(methyl)(tetrahydrofurfuryl)carbonate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: (methyl)(tetrahydrofurfuryl)carbonate
• 英文别名: Methyl oxolan-2-ylmethyl carbonate
• 化学式: C₇H₁₂O₄
• 分子量: 160.17
• InChiKey: RKAXLIQONKRWGP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  (methyl)(tetrahydrofurfuryl)carbonate 在 二甲基溴化硼 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以83%的产率得到Carbonic acid 5-bromo-2-hydroxy-pentyl ester methyl ester
  参考文献：
  名称：

  Regiocontrolled opening of cyclic ethers using dimethylboron bromide

  摘要：

  DOI：

  10.1021/jo00385a007
• 作为产物：
  描述：

  四氢糠醇 、 碳酸二甲酯 在 trisodium nitrilotriacetate 作用下， 反应 2.0h， 以41%的产率得到(methyl)(tetrahydrofurfuryl)carbonate
  参考文献：
  名称：

  Synthesis of Ditetrahydrofurfuryl Carbonate as a Fuel Additive Catalyzed by Aminopolycarboxylate Ionic Liquids

  摘要：

  A new series of aminopolycarboxylate ionic liquids were designed, synthesized, and applied for efficient and selective synthesis of ditetrahydrofurfuryl carbonate (DTC). Tetraethylammonium nitrilotriacetate ([N-2222](3)[NTA]) was demonstrated to show the best catalytic performance, in which DTC could be obtained at a yield of 80% under optimum conditions.

  DOI：

  10.1007/s10562-017-2043-3

文献信息

• DIESEL FUEL ADDITIVE
  申请人：Hexion Inc.

  公开号：US20160244687A1

  公开（公告）日：2016-08-25

  A diesel fuel and additive mixture is useful for reducing particulate matter emissions while improving or at least not aggravating oxidative stability during combustion. The additive includes at least one compound having a general formula selected from the group consisting of: and combinations thereof, wherein: R is a saturated or unsaturated hydrocarbon having from about 1 to about 6 carbons. The additive is effective in diesel at concentrations as low as from about 50 to about 1000 ppm by weight.
• US8007938B2
  申请人：——

  公开号：US8007938B2

  公开（公告）日：2011-08-30
• US9574152B2
  申请人：——

  公开号：US9574152B2

  公开（公告）日：2017-02-21
• Regiocontrolled opening of cyclic ethers using dimethylboron bromide
  作者：Yvan Guindon、Michel Therien、Yves Girard、Christiane Yoakim

  DOI：10.1021/jo00385a007

  日期：1987.5
• Synthesis of Ditetrahydrofurfuryl Carbonate as a Fuel Additive Catalyzed by Aminopolycarboxylate Ionic Liquids
  作者：Wei Huang、Duan-Jian Tao、Feng-Feng Chen、Wei Hui、Jia Zhu、Yan Zhou

  DOI：10.1007/s10562-017-2043-3

  日期：2017.6

  A new series of aminopolycarboxylate ionic liquids were designed, synthesized, and applied for efficient and selective synthesis of ditetrahydrofurfuryl carbonate (DTC). Tetraethylammonium nitrilotriacetate ([N-2222](3)[NTA]) was demonstrated to show the best catalytic performance, in which DTC could be obtained at a yield of 80% under optimum conditions.