五亚甲基硫代氨基甲酸钠 | 56368-46-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 中文名称: 五亚甲基硫代氨基甲酸钠
• 英文名称: sodium pentamethylenethiocarbamate
• 英文别名: Sodium;piperidine-1-carbothioate
• CAS: 56368-46-8
• 化学式: C₆H₁₀NOS*Na
• 分子量: 167.207
• InChiKey: DOOOLPHOMUAUEO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.88
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  58.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-氯戊烷 、 五亚甲基硫代氨基甲酸钠 以 水 为溶剂， 生成
  参考文献：
  名称：

  Valitov, R.B.; Galiakhmetov, R.N.; Kurochkin, A.K., Russian Journal of Physical Chemistry, 1985, vol. 59, # 12, p. 1782 - 1785

  摘要：

  DOI：
• 作为产物：
  描述：

  piperidinium piperidylmonothiocarbamate 、 sodium hydroxide 生成 五亚甲基硫代氨基甲酸钠
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• Process for production of chlorinated ethylene-propylene copolymers
  申请人：SHOWA DENKO KABUSHIKI KAISHA

  公开号：EP0268457A2

  公开（公告）日：1988-05-25

  A chlorinated ethylene-propylene copolymer having a chlorine content of 20 to 450/0 by weight and a Mooney viscosity (ML1 +4, 100°C) of 10 to 150 is produced by chlorinating in two or three stages, by contact with chlorine gas in an aqueous suspension, an ethylene-propylene copolymer having a propylene content of 15 to 40% by weight, a melt flow indes of 0.01 to 5.0 g/10 minutes, a melting peak as measured by differential scan calorimeter (DSC) of 80°C or more, a crystallinity as measured by X-rays of 3% or more, an index MW/ MN of the distribution of molecular wieght, determined by gel permeation chromatography (GPC), of greater than 4, and a Mooney visocisty (MH1+4, 100°C) of 10 to 180. A vulcanizable composition having superior physical properties may be obtained by formulating with (A) the chlorinated ethylene-propylene copolymer, (B) a thiourea compound, (C) a sulfur and/or sulfur donor. (D) a metal compound, and further, if necessary, (E) a dicarbamate or (F) a mercaptotriadizine compound. Further, a cross-linkable composition having superior physical properties may be obtained by formulating (A) the chlorinated ethylene-propylene copolymer with (G) an organic peroxide.

  一种氯化乙烯-丙烯共聚物，其氯含量为 20 至 450/0（重量比），门尼粘度（ML1 +4，100°C）为 10 至 150（重量比），是通过在水悬浮液中与氯气接触，分两段或三段氯化制得的，该乙烯-丙烯共聚物的丙烯含量为 15 至 40%（重量比），熔体流动指数为 0.01 至 5.0 克/10 分钟，用差示扫描量热仪 (DSC) 测得的熔峰为 80°C 或以上，用 X 射线测得的结晶度为 3% 或以上，用凝胶渗透色谱法 (GPC) 测得的分子量分布指数 MW/ MN 大于 4，以及门尼粘度 (MH1+4, 100°C) 为 10 至 180。 通过与以下物质配制，可获得具有优异物理性能的可硫化组合物：(A) 氯化乙烯-丙烯共聚物，(B) 硫脲化合物，(C) 硫和/或硫供体。(D) 金属化合物，必要时还可加入 (E) 二氨基甲酸酯或 (F) 硫代三嗪化合物。此外，还可通过将 (A) 氯化乙烯-丙烯共聚物与 (G) 有机过氧化物配制成具有优异物理性质的可交联组合物。
• Synthesis, spectroscopic characterization and structural studies of dialkyl dithiophosphinate and N,N-dialkyl dithio- and monothio-carbamate derivatives of 1-iodo-1,1,2,3,4,5-hexahydrotellurophene
  作者：Verónica Garcı́a-Montalvo、Arturo Marcelo-Polo、Ricardo Montoya、R.Alfredo Toscano、Simón Hernández-Ortega、Raymundo Cea-Olivares

  DOI：10.1016/s0022-328x(00)00718-x

  日期：2001.3

  The synthesis of the organotellurium(IV) compounds [C4H8TeI(S2PMe2)] (2), [C4H8TeI(S2PEt2)] (3), [C4H8TeI(S2CNC4H6)] (4) and [C4H8TeI(SOCNC5H10)] (6) was achieved. All of them were characterized by IR, H-1-, C-13-, P-31- and Te-125-NMR, mass spectroscopy, elemental analyses and single-crystal X-ray diffraction. In addition, the crystal and molecular structures of the previously known 1,1 -diiodotetrahydrotellurophene and [C4H8TeI(S2CNEt2)] (5) were obtained. The geometry around Te(IV) is that of a sawhorse structure in which the lone pair is apparently stereochemically active and occupying an equatorial position in a distorted trigonal bipyramid. All the structures exhibit different supramolecular associations. The intermolecular Te . . .S and Te . . . I interactions result in the formation of dimeric species in 4, and in 1 and 6. respectively. The intermolecular Te . . .S bonds in 2, 3 and 5 lead to formation of one-dimensional polymers. (C) 2001 Elsevier Science B.V. All rights reserved.
• Galiakhmetov, R. N.; Valitov, R. B.; Kurochkin, A. K., Russian Journal of Physical Chemistry, 1986, vol. 60, # 4, p. 614 - 615
  作者：Galiakhmetov, R. N.、Valitov, R. B.、Kurochkin, A. K.、Margulis, M. A.

  DOI：——

  日期：——
• Linden, J. G. M., van der; Blommerde, W.; Dix, A. H., Inorganica Chimica Acta, 1977, vol. 24, p. 261 - 268
  作者：Linden, J. G. M., van der、Blommerde, W.、Dix, A. H.、Pijpers, F. W.

  DOI：——

  日期：——
• ——
  作者：AYUSAVA TADASI、 IVANEH XIROSI、 KUDZIRA KATSUFUMI、 KAVAXARA TAKAYUKI、 TSUK+

  DOI：——

  日期：——