zirconium tetramethoxide

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: zirconium tetramethoxide
• 英文别名: zirconium methoxide；zirconium(IV) methoxide；tetramethoxyzirconium；Tetramethoxyzirkon；Methanolate;zirconium(4+)
• 化学式: C₄H₁₂O₄Zr
• 分子量: 215.361
• InChiKey: IKGXNCHYONXJSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -4.1
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  92.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  硼酸 、 zirconium tetramethoxide 生成
  参考文献：
  名称：

  SIMODA, JOSIYUKI;OTI, JOSIO

  摘要：

  DOI：
• 作为产物：
  描述：

  zirconium(IV) borohydride 在 CH₃OH 作用下， 以 正戊烷 为溶剂， 以99%的产率得到zirconium tetramethoxide
  参考文献：
  名称：

  Petrova, L. A.; Borisov, A. P.; Makhaev, V. D., Koordinatsionnaya Khimiya, 1992, vol. 18, p. 425 - 428

  摘要：

  DOI：

文献信息

• SIMODA, JOSIYUKI;OTI, JOSIO
  作者：SIMODA, JOSIYUKI、OTI, JOSIO

  DOI：——

  日期：——
• Synthesis and CO2 capture evaluation of Li2−xKxZrO3 solid solutions and crystal structure of a new lithium–potassium zirconate phase
  作者：Mayra Y. Veliz-Enriquez、Gonzalo Gonzalez、Heriberto Pfeiffer

  DOI：10.1016/j.jssc.2007.06.023

  日期：2007.9

  Solid Solutions or lithium and potassium metazirconates Li2-xKxZrO3 (where, 0 <= x <= 2) were prepared by coprecipitation. Samples were characterized by powder X-ray diffraction, scanning electron microscopy, and thermogravimetric analyses. Results showed that the solubility limits of potassium into Li2ZrO3 is x = 0.2. Furthermore, at higher potassium concentrations, a new phase was synthesized, Li2.27K1.19Zr2.16O6.05. For structural studies of this new phase, XRD data were analyzed by Rietveld refinements. Additionally, at high potassium concentrations different phases of ZrO2 were found, as potassium tends to sublimate. On the other hand, lithium-potassium rnetazirconate solid solutions, Li2-xKxZrO3, were tested as CO2 captors. Thermal analyses into a CO2 flux showed that Li2-xKxZr2O3 solid solutions present a better CO2 absorption than Li2ZrO3 pure. The differences observed in the CO2 sorption processes were explained with thermodynamic data. (c) 2007 Elsevier Inc. All rights reserved.
• Petrova, L. A.; Borisov, A. P.; Makhaev, V. D., Koordinatsionnaya Khimiya, 1992, vol. 18, p. 425 - 428
  作者：Petrova, L. A.、Borisov, A. P.、Makhaev, V. D.

  DOI：——

  日期：——