3-carbethoxy-1,2-propylene carbonate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: 3-carbethoxy-1,2-propylene carbonate
• 英文别名: glycerine carbonate propionate；(2-Oxo-1,3-dioxolan-4-yl)methyl propanoate
• 化学式: C₇H₁₀O₅
• 分子量: 174.153
• InChiKey: FXNHCWPCSHUWAC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  羟甲基二氧杂戊环酮 生成 3-carbethoxy-1,2-propylene carbonate
  参考文献：
  名称：

  GRAHE, GERWALD;LACHOWICZ, ARTUR

  摘要：

  DOI：

文献信息

• The telomerisation of 1,3-butadiene and carbon dioxide: process development and optimisation in a continuous miniplant
  作者：Arno Behr、Marc Becker

  DOI：10.1039/b608552k

  日期：——

  The telomerisation of 1,3-butadiene and carbon dioxide is one of the first homogeneously catalyzed reactions using carbon dioxide as a C1-building block. In this article we describe the process development for a miniplant applying this telomerisation in a continuous scale. Through repeated optimisation of the plant setup combined with parallel laboratory batch experiments the overall space-time-yield of the plant was enhanced significantly.

  1,3-丁二烯和二氧化碳的端聚反应是最早利用二氧化碳作为C1构建单元进行均相催化反应之一。 本文中， 我们描述了在小规模的工厂中应用这一端聚反应进行连续生产的过程开发。通过对工厂设备多次优化以结合平行的实验室批次实验， 工厂的整体空间时间产率得到显著提升。
• Synthesis of Functionalized Cyclic Carbonates by One-Pot Reactions of Carbon Dioxide, Epibromohydrin, and Phenols, Thiophenols, or Carboxylic Acids Catalyzed by Ionic Liquids
  作者：Shi Wu、Yongya Zhang、Binshen Wang、Elnazeer H. M. Elageed、Liangzheng Ji、Haihong Wu、Guohua Gao

  DOI：10.1002/ejoc.201601315

  日期：2017.1.18

  The one-pot reactions of CO2, epibromohydrin, and phenols, thiophenols, or carboxylic acids catalyzed by 1-butyl-3-[(3-hydroxyphenyl)methyl]imidazolium bromide were investigated. Three kinds of cyclic carbonates with ether, thioether, or ester groups were synthesized under mild reaction conditions in good-to-high yields. Reaction-mechanism studies indicated that the proton exchange between the alkoxide

  研究了由 1-丁基-3-[(3-羟基苯基)甲基] 溴化咪唑鎓催化的 CO2、表溴醇和苯酚、苯硫酚或羧酸的一锅法反应。在温和的反应条件下以良好到高的收率合成了三种具有醚、硫醚或酯基团的环状碳酸酯。反应机理研究表明，表溴醇与 1-溴-3-苯氧基-2-丙醇的开环反应形成的醇盐之间的质子交换在该合成路线中起着至关重要的作用。催化剂1-丁基-3-[(3-羟基苯基)甲基]溴化咪唑鎓在反应过程中转化为相应的环状碳酸酯官能化离子液体。这种转化不影响其在反应中的催化性能。
• Novel Ammonium-Polyurethane- And/Or Polycarbonate Compounds
  申请人：Wagner Roland

  公开号：US20110033411A1

  公开（公告）日：2011-02-10

  The invention relates to novel compounds, in particular ammonium-polyurethane and/or polycarbonate compounds, in particular ammonium-polyurethane-polydiorganosiloxane and/or polycarbonate-polydiorganosiloxane compounds, methods for their production as well as their use.

  本发明涉及新型化合物，特别是氨基聚氨酯和/或聚碳酸酯化合物，特别是氨基聚氨酯-聚二甲基硅氧烷和/或聚碳酸酯-聚二甲基硅氧烷化合物，以及它们的制备方法和使用。
• COMPOSITION COMPRISING AN AGROCHEMICALLY ACTIVE COMPOUND AND A CARBONATE
  申请人：BASF SE

  公开号：EP3501280A1

  公开（公告）日：2019-06-26

  A liquid composition comprising at least component (a): at least one agrochemically active compound, and component (b): at least one carbonate of the formula (I) wherein, R is selected from (vii) linear, cyclic or branched C3-C10 alkyl, (viii) phenyl, (ix) -CH2OR1, wherein R1 is selected from linear or branched C1-C6 alkyl, linear or branched C1-C6 alkyl-carbonyl, phenyl-carbonyl, benzyl-carbonyl, lactate, pyridine-carbonyl, and a residue according to the following formula (II) wherein the variables in formula (II) are as follows: R2, R3, R4, R5, and R6 are independently from each other selected from H, methyl, ethyl, propyl and phenyl; R7 is selected from H, linear, cyclic or branched C1-C10 alkyl, and phenyl; n, o, p, q, and r are independently from each other an integer in the range of 0-6, wherein the sum of the integers is in the range of 1 to 6; and optionally component (c): at least one compound selected from the group of organic solvents.

  一种液体组合物，至少包括 成分 (a)： 至少一种农用化学活性化合物，和 成分 (b)：至少一种式 (I) 的碳酸盐 其中，R 选自 (vii) 直链、环状或支链 C3-C10 烷基、 (viii) 苯基 (ix) -CH2OR1，其中 R1 选自直链或支链 C1-C6 烷基、直链或支链 C1-C6 烷基-羰基、苯基-羰基、苄基-羰基、乳酸、吡啶-羰基，以及符合下式 (II) 的残基 其中，式（II）中的变量如下： R2、R3、R4、R5 和 R6 相互独立地选自 H、甲基、乙基、丙基和苯基； R7 选自 H、直链、环状或支链 C1-C10 烷基和苯基； n、o、p、q 和 r 相互独立地为 0-6 之间的整数，其中整数之和为 1-6 之间； 以及 可选组分 (c)：至少一种选自有机溶剂组的化合物。
• GRAHE, GERWALD;LACHOWICZ, ARTUR
  作者：GRAHE, GERWALD、LACHOWICZ, ARTUR

  DOI：——

  日期：——