seguinoside E

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 单宁
• 英文名称: seguinoside E
• 英文别名: [(3S,4R,5S)-5-[(2S,3R,4S,5S,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-(4-hydroxyphenoxy)oxan-3-yl]oxy-3,4-dihydroxyoxolan-3-yl]methyl 4-hydroxy-3-methoxybenzoate
• 化学式: C₂₅H₃₀O₁₄
• 分子量: 554.505
• InChiKey: QHRHKYAZXRNVAA-KXQNOTADSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.5
• 重原子数：
  39
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  214
• 氢给体数：
  7
• 氢受体数：
  14

反应信息

• 作为反应物：
  描述：

  甲醇 、 seguinoside E 在 sodium hydroxide 作用下， 反应 6.0h， 以64%的产率得到香草酸甲酯
  参考文献：
  名称：

  Hydroquinone glycosides from leaves of Myrsine seguinii

  摘要：

  From leaves of Myrsine seguinii, seven hydroquinone glycosides were isolated. By spectroscopic analyses, their structures were elucidated to be arbutin, arbutin 2'- and 6'-O-beta-apiofuranosides (seguinosides A and B, respectively), and the benzoyl, p-hydroxybenzoyl, 3-methoxy-4-hydroxybenzoyl and 3,5-dimethoxy-4-hydroxybenzoyl esters of the alcohol hydroxyl group on C-5 " of arbutin 2'-O-beta-apiofuranoside (seguinosides C-F, respectively). (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0031-9422(98)00384-7