3,3-bis(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 3,3-bis(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene
• 英文别名: trichloro-[(1R,2R,5S,6S)-3-trichlorosilyl-3-tricyclo[4.2.1.02,5]non-7-enyl]silane
• 化学式: C₉H₁₀Cl₆Si₂
• 分子量: 387.067
• InChiKey: IDNPQAHQWIUHDA-VGRMVHKJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.42
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3,3-bis(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene 、 甲基溴化镁 以 乙醚 为溶剂， 反应 70.0h， 以54%的产率得到3,3-bis(trimethylsilyl)tricyclo[4.2.1.0^2,5]nonene-7
  参考文献：
  名称：

  Synthesis of silicon-substituted tricyclononenes

  摘要：

  A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.009
• 作为产物：
  描述：

  1,1-bis(trichlorosilyl)ethylene 、 四环庚烷 反应 180.0h， 以83%的产率得到3,3-bis(trichlorosilyl)-exo-tricyclo[4.2.1.0(2,5)]non-7-ene
  参考文献：
  名称：

  Synthesis of silicon-substituted tricyclononenes

  摘要：

  A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.09.009

文献信息

• Highly permeable polymer materials based on silicon-substituted norbornenes
  作者：M. L. Gringol’ts、M. V. Bermeshev、A. V. Syromolotov、L. E. Starannikova、M. F. Filatova、K. L. Makovetskii、E. Sh. Finkel’shtein

  DOI：10.1134/s0965544110050063

  日期：2010.9

  An approach to the manufacture of highly permeable polymers based on the synthesis and polymerization of norbornenes, norbornadienes, and tricyclononenes with different numbers and different positions of silicon-containing substituents has been developed. It has been found that these monomers are readily involved in metathesis polymerization yielding high-molecular-mass polymers possessing good filmforming properties. The addition (vinyl) polymerization of norbornenes is a more complex process; however, the product silylated polynorbornenes exhibit a higher gas permeability than the corresponding metathesis polynorbornenes. By the level of the gas-transport parameters, the silylated addition polynorbornenes obtained in the study are grouped with the most advanced high-permeability polymers. It has been shown that the presence of Me3Si substituent groups, their amount, and the main-chain structure are responsible for the enhancement of the gas permeability of polynorbornenes. Thus, a series of polymers with a regularly changing structure has been obtained, a result that makes it possible to reveal the polymer structure-property relations.
• Synthesis of silicon-substituted tricyclononenes
  作者：M.V. Bermeshev、A.V. Syromolotov、M.L. Gringolts、V.G. Lakhtin、E.Sh. Finkelshtein

  DOI：10.1016/j.tetlet.2011.09.009

  日期：2011.11

  A new series of tricyclononene derivatives with two and three silyl groups are successfully synthesized via [2 sigma+2 sigma+2 pi]-cycloaddition of silylethylenes to quadricyclane. The activity of the silylethylenes in the cycloaddition reactions was estimated. (C) 2011 Elsevier Ltd. All rights reserved.