2-bromo-3-hexyl-5-(trimethylstannyl)thiophene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 噻吩类
• 英文名称: 2-bromo-3-hexyl-5-(trimethylstannyl)thiophene
• 英文别名: 2-Bromo-3-hexyl-5-trimethylstannyl thiophene；(5-bromo-4-hexylthiophen-2-yl)-trimethylstannane
• 化学式: C₁₃H₂₃BrSSn
• 分子量: 410.006
• InChiKey: DVRXLNPMPZGGED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.18
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-己基噻吩 在 N-溴代丁二酰亚胺(NBS) 、 溶剂黄146 、 lithium diisopropyl amide 作用下， 生成 2-bromo-3-hexyl-5-(trimethylstannyl)thiophene
  参考文献：
  名称：

  Random poly(3-hexylthiophene-co -3-cyanothiophene) copolymers with high open-circuit voltage in organic solar cells

  摘要：

  DOI：

  10.1002/pola.27095

文献信息

• 낮은 밴드 갭을 갖는 유기 반도체 화합물 및 이를 포함하는 트랜지스터와 전자 소자
  申请人：SAMSUNG ELECTRONICS CO., LTD. 삼성전자주식회사(119981042713) Corp. No ▼ 130111-0006246BRN ▼124-81-00998

  公开号：KR20180027475A

  公开（公告）日：2018-03-14

  하기 화학식 1로 표시되는 구조 단위를 포함하는 유기 반도체 화합물을 제공한다. [화학식 1] 상기 화학식 1에서 각 치환기의 정의는 명세서에 정의된 바와 같다.

  提供一种含有标记为化学式1的结构单元的有机半导体化合物。在化学式1中，每个取代基的定义如规范书中所定义。
• Organic semiconductor polymer for organic thin film transistor containing quinoxaline ring in the backbone chain
  申请人：Lee Lin Bang

  公开号：US20050121668A1

  公开（公告）日：2005-06-09

  Disclosed herein is a composite-structured organic semiconductor polymer for an organic thin film transistor which contains quinoxaline rings in the backbone of the polymer. According to the organic semiconductor polymer, since quinoxaline rings having n-type semiconductor characteristics, such as high electron affinity, are incorporated into a polythiophene having p-type semiconductor characteristics, the organic semiconductor polymer simultaneously exhibits both p-type and n-type semiconductor characteristics. In addition, the polythienylquinoxaline derivative exhibits high solubility in organic solvents, co-planarity and stability in air. Furthermore, when the polythienylquinoxaline derivative is used as an active layer of an organic thin film transistor, the organic thin film transistor exhibits a high charge carrier mobility and a low off-state leakage current.

  本文公开了一种复合结构有机半导体聚合物，用于有机薄膜晶体管，其中聚合物的骨架中含有喹啉环。根据这种有机半导体聚合物，由于将具有n型半导体特性（如高电子亲和力）的喹啉环并入具有p型半导体特性的聚噻吩中，因此有机半导体聚合物同时表现出p型和n型半导体特性。此外，聚噻吩基喹啉衍生物在有机溶剂中具有高溶解度，在空气中具有共平面性和稳定性。此外，当将聚噻吩基喹啉衍生物用作有机薄膜晶体管的有源层时，有机薄膜晶体管表现出高载流子迁移率和低关断漏电流。
• Random poly(3-hexylthiophene-<i>co</i> -3-cyanothiophene) copolymers with high open-circuit voltage in organic solar cells
  作者：Petr P. Khlyabich、Andrey E. Rudenko、Barry C. Thompson

  DOI：10.1002/pola.27095

  日期：2014.4.15