cyclooctadiene cuprous chloride

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: cyclooctadiene cuprous chloride
• 英文别名: CuCl(COD)；copper(1+);cycloocta-1,5-diene;chloride
• 化学式: C₈H₁₂*Cl*Cu
• 分子量: 207.182
• InChiKey: SBXUXUZNRWWHTQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.36
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  cyclooctadiene cuprous chloride 、 sodium methacrylate 以 四氢呋喃 为溶剂， 反应 17.0h， 生成
  参考文献：
  名称：

  Preparation of metal-ion containing polymers: Synthesis and characterization of methacryliccopolymers containing copper ion

  摘要：

  Organic-inorganic hybrid materials have attained great attention due to their complementary properties from each material. Although there have been numerous reports considering the hybrid materials, it is still challenging task to develop easy accessible and versatile method for fabrication of multifunctional organic-inorganic hybrid materials. Herein, we propose novel concept to prepare metal-ion containing polymeric materials. Copper containing copolymers were prepared via radical polymerization of the copper containing monomers with several different monomers. The copper nanoparticles obtained from the direct chemical reduction show the different oxidation and hydroxidation behaviors depending on the degree of interactions for the functional groups in copper containing polymers with oxygen and/or water. Finally, because these copper containing copolymers were shown to be soluble in various organic solvents, we have attempted to produce nanofibers using electrospinning in order to confirm the excellent processability of prepared copper containing polymer. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2015.09.049
• 作为产物：
  描述：

  copper(l) chloride 、 1,5-环辛二烯 在 盐酸 作用下， 以 水 为溶剂， 反应 0.17h， 生成 cyclooctadiene cuprous chloride
  参考文献：
  名称：

  Preparation of metal-ion containing polymers: Synthesis and characterization of methacryliccopolymers containing copper ion

  摘要：

  Organic-inorganic hybrid materials have attained great attention due to their complementary properties from each material. Although there have been numerous reports considering the hybrid materials, it is still challenging task to develop easy accessible and versatile method for fabrication of multifunctional organic-inorganic hybrid materials. Herein, we propose novel concept to prepare metal-ion containing polymeric materials. Copper containing copolymers were prepared via radical polymerization of the copper containing monomers with several different monomers. The copper nanoparticles obtained from the direct chemical reduction show the different oxidation and hydroxidation behaviors depending on the degree of interactions for the functional groups in copper containing polymers with oxygen and/or water. Finally, because these copper containing copolymers were shown to be soluble in various organic solvents, we have attempted to produce nanofibers using electrospinning in order to confirm the excellent processability of prepared copper containing polymer. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2015.09.049

文献信息

• 一种六氟乙酰丙酮-环辛二烯铜（I）的合成方法
  申请人：安徽敦茂新材料科技有限公司

  公开号：CN111808124A

  公开（公告）日：2020-10-23

  本发明提出了一种六氟乙酰丙酮‑环辛二烯铜(I)的合成方法，包括以下步骤：S1、以环辛二烯氯化亚铜、六氟乙酰丙酮钠作为原料进行反应，得到黄色浑浊液；S2、将黄色浑浊液过滤，洗涤，滤液浓缩，粗产品重结晶，得到亮黄色晶体产物。本发明合成简单，反应容易操作，后处理简便，收率高，纯度高，简化了操作流程、减少了污染，容易实现产品的工业化。
• LASER IMAGING
  申请人：DataLase Ltd

  公开号：EP1704057B1

  公开（公告）日：2011-03-30
• Laser Imaging
  申请人：Khan Nazir

  公开号：US20100075848A1

  公开（公告）日：2010-03-25

  An ink formulation comprises a marking component and a metal salt that absorbs laser irradiation at 700-2000 mn and thereby causes the marking component to change colour. A copper salt in particular allows effective marking with a diode or CO 2 laser.
• US8278243B2
  申请人：——

  公开号：US8278243B2

  公开（公告）日：2012-10-02
• [EN] LASER IMAGING<br/>[FR] IMAGERIE AU LASER
  申请人：SHERWOOD TECHNOLOGY LTG

  公开号：WO2005068207A1

  公开（公告）日：2005-07-28

  An ink formulation comprises a marking component and a metal salt that absorbs laser irradiation at 700-2000 mn and thereby causes the marking component to change colour. A copper salt is particular allows effective marking with a diode or C02 laser. I