双(1,3-丙二胺)氯化铜(II) | 32270-93-2

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 双(1,3-丙二胺)氯化铜(II)
• 中文别名: 二(1,3-丙烷二胺)铜(II)二氯化物
• 英文名称: bis(1,3-propanediamine)copper(II) dichloride
• 英文别名: [(1,3-propanediamine)2Cu]Cl2；Bis(1,3-propanediaminE)copper(ii)dichloride；copper;propane-1,3-diamine;dichloride
• CAS: 32270-93-2；85761-02-0；176547-89-0；770736-33-9；15558-15-3
• 化学式: C₆H₂₀Cl₂CuN₄
• 分子量: 282.704
• InChiKey: HSUSKWQWIPIFEB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.04
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  104
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  双(1,3-丙二胺)氯化铜(II) 以 四氯化碳 、 乙醇 、 二甲基亚砜 为溶剂， 生成
  参考文献：
  名称：

  Heterobimetallic Complexes Containing Cu and Si

  摘要：

  [Bis(propanediamine)Cu]Cl-2, (1) was allowed to react with SiCl4 to yield a bimetallic complex (2). Compound (2) was then treated with pyridine to attain the maximum coordination number of silicon (3). The reaction was also followed conductometrically. Complex (3) was reacted with sodium diethyl dithiocarbamate (dtc) to yield (4). The dtc in (4) acts as a bidentate chelating agent as its IR spectrum showed the CS2 stretching frequency at 1020 cm(-1) I which is characteristic of a symmetrically bonded dithiocarbamate group. There is a common peak in the range 246 to 260 nm in the UV-Vis. spectra of (1), (2) and (3) due to L --> M charge transfer. The EPR spectra of all species showed different environments for the Cu(II) ion in the various compounds indicating stereochemical changes.

  DOI：

  10.1081/sim-120024322
• 作为产物：
  描述：

  copper(II) choride dihydrate 、 1,3-丙二胺 以 乙醇 为溶剂， 以51%的产率得到双(1,3-丙二胺)氯化铜(II)
  参考文献：
  名称：

  Heterobimetallic Complexes Containing Cu and Si

  摘要：

  [Bis(propanediamine)Cu]Cl-2, (1) was allowed to react with SiCl4 to yield a bimetallic complex (2). Compound (2) was then treated with pyridine to attain the maximum coordination number of silicon (3). The reaction was also followed conductometrically. Complex (3) was reacted with sodium diethyl dithiocarbamate (dtc) to yield (4). The dtc in (4) acts as a bidentate chelating agent as its IR spectrum showed the CS2 stretching frequency at 1020 cm(-1) I which is characteristic of a symmetrically bonded dithiocarbamate group. There is a common peak in the range 246 to 260 nm in the UV-Vis. spectra of (1), (2) and (3) due to L --> M charge transfer. The EPR spectra of all species showed different environments for the Cu(II) ion in the various compounds indicating stereochemical changes.

  DOI：

  10.1081/sim-120024322

文献信息

• Conformational flexibility of the di (1,3-diaminopropane)- copper (II) cation Part 2. Structure determination for aqua-di(1,3-diaminopropane-N,N′)-copper (II) dichloride and chlorodi (1,3-diaminopropane-N,N'⊃-copper(II) chloride methanol solvate and DF17 calculations for aqua-di (1,3-diaminopropane-N,N′) copper (II) cation
  作者：Markku R. Sundberg、Reijo Sillanpää、Rolf Uggla

  DOI：10.1016/0020-1693(95)04796-4

  日期：1996.4

  The structures of aqua-di(1,3-diaminopropane-N,N′)copper (II) dichloride (1) and chloro-di(1,3-diaminopropane-N N′) copper (II) chloride methanol solvate (2) were determined by single crystal X-ray methods. [Cu(tn)2H2O]Cl2 (1) (tn=1,3-diaminopropane), C6H22Cl2CuN4O, Mr = 300.72, tetragonal, space group P42nm (No. 102), a = 9.3146 (5) , c = 7.591(1) A, V = 658.63(9) A3, Z = 2, Dc = 1.516 g cm−3. [Cu(tn)2Cl]Cl·MeOH

  水合二（1,3-二氨基丙烷-N，N'）铜（II）（1）和氯二（1,3-二氨基丙烷-N N'）氯化铜（II）的甲醇溶剂化物（2）的结构用单晶X射线法测定。[Cu（tn）2H2O] Cl2（1）（tn = 1,3-二氨基丙烷），C6H22Cl2CuN4O，Mr = 300.72，方形，空间群P42nm（No. 102），a = 9.3146（5），c = 7.591（1 ）A，V ＝ 658.63（9）A3，Z ＝ 2，Dc ＝ 1.516g cm-3。[Cu（tn）2Cl] Cl·MeOH（2），C7H24Cl2CuN4O，Mr = 314.74，单斜晶系，空间群P21 / c（No.14），a = 8.598（2），b = 16.176（2），c = 10.418 （4）A，β＝ 107.11（3）°，V ＝ 1384.7（7）A3，Z ＝ 4，Dc ＝ 1.510g cm-3。化合物1在
• Method of manufacturing semiconductor quantum dot and semiconductor quantum dot
  申请人：FUJIFILM Corporation

  公开号：US10947112B2

  公开（公告）日：2021-03-16

  There is provided a method of manufacturing a semiconductor quantum dot including the following steps (A1) and (B1): a step (A1) of causing a nanoparticle including a specific compound semiconductor and a salt of a specific metal a1 to react with each other to introduce the metal a1 into a surface layer of the nanoparticle; and a step (B1) of causing the nanoparticle in which the metal a1 is introduced into the surface layer and a salt of a specific metal b1 to react with each other to introduce the metal b1 into the surface layer of the nanoparticle. There is provided a semiconductor quantum dot having a structure in which a specific metal a1 and/or a specific metal b1 is introduced into a surface layer of a nanoparticle including a specific compound semiconductor.

  本发明提供了一种半导体量子点的制造方法，包括以下步骤（A1）和（B1）： 使包括特定化合物半导体和特定金属 a1 的盐的纳米粒子相互反应以将金属 a1 引入纳米粒子的表面层的步骤（A1）；以及 使将金属 a1 引入表层的纳米粒子和特定金属 b1 的盐相互反应，将金属 b1 引入纳米粒子表层的步骤 (B1)。 本发明提供了一种半导体量子点，其结构是将特定金属 a1 和/或特定金属 b1 引入包括特定化合物半导体的纳米粒子的表面层。
• Chemical polymerization initiator, adhesive composition, adhesive composition kit, dental material, dental material kit, and method of storing adhesive composition
  申请人：TOKUYAMA DENTAL CORPORATION

  公开号：US11325993B2

  公开（公告）日：2022-05-10

  Provided are a chemical polymerization initiator including (a) a thiourea compound, (b) a peroxyester, (c) a divalent copper compound, and (d) an aryl borate compound, an adhesive composition, an adhesive composition kit, a dental material, and a dental material kit each using the chemical polymerization initiator, and a method of storing the adhesive composition.

  本文提供了一种化学聚合引发剂，包括 (a) 硫脲化合物、(b) 过氧化酯、(c) 二价铜化合物和 (d) 芳基硼酸酯化合物；一种粘合剂组合物；一种粘合剂组合物试剂盒；一种牙科材料和一种牙科材料试剂盒；以及一种储存粘合剂组合物的方法。
• Synthesis and structures of Octaaza NiII and CuII macrocyclic complexes containing biimidazole
  作者：G.B. El-Hefnawy、M. El-Kersh、S.H. Etaiw、R. El-Tabbakh

  DOI：10.1016/s0277-5387(97)00183-6

  日期：1997.9

  The reactions of bis-(ethylenediamine)MX2, M(en)(2)X-2, bis-(1,3-propylenediamine)MX2, M(1,3-DAP)(2)X-2, and bis-(2,2-dimethyl-1,3-propylenediamine)MX2, M(2,2-DM-1,3-DAP)(2)X-2 complexes, [M = Cu-II or Ni-II and X = Cl- or ClO4-], after adjusting the pH values to 5, with 1,1-diacetyl-2,2'-biimidazole (Ac(2)BiIm) afforded octaazamacrocyclic Cu-II complexes (1-6) and Ni-II complexes (7-12). The solid complexes were characterized by elemental analysis, molar conductivities, IR, UV-vis, EPR, NMR and atomic absorption spectra, back titration, TGA and DTA. (C) 1997 Elsevier Science Ltd.
• CHEMICAL POLYMERIZATION INITIATOR, ADHESIVE COMPOSITION, ADHESIVE COMPOSITION KIT, DENTAL MATERIAL, DENTAL MATERIAL KIT, AND METHOD FOR STORING ADHESIVE COMPOSITION
  申请人：Tokuyama Dental Corporation

  公开号：EP3693400B1

  公开（公告）日：2021-10-06