Pulse radiolysis study of I− oxidation with radical anions Cl2
⋅− in an aqueous solution
作者:B. G. Ershov、E. Janata、A. V. Gordeeva
DOI:10.1007/s11172-005-0413-2
日期:2005.6
Radiation-chemical transformations of chloride solutions in the presence of iodide additives were studied by pulseradiolysis. Radicalanion Cl2⋅− oxidize I− ion, while in the secondary reactions Cl2 reacts with I− to form a mixed trihalide ion ICl2−. A reaction model that satisfactorily describes the experimental data was proposed.