triphenyl-n-butyl phosphonium bromide

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: triphenyl-n-butyl phosphonium bromide
• 英文别名: 4,4,4-Triphenylbutylphosphanium;bromide
• 化学式: BrH*C₂₂H₂₃P
• 分子量: 399.31
• InChiKey: XTPHBWGZLPWPQR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.41
• 重原子数：
  24
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  triphenyl-n-butyl phosphonium bromide 、 正丁醛 以 六甲基磷酰三胺 为溶剂， 生成 辛烯
  参考文献：
  名称：

  Process for preparing cis-olefins

  摘要：

  一种制备式为##STR1##的顺式烯烃的方法，其中R为烷基或烯基，R.sup.1为烷基和烯基，可选择地通过羟基、羰基酯或乙酰氧基取代，该方法包括在六烷基磷酸三胺中的化合物R-CH.sub.2-P.sup.+(C.sub.6H.sub.5).sub.3Br.sup.-的亚胺溶液中，加入式为R.sup.1-CHO的醛。

  公开号：

  US04057593A1

文献信息

• DIFUNCTIONAL (METH)ACRYLATE WRITING MONOMERS
  申请人：Fäcke Thomas

  公开号：US20130252140A1

  公开（公告）日：2013-09-26

  The invention relates to compounds, of formula (I) in which X is CH 3 or hydrogen, Z is a linear or branched C2 to C4 alky radical, R is a linear or branched, optionally heteroatom-substituted aliphatic, aromatic or araliphatic radical, Y in each occurrence is independently hydrogen, methyl, ethyl, propyl, n-butyl, tert-butyl, chlorine, bromine, iodine, methylthio, phenyl or phenylthio, n is from 0 to 4 and m is from 0 to 5. The invention further relates to the use of such a compound as writing monomer in a photopolymer formulation. In addition, a photopolymer formulation comprising as least a polyisocyanate component, a polyol component, a photoinitiator and a compound of formula (I) as writing monomer, and also the use of the photopolymer formulation for producing holographic media, are likewise subjects of the invention.

  本发明涉及公式(I)中的化合物，其中X为CH3或氢，Z为线性或支链的C2到C4烷基基团，R为线性或支链的、可选地含杂原子的脂肪族、芳香族或芳基脂肪族基团，Y在每次出现时独立地为氢、甲基、乙基、丙基、正丁基、叔丁基、氯、溴、碘、甲硫基、苯基或苯硫基，n为0到4，m为0到5。本发明还涉及将该化合物用作光聚物配方中的写入单体的用途。此外，一种光聚物配方包括至少聚异氰酸酯组分、聚醇组分、光引发剂和公式(I)中的化合物作为写入单体，以及使用该光聚物配方制备全息媒体，也是本发明的主题。
• ANTI-FOGGING FILM-FORMING MATERIAL, COATING LIQUID FOR FORMING ANTI-FOGGING FILM, ANTI-FOGGING ARTICLE, AND METHODS FOR PRODUCING THESE
  申请人：Central Glass Co., Ltd.

  公开号：EP2868723A1

  公开（公告）日：2015-05-06

  Disclosed is an antifogging film-forming material obtained by reacting, in the presence of a quaternary ammonium salt or quaternary phosphonium salt, a copolymer represented by a certain general formula with a multifunctional epoxy compound having a solubility of 40-100 mass% in 25°C water. The antifogging film-forming material is characterized by having a weight average molecular weight of 100,000-5,000,000. With this material, it becomes possible to obtain an antifogging article excellent in antifogging property, heat resistance, chemical resistance and abrasion resistance.

  本发明公开了一种防雾成膜材料，它是在季铵盐或季鏻盐的存在下，由一定通式表示的共聚物与在 25°C 水中溶解度为 40-100 质量％的多功能环氧化合物反应而得。这种防雾成膜材料的特点是重量平均分子量在 100,000-5,000,000 之间。有了这种材料，就可以获得防雾性能、耐热性、耐化学性和耐磨性都非常出色的防雾产品。
• NONIMMUNOSUPPRESSIVE CYCLOSPORINE ANALOGUE MOLECULES
  申请人：Isotechnika Pharma Inc.

  公开号：EP2307446A1

  公开（公告）日：2011-04-13
• CYCLOSPORINE ANALOGUE MOLECULES MODIFIED AT AMINO ACID 1 AND 3
  申请人：Isotechnika Pharma Inc.

  公开号：EP2651965A1

  公开（公告）日：2013-10-23
• NOVEL THERMOPLASTIC POLYHYDROXY POLYETHER RESIN AND RESIN COMPOSITION COMPRISING THE SAME
  申请人：Gunji Masao

  公开号：US20100119805A1

  公开（公告）日：2010-05-13

  A novel flame-retardant thermoplastic polyhydroxy polyether resin obtained by reacting at least one epoxy resin (A) selected from glycidyl esters of divalent aliphatic carboxylic acids having 15 to 64 carbon atoms or glycidyl ethers of divalent aliphatic alcohols having 15 to 64 carbon atoms with a phosphorus atom-containing divalent phenol compound (B) as essential components, wherein the component (A) accounts for 2 to 52 mol % with respect to the whole resin, the weight average molecular weight thereof is 10,000 to 200,000, and the phosphorus content thereof is 1 to 5 wt %.