1,3-bis(trimethylsilyl)imidazolium chloride

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,3-bis(trimethylsilyl)imidazolium chloride
• 英文别名: bistrimethylsilylimidazolium chlorid；1,3-Bis(trimethylsilyl)-1H-imidazol-3-ium Chloride；trimethyl-(3-trimethylsilylimidazol-1-ium-1-yl)silane;chloride
• 化学式: C₉H₂₁N₂Si₂*Cl
• 分子量: 248.903
• InChiKey: BUCAPEUWYDFHEJ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.85
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  8.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,3-bis(trimethylsilyl)imidazolium chloride 生成 三甲基硅咪唑
  参考文献：
  名称：

  Synthesis and structure of silyl-substituted imidazol-2-ylidenes and their precursors

  摘要：

  Previously unknown heterocyclic carbenes and their precursors containing a silicon atom in the side chain were prepared. Their structures were studied by multinuclear H-1, C-13, N-15, and Si-29 NMR spectroscopy.

  DOI：

  10.1134/s1070363207060242
• 作为产物：
  描述：

  三甲基氯硅烷 、 三甲基硅咪唑 以 二氯甲烷 为溶剂， 生成 1,3-bis(trimethylsilyl)imidazolium chloride
  参考文献：
  名称：

  N,N-双(甲硅烷氧基)烯胺化学 7. N,N-双(甲硅烷氧基)烯胺对叔胺和含氮杂环的季铵化

  摘要：

  研究了 N,N-双 (甲硅烷氧基) 烯胺与叔胺和含氮杂环的偶联，以提供相应的功能化铵盐或亚胺盐。确定了其应用领域，并提出了合成目标产物的最佳程序。讨论了形成共轭亚硝基烯烃或甲硅烷基亚硝基阳离子作为关键中间体的机制。

  DOI：

  10.1007/s11172-005-0106-x

文献信息

• Chemistry of N,N-bis(silyloxy)enamines 7. Quaternization of tertiary amines and nitrogen-containing heterocycles by N,N-bis(silyloxy)enamines
  作者：A. V. Lesiv、S. L. Ioffe、Yu. A. Strelenko、V. M. Danilenko

  DOI：10.1007/s11172-005-0106-x

  日期：2004.10

  Coupling of N,N-bis(silyloxy)enamines with tertiary amines and nitrogen-containing heterocycles affording the corresponding functionalized ammonium or iminium salts was studied. The area of its application was determined, and optimal procedures for the synthesis of the target products were proposed. The mechanism including the formation of conjugated nitroso alkene or a silylnitrosonium cation as key

  研究了 N,N-双 (甲硅烷氧基) 烯胺与叔胺和含氮杂环的偶联，以提供相应的功能化铵盐或亚胺盐。确定了其应用领域，并提出了合成目标产物的最佳程序。讨论了形成共轭亚硝基烯烃或甲硅烷基亚硝基阳离子作为关键中间体的机制。
• The interaction of electrophilic silanes (Me3SiX, X = ClO4, I, CF3SO3, Br, Cl) with nucleophiles. The nature of silylation mixtures in solution.
  作者：Alan R. Bassindale、Tim Stout

  DOI：10.1016/s0040-4039(00)98309-6

  日期：1985.1
• Bassindale, Alan R.; Stout, Tim, Journal of the Chemical Society. Perkin transactions II, 1986, p. 221 - 226
  作者：Bassindale, Alan R.、Stout, Tim

  DOI：——

  日期：——
• Synthesis and structure of silyl-substituted imidazol-2-ylidenes and their precursors
  作者：T. N. Komarova、L. I. Larina、E. V. Abramova、G. V. Dolgushin

  DOI：10.1134/s1070363207060242

  日期：2007.6

  Previously unknown heterocyclic carbenes and their precursors containing a silicon atom in the side chain were prepared. Their structures were studied by multinuclear H-1, C-13, N-15, and Si-29 NMR spectroscopy.