(H), and the de Haas-van Alphen (dHvA) effect of YbSb2 which is a type-I superconductor having a layerd crystal structure. We have also performed a band structure calculation, and its comparison with observed dHvA signals indicates that there exists a quasi-two-dimensional Fermi surface (FS), reflecting the anisotropic crystal structure. The dHvA effect was also detectable by a commercial SQUID magnetometer, which directly measures M(li) and allows us to determine its absolute value. We have observed an excellent agreement in an amplitude of M(H) with a formula derived from the so-called Lifshitz-Kosevich theory, but a departure in a phase from it. The latter may be ascribed to the two-dimensional nature of the FS. A T-2 law of rho(T) observed at low temperatures has been attributed to phonon scatterings of carriers having the cylindrical FS with a small diameter. [S0163-1829(99)03807-2].
• Rustamov, P. G.; Maksudova, T. F.; Aliev, O. M., Russian Journal of Inorganic ChemistryRuss. J. Inorg. Chem. (Transl. of Zh. Neorg. Khim.), 1982, vol. 27, p. 1010 - 1013
  作者：Rustamov, P. G.、Maksudova, T. F.、Aliev, O. M.

  DOI：——

  日期：——