作者:J.V. Kingston、G. Wilkinson
DOI:10.1016/0022-1902(66)80397-4
日期:1966.11
Compounds of the type [Ru(S2−)2(CO)] [Ru(S2−)2(CO)2] and [Ru(S2−)2(CO)2],Cl, (S2− R2NCS2−) are prepared by treating a carbonyl-containing ruthenium solution with a dithiocarbamate solution. In this manner the complexes [RuII(C2H5)2NCS2}2(CO)], [RuII(CH3)2NCS2}2(CO) [RuII(CH3)2NCS2}2(CO)2], [RuII(C6H5CH2)2(CO)2] and [RuIII(C6H5CH2)2NCS 2}(CO)2] are isolated. [RuII(C6H5S−)2(CO)2]3, [RuIICl2(CO)2(SnCl3)2]2−
该类型的化合物的[Ru(S 2 - )2(CO)]的[Ru(š 2 - )2(CO)2 ]和[茹(š 2 - )2(CO)2 ],氯,(S 2 - - [R 2 NCS 2 - )是通过用二硫代氨基甲酸酯溶液含羰基钌溶液制备。以这种方式,络合物[Ru II (C 2 H 5)2 NCS 2 } 2(CO)],[Ru II (CH 3)2 NCS2 } 2(CO)[Ru II (CH 3)2 NCS 2 } 2(CO)2 ],[Ru II (C 6 H 5 CH 2)2(CO)2 ]和[Ru III (C分离出6 H 5 CH 2)2 NCS 2 }(CO)2 ]。的[Ru II(C 6 H ^ 5小号- )2(CO)2 ] 3,[茹当类似的含羰基溶液分别用无水亚锡苯硫酚处理时,会形成II Cl 2(CO)2(SnCl 3)2 ] 2-和[Ru II Br 2(CO)2(SnBr