1,3,3-trimethyl-6'-(4-(4-hydroxyphenyl)piperazin-1-yl)-spiro[indoline-2,3'-3H-naphtho[2,1-b][1,4]oxazine]

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪烷类
• 英文名称: 1,3,3-trimethyl-6'-(4-(4-hydroxyphenyl)piperazin-1-yl)-spiro[indoline-2,3'-3H-naphtho[2,1-b][1,4]oxazine]
• 英文别名: 4-[4-(1',3',3'-Trimethylspiro[benzo[f][1,4]benzoxazine-3,2'-indole]-6-yl)piperazin-1-yl]phenol
• 化学式: C₃₂H₃₂N₄O₂
• 分子量: 504.632
• InChiKey: GPBFBOKZQABMOR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  38
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  51.5
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  1-对羟基苯基哌嗪 生成 1,3,3-trimethyl-6'-(4-(4-hydroxyphenyl)piperazin-1-yl)-spiro[indoline-2,3'-3H-naphtho[2,1-b][1,4]oxazine]
  参考文献：
  名称：

  Photochromic compounds

  摘要：

  本文披露的各种非限定实施例通常涉及光致变色化合物，可以是热可逆或非热可逆的，并且由此制成的物品。其他非限定实施例涉及光致-二色化合物，可以是热可逆或非热可逆的，并且由此制成的物品。例如，一个非限定实施例提供了一种热可逆的、光致变色化合物，适用于至少具有第一状态和第二状态，其中该热可逆的、光致变色化合物在至少一个状态下的平均吸收比大于2.3，根据CELL METHOD确定。另一个非限定实施例提供了一种光致变色化合物，包括：(a)至少一种从吡喃、噁唑和富里德中选择的光致变色基团；以及(b)连接到至少一种光致变色基团的至少一种延长剂L，由以下公式表示：—[S1]c-[Q1-[S2]d]d′-[Q2-[S3]e]e′-[Q3-[S4]f]f′—S5—P，如本文所述。

  公开号：

  US20050004361A1

文献信息

• PHOTOCHROMIC COMPOUNDS
  申请人：TRANSITIONS OPTICAL, INC.

  公开号：EP1639058B1

  公开（公告）日：2020-10-21
• POLARIZING PHOTOCHROMIC DEVICES AND METHODS OF MAKING THE SAME
  申请人：TRANSITIONS OPTICAL, INC.

  公开号：EP1642160B1

  公开（公告）日：2018-04-11
• Polarizing, photochromic devices and methods of making the same
  申请人：Kumar Anil

  公开号：US20050012998A1

  公开（公告）日：2005-01-20

  Various embodiments disclosed herein relate to optical elements comprising an at least partial coating having a first state and a second state connected to at least a portion of a substrate, the at least partial coating being adapted to switch from the first state to the second state in response to at least actinic radiation, to revert back to the first state in response to thermal energy, and to linearly polarize at least transmitted radiation in at least one of the first state and the second state. Other embodiments relate to optical elements comprising a substrate and at least one at least partially aligned photochromic-dichroic compound connected to at least a portion of the substrate and having an average absorption ratio greater than 2.3 in the activated state as determined according to CELL METHOD. Still other embodiments relate to security devices, liquid crystal cells and methods of making the same.
• Polirizing, photochromic devices and methods of making the same
  申请人：Kumar Anil

  公开号：US20070053048A1

  公开（公告）日：2007-03-08

  An optical element including: a substrate; and an at least partial coating having a first state and a second state on at least a portion of the substrate, the at least partial coating being adapted to be circularly polarizing or elliptically polarizing in at least one state and containing: a chiral nematic or cholesteric liquid crystal material having molecules that are helically arranged through a thickness of the at least partial coating; and at least one photochromic-dichroic compound that is at least partially aligned with the liquid crystal material such that a long axis of a molecule of the photochromic-dichroic compound is generally parallel to the molecules of the liquid crystal material.
• POLARIZING, PHOTOCHROMIC DEVICES AND METHODS OF MAKING THE SAME
  申请人：Kumar Anil

  公开号：US20080123172A1

  公开（公告）日：2008-05-29

  A method of making an optical element including: forming an at least partial coating of an alignment medium to at least a portion of at least one surface of a substrate and at least partially ordering at least a portion of the alignment medium; forming at least one at least partial coating of an alignment transfer material on at least a portion of the coating of the alignment medium and aligning the alignment transfer material with at least a portion of the ordered alignment medium; and forming an at least partial coating including an anisotropic material and at least one photochromic-dichroic compound on the alignment transfer material, aligning at least a portion of the anisotropic material with the at least partially aligned alignment transfer material, and aligning at least a portion of the photochromic-dichroic compound with aligned anisotropic material.