二丁基-氯-(2-乙氧基乙基)锡烷 | 135905-63-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 二丁基-氯-(2-乙氧基乙基)锡烷
• 英文名称: chloro{2-(ethyloxi)ethyl}dibutylstannane
• 英文别名: 2-ethoxyethyl-dibutyl-tin chloride；Dibutyl(2-ethoxyethyl)stannanylium;chloride
• CAS: 135905-63-4
• 化学式: C₁₂H₂₇ClOSn
• 分子量: 341.509
• InChiKey: GOLOTTWLXQSQGM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.81
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二丁基-氯-(2-乙氧基乙基)锡烷 、 lithium dimethylamide 以 四氢呋喃 为溶剂， 以73%的产率得到二丁基(二甲氨基)(2-乙氧基乙基)锡烷
  参考文献：
  名称：

  A new strategy for the synthesis of homologously pure linear polystannane oligomers

  摘要：

  The reagent 6 is utilized for the stepwise synthesis of linear polystannane oligomers in which hydrostannolysis is employed as the Sn-Sn bond-forming reaction, and DIBAL-H is used to regenerate a new Sn-H functionality for extended chain growth through repetition of the two-step reaction sequence. The electronic spectra of these oligomers are influenced by chain length and the specific placement of substituents, as demonstrated by the homologous series 7, 9, and 13-15 and the phenylated di- and tristannanes 18-20.

  DOI：

  10.1021/om00040a007
• 作为产物：
  描述：

  dibutyltin chloride 、 乙烯基乙醚 以 环己烷 为溶剂， 生成 二丁基-氯-(2-乙氧基乙基)锡烷
  参考文献：
  名称：

  取代的[2-（酰氧基）烷基]二有机锡化合物Bu 2 Sn（X）CH 2 CHR 1 OCOR 2（X卤素2,4-戊二酮酸酯或OCOR）的合成和热分解，有机锡催化剂的潜在来源

  摘要：

  卤代-，（2,4-戊二酮-O，O '）和（酰氧基[2-（酰氧基）乙基]二丁基锡烷，Bu 2 Sn（X）CH 2 CHR 1 OCOR 2（X卤素，2,4-戊二酸酯可以通过乙烯基酯的加氢锡化或苯乙烯基锂化合物与环氧化物的缩合反应再进行酯化反应来制备，这些热不稳定化合物很容易在带有两个杂原子供体的二有机锡化合物中分解。聚氨酯的制备。

  DOI：

  10.1016/0022-328x(93)80143-y

文献信息

• A new strategy for the synthesis of homologously pure linear polystannane oligomers
  作者：Lawrence R. Sita

  DOI：10.1021/om00040a007

  日期：1992.4

  The reagent 6 is utilized for the stepwise synthesis of linear polystannane oligomers in which hydrostannolysis is employed as the Sn-Sn bond-forming reaction, and DIBAL-H is used to regenerate a new Sn-H functionality for extended chain growth through repetition of the two-step reaction sequence. The electronic spectra of these oligomers are influenced by chain length and the specific placement of substituents, as demonstrated by the homologous series 7, 9, and 13-15 and the phenylated di- and tristannanes 18-20.
• Synthesis and thermal decomposition of substituted [2-(acyloxy)alkyl]diorganotin compounds, Bu2Sn(X)CH2 CHR1OCOR2 (X  halogen 2,4-pentanedionate or OCOR), potential sources of organotin catalysts
  作者：B. Jousseaume、V. Guillou、N. Noiret、M. Pereyre、J.-M. Francés

  DOI：10.1016/0022-328x(93)80143-y

  日期：1993.5

  and (acyloxy[2-(acyloxy)ethyl]dibutylstannanes, Bu2Sn(X)CH2CHR1OCOR2 (X  halogen, 2,4- pentanedionate, or OCOR) have been prepared, either by hydrostannation of vinyl esters or by condensation of stannyllithium compounds with epoxides followed by esterification. These thermally unstable compounds are easily decomposed in diorganotin compounds with two heteroatom donors. Some are good catalyst sources

  卤代-，（2,4-戊二酮-O，O '）和（酰氧基[2-（酰氧基）乙基]二丁基锡烷，Bu 2 Sn（X）CH 2 CHR 1 OCOR 2（X卤素，2,4-戊二酸酯可以通过乙烯基酯的加氢锡化或苯乙烯基锂化合物与环氧化物的缩合反应再进行酯化反应来制备，这些热不稳定化合物很容易在带有两个杂原子供体的二有机锡化合物中分解。聚氨酯的制备。