N,N'-diformyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidine)hexanediamine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: N,N'-diformyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidine)hexanediamine
• 英文别名: N-[6-[formyl-(2,2,6,6-tetramethylpiperidin-1-yl)amino]hexyl]-N-(2,2,6,6-tetramethylpiperidin-1-yl)formamide
• 化学式: C₂₆H₅₀N₄O₂
• 分子量: 450.709
• InChiKey: UZBOXUKPACYXBQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  47.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  N,N’-di(2,2,6,6-tetramethyl-4-piperidine)hexamethylenediamine 、 formamide 在 solid superacid catalyst 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 为溶剂， 反应 4.0h， 以98%的产率得到N,N'-diformyl-N,N'-bis(2,2,6,6-tetramethyl-4-piperidine)hexanediamine
  参考文献：
  名称：

  一种哌啶化合物及其制备工艺

  摘要：

  本发明公开了一种哌啶化合物及其制备工艺，其结构通式为：。其制备工艺为：在固体超强酸存在的情况下，将结构式如下的化合物与甲酰化试剂置于溶剂中充分反应，加碱液，析出晶体，分离、洗涤、烘干即可；。本发明的工艺采用高效的固体超强酸作为催化剂，催化剂用量少，反应完毕后直接过滤除去催化剂，后续处理简单而且催化剂可循环利用，同时制备工艺反应温度低、时间短，减少了副产物，显著提高收率和产品纯度，工艺简单高效。

  公开号：

  CN105017131B

文献信息

• 一种哌啶化合物及其制备工艺
  申请人：广州合成材料研究院有限公司

  公开号：CN105017131B

  公开（公告）日：2018-01-16

  本发明公开了一种哌啶化合物及其制备工艺，其结构通式为：。其制备工艺为：在固体超强酸存在的情况下，将结构式如下的化合物与甲酰化试剂置于溶剂中充分反应，加碱液，析出晶体，分离、洗涤、烘干即可；。本发明的工艺采用高效的固体超强酸作为催化剂，催化剂用量少，反应完毕后直接过滤除去催化剂，后续处理简单而且催化剂可循环利用，同时制备工艺反应温度低、时间短，减少了副产物，显著提高收率和产品纯度，工艺简单高效。
• AGROCHEMICAL FORMULATIONS COMPRISING A PESTICIDE, AN ORGANIC UV-PHOTOPROTECTIVE FILTER AND COATED METAL-OXIDE NANOPARTICLES
  申请人：BASF SE

  公开号：EP2306818A2

  公开（公告）日：2011-04-13
• Agrochemical Formulations Comprising A Pesticide, An Organic UV-Photoprotective Filter And Coated Metal-Oxide Nanoparticles
  申请人：Ishaque Michael

  公开号：US20110111957A1

  公开（公告）日：2011-05-12

  The present invention relates to an agrochemical formulation comprising a pesticide, an organic UV photoprotective filter and coated metal oxide nanoparticles. It also relates to a method for preparing said formulation. Further on, it also relates to the use of a mixture of an organic UV photoprotective filter and coated metal oxide nanoparticles in agrochemical formulations and the use of a agrochemical formulation according to the invention for stabilizing a pesticide against UV irradiation. Further on, it relates to a method of combating harmful insects and/or phytopathogenic fungi, which comprises contacting plants, soil or habitat of plants in or on which the harmful insects and/or phytopathogenic fungi are growing or may grow, plants or soil to be protected from attack or infestation by said harmful insects and/or phytopathogenic fungi with an effective amount of the formulation according to the invention, to a method of controlling undesired vegetation, which comprises allowing a herbicidal effective amount of said formulation to act on plants, their habitat.
• US8404263B2
  申请人：——

  公开号：US8404263B2

  公开（公告）日：2013-03-26
• [EN] AGROCHEMICAL FORMULATION COMPRISING A PESTICIDE, AN ORGANIC UV PHOTOPROTECTIVE FILTER AND COATED METAL OXIDE NANOPARTICLES<br/>[FR] PRÉPARATION AGROCHIMIQUE CONTENANT UN PESTICIDE, UN FILTRE ORGANIQUE PHOTOPROTECTEUR ANTI-UV ET DES NANOPARTICULES D'OXYDE MÉTALLIQUE ENROBÉES
  申请人：BASF SE

  公开号：WO2009153231A2

  公开（公告）日：2009-12-23

  The present invention relates to an agrochemical formulation comprising a pesticide, an organic UV photoprotective filter and coated metal oxide nanoparticles. It also relates to a method for preparing said formulation. Further on, it also relates to the use of a mixture of an organic UV photoprotective filter and coated metal oxide nanoparticles in agrochemical formulations and the use of a agrochemical formulation according to the invention for stabilizing a pesticide against UV irradiation. Further on, it relates to a method of combating harmful insects and/or phytopathogenic fungi, which comprises contacting plants, soil or habitat of plants in or on which the harmful insects and/or phytopathogenic fungi are growing or may grow, plants or soil to be protected from attack or infestation by said harmful insects and/or phytopathogenic fungi with an effective amount of the formulation according to the invention, to a method of controlling undesired vegetation, which comprises allowing a herbicidal effective amount of said formulation to act on plants, their habitat.