triethoxy(2-glycidoxy-1-methylethyl)silane

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: triethoxy(2-glycidoxy-1-methylethyl)silane
• 英文别名: Triethoxy-[2-(oxiran-2-ylmethoxy)propyl]silane
• 化学式: C₁₂H₂₆O₅Si
• 分子量: 278.421
• InChiKey: CFUDQABJYSJIQY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.84
• 重原子数：
  18
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  49.4
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  烯丙基缩水甘油醚 、 三乙氧基硅烷 在 Speier's catalyst 作用下， 反应 1.5h， 以78.9%的产率得到3-缩水甘油醚氧基丙基三乙氧基硅烷
  参考文献：
  名称：

  Hydrosilylation of allyl glycidyl ether with triethoxysilane

  摘要：

  Hydrosilylation of allyl glycidyl ether with triethoxysilane in presence of Speier's catalyst leads to triethoxy(3-glycidoxypropyl)silane and triethoxy(2-glycidoxy-1-methylethyl)silane and is accompanied by isomerization of allyl glycidyl ether and cleavage of the oxirane ring and the ether bond. An effect of admixtures in allyl glycidyl ether on the process is revealed. Some other hydrosilylation catalysts and additives to Speier's catalyst are studied.

  DOI：

  10.1134/s1070363207010082

文献信息

• Hydrosilylation of allyl glycidyl ether with triethoxysilane
  作者：E. A. Chernyshev、Z. V. Belyakova、L. K. Knyazeva、N. N. Khromykh

  DOI：10.1134/s1070363207010082

  日期：2007.1

  Hydrosilylation of allyl glycidyl ether with triethoxysilane in presence of Speier's catalyst leads to triethoxy(3-glycidoxypropyl)silane and triethoxy(2-glycidoxy-1-methylethyl)silane and is accompanied by isomerization of allyl glycidyl ether and cleavage of the oxirane ring and the ether bond. An effect of admixtures in allyl glycidyl ether on the process is revealed. Some other hydrosilylation catalysts and additives to Speier's catalyst are studied.