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tin antimony

中文名称
——
中文别名
——
英文名称
tin antimony
英文别名
——
tin antimony化学式
CAS
——
化学式
SbSn
mdl
——
分子量
240.46
InChiKey
SOSPPDMSZLJFAZ-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    -2.1
  • 重原子数:
    2.0
  • 可旋转键数:
    0.0
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.0
  • 拓扑面积:
    0.0
  • 氢给体数:
    0.0
  • 氢受体数:
    0.0

反应信息

  • 作为反应物:
    描述:
    tin antimony氧气 作用下, 生成
    参考文献:
    名称:
    Boudeulle, M.; Durand, D.; Michel, P., 1970, vol. 7, p. 1 - 7
    摘要:
    DOI:
  • 作为产物:
    描述:
    antimony(III) trioxide 、 tin(II) oxide 在 hydrogen 作用下, 以 neat (no solvent, solid phase) 为溶剂, 生成 tin antimony
    参考文献:
    名称:
    Reductive synthesis of metal antimonides
    摘要:
    A new low temperature synthetic route to binary and ternary metal antimonides is reported. Binary transition metal antimonides prepared include CoSb3, CoSb2, CoSb, NiSb, NiSb2, Cu2Sb and Mo3Sb2; new ternary compositions prepared include the series Co1-xNixSb (0.1 <= x <= 0.9). The intermetallic SnSb has also been prepared by this route. The synthetic method is simple and does not require the use of very high temperatures, multi-step reactions or reaction under vacuum. Compounds were synthesised by the reduction of mixed metal oxides under 10% hydrogen in argon at moderate temperatures (approx. 450 degrees C). The route affords some control over the stoichiometry of the product. High purity binary phases formed include CoSb3, CoSb, NiSb, Cu2Sb and SnSb. Owing to the significantly different reduction temperatures of the starting metal oxides, Mo3Sb2 was formed with impurities of MoO2 and Sb metal. CoSb2 and NiSb2 were formed with impurities of CoSb3 and NiSb2 respectively. (C) 2010 Elsevier B.V. All rights reserved.
    DOI:
    10.1016/j.jallcom.2010.06.078
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文献信息

  • Inexpensive colloidal SnSb nanoalloys as efficient anode materials for lithium- and sodium-ion batteries
    作者:Marc Walter、Simon Doswald、Maksym V. Kovalenko
    DOI:10.1039/c5ta10568d
    日期:——

    The quest for higher energy densities of lithium-ion batteries (LIBs) and emerging sodium-ion analogues (SIBs) has motivated an intense research effort toward novel electrode materials.

    寻求更高能量密度的离子电池(LIBs)和新兴的钠离子类似物(SIBs)的需求,已经激发了对新型电极材料的强烈研究努力。
  • SnSb–ZnO composite materials as high performance anodes for lithium-ion batteries
    作者:Yongliang Li、Wei Zhang、Huihua Cai、Jingwei Wang、Xiangzhong Ren、Peixin Zhang
    DOI:10.1039/c5ra21449a
    日期:——

    The addition of ZnO significantly improved the cycling performance and rate capability of SnSb alloy anode material.

    添加ZnO显著提高了SnSb合负极材料的循环性能和倍率能力。
  • Structural and superconducting analysis of topologically non-trivial alloy of Sn1-xSbx (x=0.4, 0.5, 0.6)
    作者:M.M. Sharma、Prince Sharma、Ganesh Gurjar、S. Patnaik、V.P.S. Awana
    DOI:10.1016/j.jpcs.2021.110136
    日期:2021.9
    In the present article, we report a comprehensive study of structural and physical properties of binary alloy Sn1-xSbx (x = 0.4, 0.5, 0.6). All the alloys are grown through the self-flux method under well-optimized heat treatment. The as-grown crystals are structurally characterized through Powder X-Ray Diffraction (PXRD), Scanning Electron Microscope (SEM), and Energy Dispersive X-Ray Analysis (EDAX)
    在本文中,我们报告了对二元合Sn 1-x Sb x(x = 0.4,0.5,0.6)的结构和物理性能的全面研究。所有合均通过自熔法在优化的热处理条件下生长。生长的晶体通过粉末X射线衍射(PXRD),扫描电子显微镜(SEM)和能量色散X射线分析(EDAX)进行结构表征。同时,使用X射线光电子能谱(XPS)探测晶体的表面。如Rietveld精制的PXRD图所示,所有晶体均以R -3 m空间基团的菱面体结构结晶。1-xx对于x = 0.6的特定合,发现Cr具有一个带有细长晶胞的次级相和一个初级相。这些二元系统被认为是拓扑超导性的可能候选者,因为它们在DFT计算中包括自旋轨道耦合(SOC)协议显示了费米能级附近的频带开放。但是,通过在10 Oe磁场下的场致冷(FC)和零场致冷(ZFC)测量下的直流磁化测量可以确认所有样品中的超导性。通过在2K下的等温磁化(MH)测量来确定观察到的超导性,其中这些二元合被证明是II型超导体。
  • The phase equilibria in the Sb-Sn system – Part II: Experimental results
    作者:Clemens Schmetterer、Julia Polt、Hans Flandorfer
    DOI:10.1016/j.jallcom.2017.11.367
    日期:2018.4
    Abstract Based on results from XRD, SEM/EDX and DTA, a new version of the Sb-Sn phase diagram was established that includes the Sb 3 Sn 4 phase with R 3 ¯ m space group and a commensurately ordered superstructure that can be derived from stacking seven layers of the conventional rhombohedral SbSn cell. The close structural relationships between these two structures have so far caused Sb 3 Sn 4 to be
    摘要 基于 XRD、SEM/EDX 和 DTA 的结果,建立了新版本的 Sb-Sn 相图,其中包括具有 R 3 ¯ m 空间群的 Sb 3 Sn 4 相和相应有序的超结构,可以从堆叠七层常规菱面体 SbSn 电池。迄今为止,这两种结构之间的密切结构关系导致 Sb 3 Sn 4 在大多数工作中被忽视。可以排除 Sb 2 Sn 3 相,该相已在某些相图版本中建立而没有明确的证据或结构描述。现在可以根据第一部分的综合文献综述和当前工作的新数据,以一致的方式解释看似不同的文献结果,第二部分。
  • Ba-filled Ni–Sb–Sn based skutterudites with anomalously high lattice thermal conductivity
    作者:W. Paschinger、G. Rogl、A. Grytsiv、H. Michor、P. R. Heinrich、H. Müller、S. Puchegger、B. Klobes、R. P. Hermann、M. Reinecker、Ch. Eisenmenger-Sitter、P. Broz、E. Bauer、G. Giester、M. Zehetbauer、P. F. Rogl
    DOI:10.1039/c6dt01298a
    日期:——
    the high levels of lattice thermal conductivity. The elastic moduli, collected from Resonant Ultrasonic Spectroscopy ranged from 100 GPa for Ni4Sb8.2Sn3.8 to 116 GPa for Ba0.92Ni4Sb6.7Sn5.3. The thermal expansion coefficients were 11.8 × 10−6 K−1 for Ni4Sb8.2Sn3.8 and 13.8 × 10−6 K−1 for Ba0.92Ni4Sb6.7Sn5.3. The room temperature Vickers hardness values vary within the range from 2.6 GPa to 4.7 GPa. Severe
    新型填充的方矿Ba y Ni 4 Sb 12− x Sn x(y max = 0.93)是通过电弧熔化,然后在真空密封的石英小瓶中于250、350和450°C退火长达30天而制备的。在Ni-Sn-Sb三元系和Ba-Ni-Sb-Sn四元系中的方矿相进行了均质区域的扩展,固相线温度和结构研究。通过电子探针显微分析(EPMA)和X射线粉末衍射(XPD)建立了Ni-Sn-Sb系统在450°C时的相平衡。笼子很小Ni 4(Sb,Sn)12,Ba-Ni-Sn-Sb方矿体系非常适合研究填充原子对声子热导率的影响。使用组成为Ni 4 Sb 8.2 Sn 3.8,Ba 0.42 Ni 4 Sb 8.2 Sn 3.8和Ba 0.92 Ni 4 Sb 6.7 Sn 5.3的单相样品测量其物理性能,即温度相关的电阻率,塞贝克系数和热导率。电阻率数据显示了从属行为到半导体行为的过渡。从塞贝克系数数据中的最大
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