二氯(去菠二烯)铂(II) | 12152-26-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 二氯(去菠二烯)铂(II)
• 中文别名: 二氯(降冰片二烯)铂(II)；降冰片烯二氯化铂
• 英文名称: dichloro(2,3,5,6-η4-bicyclo{2.2.1}hepta-2,5-dien)platinum(II)
• 英文别名: Pt(norbornadiene)Cl2；(2,5-norbornadiene)PtCl2；dichloro(η-norborna-2,5-diene)platinum(II)；bicyclo[2.2.1]hepta-2,5-diene;platinum(2+);dichloride
• CAS: 12152-26-0
• 化学式: C₇H₈Cl₂Pt
• 分子量: 358.127
• InChiKey: AYGLNRVTDUMGOQ-UHFFFAOYSA-L

物化性质

• 熔点：
  186-218°C (decomposition)

计算性质

• 辛醇/水分配系数(LogP)：
  3.13
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险性防范说明：
  P264,P280,P302+P352,P337+P313,P305+P351+P338,P362+P364,P332+P313
• 危险性描述：
  H315,H319
• 储存条件：
  在室温和惰性气体环境中

SDS

---

Section 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE
Product identifiers
Product name : Dichloro(norbornadiene)platinum(II)
CAS-No. : 12152-26-0

---

Section 2. HAZARDS IDENTIFICATION
Classification of the substance or mixture
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC.
Label elements
Safety data sheet available on request for professional users.
Other hazards - none

---

Section 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substances
Formula : C7H8Cl2Pt
Molecular Weight : 358,12 g/mol

---

Section 4. FIRST AID MEASURES
Description of first aid measures
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
Most important symptoms and effects, both acute and delayed
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Indication of any immediate medical attention and special treatment needed
no data available

---

Section 5. FIREFIGHTING MEASURES
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Carbon oxides, Hydrogen chloride gas
Carbon oxides, Hydrogen chloride gas
Advice for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Further information
no data available

---

Section 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure
adequate ventilation. Avoid breathing dust.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
Methods and materials for containment and cleaning up
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
Reference to other sections
For disposal see section 13.

---

Section 7. HANDLING AND STORAGE
Precautions for safe handling
Avoid formation of dust and aerosols.
Provide appropriate exhaust ventilation at places where dust is formed.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Recommended storage temperature: 2 - 8 °C
Air sensitive. Packaged under inert gas. Handle and store under inert gas.
Specific end uses
no data available

---

Section 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and
at the end of workday.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous
substances, and to the specific work-place., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired,
use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).

---

Section 9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour no data available
c) Odour Threshold no data available
d) pH no data available
e) Melting point/freezing Melting point/range: 186 - 218 °C
point
f) Initial boiling point and no data available
boiling range
g) Flash point not applicable
h) Evaporation rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility no data available
o) Partition coefficient: n- log Pow: 1,810
octanol/water
p) Autoignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Other safety information
no data available

---

Section 10. STABILITY AND REACTIVITY
Reactivity
no data available
Chemical stability
no data available
Possibility of hazardous reactions
no data available
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
Other decomposition products - no data available

---

Section 11. TOXICOLOGICAL INFORMATION
Information on toxicological effects
Acute toxicity
no data available
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
no data available
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been
thoroughly investigated.
Additional Information
RTECS: Not available

---

Section 12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Results of PBT and vPvB assessment
no data available
Other adverse effects
Harmful to aquatic life.
no data available

---

Section 13. DISPOSAL CONSIDERATIONS
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material
with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.
Contaminated packaging
Dispose of as unused product.

---

Section 14. TRANSPORT INFORMATION
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
no data available

---

Section 15. REGULATORY INFORMATION
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
no data available
Chemical Safety Assessment

---

SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  二氯(去菠二烯)铂(II) 在 aniline 、 NEt₃ 作用下， 以 二氯甲烷 为溶剂， 以67%的产率得到[(Pt(endo-5σ,2π-exo-6-phenylamido-bicyclo[2.2.1]hept-2-enyl)Cl)2]
  参考文献：
  名称：

  涉及过渡金属的反应。第十一部分。亲核试剂与二烯铂配合物的反应

  摘要：

  研究了配合物[Pt（二烯）Cl 2 ]（二烯=降冰片二烯或二环戊二烯）与亲核试剂OPr i–，NH 2 Ph，SPh –和SCN –的反应。在每种情况下，二环戊二烯配合物都会受到二烯的攻击，S-亲核试剂也会在铂上产生取代。降冰片二烯配合物和S-亲核试剂仅发生过反应，但OPr i–和NH 2会发现对有机配体的攻击这些产品与中性单齿和双齿配体的反应通常会导致桥裂反应，但在某些情况下，降冰片烯基衍生物会发生重排，变为降冰片烯系统。描述了烯基配合物与其他亲核试剂（OMe –或NHPh –）的反应，以生成双σ键的亚烷基铂配合物。

  DOI：

  10.1039/dt9760002355
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 2,5-降冰片二烯 在 tin(ll) chloride 作用下， 以 水 为溶剂， 生成 二氯(去菠二烯)铂(II)
  参考文献：
  名称：

  A vibrational study of the metal—olefin bond in norbornadiene complexes of Rh(I), Pd(II) and Pt(II)

  摘要：

  DOI：

  10.1016/0584-8539(80)80164-4
• 作为试剂：
  描述：

  2,7-bis(trimethylstannyl)-9,9-dimethylfluorene 在 二氯(去菠二烯)铂(II) 、 1,1'-双(二苯基膦)二茂铁 、 溴 作用下， 以 四氢呋喃 、 二氯甲烷 、 甲苯 为溶剂， 反应 76.0h， 以11%的产率得到C₆₀H₄₈
  参考文献：
  名称：

  EP2484656

  摘要：

  公开号：

文献信息

• Asymmetric hydroformylation catalyzed by homogeneous and polymer-supported platinum complexes containing chiral phosphine ligands
  作者：Giovanni Parrinello、J. K. Stille

  DOI：10.1021/ja00257a036

  日期：1987.11

  Hydroformylation de styrene, isobutyl-4styrene, vinyl-2 et methoxy-6 vinyl-2-naphtalenes, acetate de vinyle, methacrylate de methyle, norbornene, en presence de chlorure stanneux et en presence d'orthoformiate de triethyle

  加氢甲酰化脱苯乙烯、异丁基-4 苯乙烯、乙烯基-2 和甲氧基-6 乙烯基-2-萘、乙酸乙烯酯、甲基丙烯酸酯、降冰片烯、氯化物 stanneux 和三乙基正甲酸酯的存在
• Untersuchungen zum mechanismus der reduktiven photo-eliminierung des biphenyl-systems aus cis-bis(phenyl) platin(II)-verbindungen
  作者：Hans-Albert Brune、Edith Hupfer、Günther Schmidtberg、Andrea Baur

  DOI：10.1016/0022-328x(92)83152-8

  日期：1992.2

  2-bis(diphenylphosphino)benzene), substituents of increasing van der Waals volumes have been introduced into the ortho- or meta-positions of the platinum-bonded phenyl rings in order to influence the relative orientations of these rings with espect to the plane defined by the four valences of the central platinum. The consequences of the different conformations on the photochemical elimination of the biphenyl

  在类型[（η的化合物2 -diphosphine）双（苯基）铂（II）]（二膦= 1,2-双（二苯基膦基）乙烷，顺-1,2-双（二苯基膦基）乙烯，1,2-双（二苯基膦基）苯），范德华体积增加的取代基已引入邻位或间位为了影响这些环相对于由中心铂的四个化合价所定义的平面的相对取向，它们与铂键合的苯环的位置相对应。在结晶和液相中研究了不同构象对从双（苯基）铂化合物光化学消除联苯系统的影响，其结果是，只有当两个苯环都垂直取向（或几乎垂直于铂平面。
• Bis(t-butyl)-dibenzoplatinol-Verbindungen: Ein Beitrag zum Mechanismus der photochemischen Biphenyl-Eliminerung aus Bis(phenyl)platin(II)-Verbindungen
  作者：Robert Hohenadel、Hans-Albert Brune

  DOI：10.1016/0022-328x(88)80364-4

  日期：1988.8

  Syntheses of three compounds are described, in which 4,4′-bis(t-butyl)biphenyl is bonded simultaneously by its 2,2′-carbons to a central platinum viz. 9,9-(2,3,5,6-η4-bicyclo[2.2.1]hepta-2,5-diene)-2,7-bis(t-butyl)dibenzoplatinol (5), 9,9-bis(triphenylphosphane)-2,7-bis(t-butyl)-dibenzoplatinol (6) and 9,9-(η2-2,2′-bipyridin)-2,7-bis(t-butyl)-dibenzoplatinol (7). The connection of the two platinum-bonded

  描述了三种化合物的合成，其中4,4'-双（叔丁基）联苯通过其2,2'-碳同时键合到中心铂上。9,9-（2,3,5,6-η 4 -双环[2.2.1]庚-2,5-二烯）-2,7-二（叔丁基）dibenzoplatinol（5），9,9-双（三苯基膦）-2,7-双（叔-丁基）-dibenzoplatinol（6）和9,9-（η 2 -2,2'-联吡啶）-2,7-二（叔丁基）-dibenzoplatinol（7）。两个与铂键合的苯环的连接相对于铂的配位平面为共面取向。在该取向中的化合物5，6和7是光稳定的；这与双（苯基）铂（II）化合物的可光化性相反，在该化合物中，两个苯环的取向使得它们的平面垂直于配位平面。
• Synthesis, 119Sn, 13C and 195Pt NMR studies of five-coordinate rhodium(I), iridium(I) and platinum(II) complexes containing three trichlorostannate ligands
  作者：M. Kretschmer、P.S. Pregosin、H. Rüegger

  DOI：10.1016/0022-328x(83)80028-x

  日期：1983.1

  five-coordinate tris(trichlorostannato) complexes of RhI, IrI and PtII are reported. The RhI and IrI complexes are complex dianions of the form (PPN)2[M(SnCl3)3L2] where L can be CO, CN (cyclohexyl) or L2, a diolefin such as 1,5-COD or NBD (norbornadiene). The anionic platinum complexes (PPN)[Pt(SnCl3)3L2] contain similar L ligands. A number of neutral monotrichlorostannato complexes of type [M(SnCl3)L4] including

  报道了Rh I，Ir I和Pt II的新的五配位三（三氯三甲基锡）配合物的合成和119 Sn NMR特征。Rh I和Ir I络合物是（PPN）2 [M（SnCl 3）3 L 2 ]形式的络合物，其中L可以是CO，CN（环己基）或L 2，二烯烃，例如1,5 -COD或NBD（降冰片二烯）。阴离子铂络合物（PPN）[Pt（SnCl 3）3 L 2 ]包含相似的L配体。[M（SnCl 3）L型的许多中性一氯三锡锡络合物4 ]，包括物[Ir（的SnCl 3）（NBD）（1,5-COD）]已经制备和表征。它们的δ（119 Sn），δ（13 C），δ（195 Pt）以及1 J（103 Rh，119 Sn），1 J（195 Pt，119 Sn），2 J（119 Sn，117 Sn）给出2 J（119 Sn，13 C）数据。甲反影响系列，基于1 Ĵ（195的Pt，119的Sn），揭示了以下的序列：H -
• Synthesen von Bis(naphthyl)platin(II)-Verbindungen
  作者：Claus Weisemann、Günther Schmidtberg、Hans-Albert Brune

  DOI：10.1016/0022-328x(89)85280-5

  日期：1989.2

  bis(naphthyl)platinum(II) compounds with substituents in the 2- or 4-positions of the naphthyl ligands, (1,2,5,6-η4-cycloocta-1,5-diene)bis(naphth-1-yl)platinum(II), (1,2,5,6-η4-hexa-1,5-diene)bis(naphth-1-yl)platinum(II) (2,3,5,6-η4-bicyclo[2.2.1]hepta-2,5-diene)bis(naphth-1-yl)platinum(II), cis-bis(dimethylsulfoxide)bis-(naphth-1-yl)platinum(II) and cis-bis(naphth-1-yl)bis(triphenylphosphane)platinum(II)

  双（萘基）铂（II）化合物与在萘基配体的2-或4-位的取代基，（1,2,5,6-η 4 -cycloocta -1,5-二烯基）双（萘-1-基）铂（II），（1,2,5,6-η 4 -六-1,5-二烯）双（萘-1-基）铂（II）（2,3,5,6-η 4-双环[2.2.1]庚-2,5-二烯）双（萘-1-基）铂（II），顺式-双（二甲基亚砜）双-（萘-1-基）铂（II）和顺式-双（萘-1-基）双（三苯基膦）铂（II）由有机锡化合物三甲基（萘-1-基）-锡烷或三（正丁基）（萘-1-基）合成锡烷在类似位置具有取代基。